The invention relates to a catalyst for removing NOx. The catalyst comprises a main catalyst, a carrier and a glass fiber, wherein the main catalyst is 0.05 to 3 weight percent of vanadium pentoxide (V2O5), the carrier is 85 to 97 weight percent of composite titanium white powder, and the glass fiber is 3 to 7 percent. A preparation method for the catalyst comprises processes of raw material kneading, filtration and ageing, extrusion molding, drying and dehydration, roasting for strengthening, finished product cutting, end face hardening, detection and packing and auxiliary processes of waste gas treatment for manufacturing high value added products, waste water recycle, grinding and recycle of dust waste and the like. The catalyst realizes green zero release in preparation, can be used for removing the NOx, and is suitable for an SCR (selective catalytic reduction) denitration process; and meanwhile, the activity and the service life of the catalyst are stabilized, and the catalyst is a great breakthrough in the catalyst industry.