Non-arsenic composite oxide clarifying agent

A compound oxidation and clarifying agent technology, which is applied in glass forming, glass manufacturing equipment, glass rolling, etc., can solve the problems of deliquescence of clarifying agent, complicated feeding process, poor chemical stability, etc., and achieve good clarification effect and not easy Weighing accidents, the effect of accurate weighing of ingredients

Inactive Publication Date: 2017-06-13
杨京安
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide an arsenic-free composite oxidation clarification solution to solve the defects of poor clarification effect, complicated feeding process, high labor intensity, long batching time, easy deliquescence of clarifier and poor chemical stability in the prior art. agent to solve the above problems

Method used

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Experimental program
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Effect test

Embodiment 1

[0033] The invention discloses an arsenic-free composite oxidation clarifying agent. According to the weight percentage, the composition is as follows: Sb 2 o 3 10.82 wt%, Na 2 SO 4 33.90 wt%, NaNO 3 54.51 wt%, Fe 2 o 3 0.005 wt%, NaCl 0.35 wt%.

[0034] The invention discloses an arsenic-free composite oxidation clarifying agent, which is prepared from the following raw materials according to mass percentage: 10.87wt% of antimony trioxide powder, 34.24wt% of Glauber's salt and 54.89wt% of sodium nitrate.

[0035] As a preference, the present invention also discloses a method for preparing ultra-white soda calcium silicate rolled glass by using the above-mentioned arsenic-free composite oxidation clarifying agent. The specific steps are as follows:

[0036] (1) Add Glauber's salt, sodium nitrate, and antimony powder into the mixer and stir and mix, and then seal and pack in a packaging bag to prepare an arsenic-free composite oxidation clarifier for use;

[0037] (2)...

Embodiment 2

[0046] The invention discloses an arsenic-free composite oxidation clarifying agent. According to the weight percentage, the composition is as follows: Sb 2 o 3 11.19wt%, Na 2 SO 4 42.39 wt%, NaNO 3 45.66wt%, Fe 2 o 3 0.004 wt%, NaCl 0.35 wt%.

[0047] The invention discloses an arsenic-free composite oxidation clarifying agent, which is prepared from the following raw materials according to mass percentage: 11.25wt% of antimony trioxide powder, 42.82wt% of Glauber's salt, 45.98wt% of sodium nitrate and 0.5wt% of water.

[0048] The invention also discloses a method for preparing ultra-white sodium calcium silicate rolled glass by using the above-mentioned arsenic-free composite oxidation clarifier, the specific steps are as follows:

[0049] (1) Add Glauber's salt, sodium nitrate, and antimony powder into the mixer and stir and mix, and then seal and pack in a packaging bag to prepare an arsenic-free composite oxidation clarifier for use;

[0050] (2) Weigh silica sa...

Embodiment 3

[0059] The invention discloses an arsenic-free composite oxidation clarifying agent. According to the weight percentage, the composition is as follows: Sb 2 o 3 11.44 wt%, Na 2 SO 4 41.55 wt%, NaNO 3 46.20 wt%, Fe 2 o 3 0.003 wt%, NaCl 0.35 wt%.

[0060] The invention discloses an arsenic-free composite oxidation clarifying agent, which is prepared from the following raw materials according to mass percentage: 11.50wt% of antimony trioxide powder, 41.97wt% of Glauber's salt, 46.53wt% of sodium nitrate and 0.5wt% of water.

[0061] The invention also discloses a method for preparing ultra-white sodium calcium silicate rolled glass by using the above-mentioned arsenic-free composite oxidation clarifier, the specific steps are as follows:

[0062] (1) Add Glauber's salt, sodium nitrate, and antimony powder into the mixer and stir and mix, and then seal and pack in a packaging bag to prepare an arsenic-free composite oxidation clarifier for use;

[0063] (2) Weigh silica...

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PUM

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Abstract

The invention discloses a non-arsenic composite oxide clarifying agent, which is prepared from the following components in percentages by weight: 9.5-15wt% of Sb2O3, 33.0-49.0wt% of Na2SO4, 40.0-55wt% of NaNO3, less than 0.006wt% of Fe2O3 and less than or equal to 0.35twt% of NaCl. The non-arsenic composite oxide clarifying agent has the characteristics that the clarifying agent used for low-iron, sodium and calcium silicate ultra-white rolled glass is redesigned and combined into a brand-new composite component, so that the feeding link is reduced, the ingredient weighing time is shortened, the manpower is saved, the labor intensity of a worker is reduced, the cost is reduced, more importantly, pollution to the environment caused by material flying is reduced, the hygroscopy of the material is reduced and the chemical stability of the clarifying agent is improved.

Description

technical field [0001] The invention relates to the technical field of production of low-iron sodium calcium silicate ultra-clear rolled glass, in particular to an arsenic-free composite oxidation clarifier. Background technique [0002] Ultra-clear (low-iron) soda-lime silicate rolled glass is widely used in the solar energy industry, among which, the main factor affecting the transmittance and whiteness of ultra-white (low-iron) soda-lime-silicate rolled glass is the iron oxide in the glass The form and content of the material, the iron oxides contained in the glass mainly include ferrous oxide (FeO) and iron oxide (Fe 2 o 3 ) two forms, ferrous oxide (FeO) can make the glass light blue-green, iron oxide (Fe2O3) can make the glass light yellow-green, the change between them is also reversible, that is, Fe 2 o 3 ⇌ 2FeO + 1 / 2 O 2 , under high temperature conditions and when there is a reducing agent, the content of ferrous oxide is dominant, making the glass appear light...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C1/00C03C4/00C03B13/00
CPCC03C1/004C03B13/00C03C4/005C03C4/0092
Inventor 杨镇远杨京安
Owner 杨京安
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