A supported catalyst, its preparation method and application, and its catalytic cycloalkane hydrogenolysis ring-opening method
A supported catalyst and catalyst technology, applied in molecular sieve catalysts, chemical instruments and methods, physical/chemical process catalysts, etc., to achieve high hydrogenolysis ring-opening activity and low cracking rate
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[0033] The present invention also provides a preparation method of a supported catalyst, the method comprising the steps of:
[0034] 1) impregnating the carrier with a solution containing a compound of the first metal component and a compound of the second metal component;
[0035] 2) reducing and activating the impregnated carrier obtained in step 1);
[0036] 3) impregnating the product after step 2) reduction activation with a solution of a compound containing the second metal active component in a reducing or inert atmosphere;
[0037] 4) impregnating the support with a solution of a compound containing an alkali metal component;
[0038] Wherein, the weight ratio of the compound of the first metal active component and the compound of the second metal active component in terms of metal elements in step 1) is 10-600: 1, and the compound of the second metal active component is in step 1) and Step 3) The weight ratio in terms of metal elements is 0.01-0.8:1, the first meta...
Embodiment 1
[0074] This example is used to illustrate the catalyst provided by the present invention and its preparation method.
[0075] According to the required metal salt content of the equal volume impregnation method, 32.4 milliliters of nickel nitrate and iridium chloride impregnation solution containing 167 grams per liter of nickel and 2.22 grams per liter of iridium were prepared. Decant the impregnation solution to 36 g SiO 2 -Al 2 o 3 Carrier (prepared according to Example 2 of CN201110139331.X), after stirring evenly at 25°C and standing for 4 hours, drying at 120°C, roasting at 350°C for 4 hours, hydrogen reduction at 350°C for 4 hours, the hydrogen pressure is 0.1 MPa . Cool down to room temperature after reduction, and add 48.6 ml of mixed aqueous solution of iridium chloride and potassium chloride containing 2.96 g / L iridium and 2.96 g / L potassium under a hydrogen atmosphere, let it stand for 1 hour, and then dry it with hydrogen gas . Then by O 2 / N 2 The mixed ga...
Embodiment 2
[0085] This example is used to illustrate the catalyst provided by the present invention and its preparation method.
[0086] According to the required metal salt content of the equal volume impregnation method, 32.4 milliliters of cobalt nitrate and dichlorotetraammine platinum impregnating solution containing 167 grams per liter of cobalt and 1.11 grams per liter of platinum were prepared. The impregnating liquid is decanted to 36 grams of hydrogen-form Y-Beta composite molecular sieve-alumina carriers (prepared according to the carrier D1 of Example 1 of CN101992120A), stirred evenly at 25° C., left to stand for 4 hours, and dried at 110° C. Calcination at 500°C for 4 hours, hydrogen reduction at 350°C for 4 hours, hydrogen pressure at 0.1 MPa. After reduction, it was lowered to room temperature, and 48.6 milliliters of a mixed aqueous solution of dichlorotetraammineplatinum and sodium chloride containing 1.85 g / L of platinum and 1.48 g / L of sodium were added under a hydrog...
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