The invention provides a vinyl sulfonamide connector and application thereof. The structural formula of the vinyl sulfonamide connector is as shown in formula I, wherein X is selected from C or N; R is selected from one of or optional combination of hydrogen, amide, nitryl, hydroxyl, alkyl hydroxyl, aromatic hydroxyl, amino, alkyl amino, aromatic amino, sulfydryl, alkyl sulfydryl, aromatic sulfydryl, carboxylic acid, alkyl carboxylic acid, aromatic carboxylic acid, alkynyl, alkyl alkynyl, aromatic alkynyl, azide, alkyl azide, aromatic azide, carbonyl, alkyl carbonyl, aromatic carbonyl, aldehyde group, alkyl aldehyde group and aromatic aldehyde group; R1 is selected from one of or optional combination of hydrogen, linear, branched or cyclic alkane, acid, aldehyde group, linear carbonyl, benzyl or other aromatic benzyl and phenyl or other aromatic groups. The vinyl sulfonamide connector is high in selectivity and good in product stability.