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High-strength and high-toughness environmental-protection recycled PP composite material, as well as preparation method and application thereof

A technology for recycling polypropylene and composite materials, applied in the field of environmentally friendly recycled materials preparation, can solve the problems of affecting a wide range of application manufacturing industries, poor dispersion, high price, and achieve the effects of improving crystal transformation efficiency, reducing usage, and convenient processing.

Pending Publication Date: 2017-05-10
JINAN UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

A typical and convenient way to change the crystal form is to add a β-nucleating agent, such as: organic carboxylic acids and their salts, aromatic amides, inorganics, etc., and organic carboxylic acids and their salts have high melting points and heat resistance. It has good performance and good conversion effect and becomes a highly efficient β-nucleating agent with extraordinary potential, but it also has problems such as poor dispersion and high price, which affect its wide application in the manufacturing industry

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Preparation of β-nucleating agent (CaPA):

[0027] Weigh an appropriate amount of pimelic acid and calcium hydroxide (slightly excessive calcium hydroxide) with a molar ratio of 1:1, dissolve the two in an appropriate amount of deionized water, stir and dissolve, and pour the pimelic acid solution evenly into the Pour it into the calcium hydroxide solution while keeping stirring. After pouring, place it in a magnetic stirrer to stir for 24 hours, then place it in a vacuum drying oven to dry the mixed solution, and set the temperature to 85°C. After the water evaporates completely, the finished product When it was white lumpy cracks, it was taken out and ground in a mortar to obtain CaPA powder.

[0028] Preparation of environmentally friendly recycled polypropylene composites:

[0029] The mass percent of each component is as follows:

[0030] β-nucleating agent (CaPA): 0.01%~0.1% (the percentage is the ratio of CaPA to rPP usage)

[0031] Waste printed circuit board...

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PUM

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Abstract

The invention belongs to the technical field of environmental protection materials, and in particular relates to a high-strength and high-toughness environmental-protection recycled PP composite material. The high-strength and high-toughness environmental-protection recycled PP composite material comprises the following components in parts by weight: 80 to 95 parts of recycled PP, 5 to 20 parts of waste PCB nonmetallic epoxy resin powder, and a beta-nucleating agent of which the usage amount accounts for 0.01 to 0.1% of recycled PP; the beta-nucleating agent is calcium pimelate. According to the invention, the waste PCB nonmetallic epoxy resin powder is taken as a filling reinforcer, and the calcium pimelate is prepared to be the beta-nucleating agent and added into the recycled PP, so that the high-strength and high-toughness recycled PP composite material is prepared, the cost can be saved, and the white pollution can be reduced; the wastes are turned into useful resources, and the high-strength and high-toughness environmental-protection recycled PP composite material is convenient to process (feeding at a side material opening is not required), and environment-friendly; furthermore, the beta-nucleating agent provided by the invention is used with PCB, thereby being capable of promoting the dispersion of the beta-nucleating agent, increasing the crystal transformation efficiency, further reducing the usage amount and lowering the cost.

Description

technical field [0001] The invention belongs to the technical field of preparation of environmentally friendly recycled materials, and more specifically relates to a high-strength, high-toughness environmentally friendly recycled polypropylene composite material and its preparation method and application. Background technique [0002] With the increasing maturity of the research on polymer materials, the society has been flooded with polymers, and when such items lose their use value, they will bring about a serious environmental pollution problem - white pollution. As one of the general-purpose plastics, polypropylene (PP) is used globally every year due to its excellent mechanical properties and physical and chemical properties. One of its typical uses is as a packaging material. However, as a thermoplastic material, polypropylene has good prospects for recycling. However, the used polypropylene often has problems such as oxidation and aging, which leads to a certain degr...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L63/00C08K5/098
CPCC08L23/12C08L2205/242C08L63/00C08K5/098
Inventor 林志丹冼嘉明曹琳柏晓鹤李卫
Owner JINAN UNIVERSITY