Deep compounding sulphur-fixing agent applicable to low sulfur content barbecue coal

The technology of a sulfur-fixing agent and sulfur content, which is applied in the field of coal cleaning, can solve the problems such as the difficulty of realizing the requirement of deep sulfur-fixing of low-sulfur barbecue coal, the difficulty of guaranteeing the food safety of barbecued food with peculiar smell, and the high temperature secondary decomposition of calcium sulfate is not considered, etc. Achieve the effect of improving sulfur fixation rate, low cost and simple components

Inactive Publication Date: 2017-06-13
兰州兰煤节净能源有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this type of composite sulfur fixation agent does not consider the high temperature secondary decomposition of calcium sulfate generated by the reaction of desulfurization components and sulfur, resulting in poor sulfur fixation effect in the high temperature section. It is still difficult to meet the requirements of deep sulfur fixation for low-sulfur barbecue coal after experimental verification
[0005] It can be said that the higher the sulfur content of the coal, the better the sulfur fixation effect can be achieved regardless of the use of calcium-based sulfur fixative or composite sulfur fixer, but for the barbecue coal prepared from low-sulfur coal, the existing solid Sulfur agents have been verified to be difficult to meet the requirements of deep sulfur fixation, and it is difficult to avoid the precipitation of a small amount of sulfur-containing gas during the combustion of low-sulfur barbecue coal, resulting in serious odor of barbecued food and difficult to guarantee food safety

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A deep composite sulfur-fixing agent suitable for low-sulfur partial roasting coal, including the following components by weight: 80 parts of calcium-based basic aggregate agent, 7 parts of salt additives, 5 parts of metal oxide additives, and reaction catalysts 4 parts, 1 part of white mud, 2 parts of clay, 1 part of potassium feldspar; of which:

[0032] The calcium-based basic aggregate agent is all composed of calcium hydroxide;

[0033] The components of the salt additive are formed according to the following proportions by weight: 5 parts of potassium carbonate and 3 parts of sodium chloride;

[0034] The components of the metal oxide additive are composed of the following proportions by weight: 5 parts of aluminum oxide, 1 part of ferric oxide, and 2 parts of magnesium oxide;

[0035] The components of the reaction catalyst are formed according to the following proportions by weight: 1 part of potassium chlorate and 3 parts of ethylene glycol monoethyl ether.

Embodiment 2

[0037] A deep composite sulfur-fixing agent suitable for low-sulfur partial roasting coal, including the following components by weight: 82 parts of calcium-based basic aggregate agent, 3 parts of salt additives, 4 parts of metal oxide additives, and reaction catalysts 3 parts, 0.5 parts of white mud, 2 parts of potassium feldspar; of which:

[0038] The components of the calcium-based basic aggregate agent are composed of the following proportions by weight: 10 parts of calcium oxide, 40 parts of calcium hydroxide, and 10 parts of calcium carbonate;

[0039] The components of the salt additive are formed according to the following proportions by weight: 3 parts of potassium carbonate, 1 part of sodium carbonate, and 2 parts of sodium chloride;

[0040] The metal oxide additives are all composed of aluminum oxide;

[0041] The components of the reaction catalyst are formed according to the following proportions by weight: 2 parts of potassium chlorate and 3 parts of ethylene ...

Embodiment 3

[0043] A deep composite sulfur-fixing agent suitable for low-sulfur partial roasting coal, including the following components by weight: 85 parts of calcium-based basic aggregate agent, 5 parts of salt additives, 5 parts of metal oxide additives, and reaction catalysts 5 parts, 2 parts of white mud, 1 part of clay, 2 parts of potassium feldspar; of which:

[0044] The components of the calcium-based basic aggregate agent are composed of the following proportions by weight: 20 parts of calcium oxide, 80 parts of calcium hydroxide, and 20 parts of calcium carbonate;

[0045] The components of the salt additive are formed according to the following proportions by weight: 2 parts of potassium carbonate, 1 part of sodium carbonate, and 4 parts of sodium chloride;

[0046] The components of the metal oxide additive are composed of the following proportions by weight: 4 parts of aluminum oxide, 1 part of ferric oxide, and 1 part of magnesium oxide;

[0047] The components of the rea...

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PUM

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Abstract

The invention provides a deep compounding sulphur-fixing agent applicable to low sulfur content barbecue coal, wherein the deep compounding sulphur-fixing agent is prepared from, by weight, 80-90 parts of calcium-based basic aggregate agent, 3-7 parts of salt additive, 3-5 parts of metal oxide additive, and 2-5 parts of reaction catalyst, wherein the calcium-based basic aggregate agent comprises calcium oxide, calcium hydroxide and calcium carbonate; the salt additive comprises potassium carbonate, sodium carbonate and sodium chloride; the metal oxide additive comprises aluminium oxide, iron trioxide and magnesium oxide; the reaction catalyst comprises potassium chlorate and ethylene glycol monoethyl ether. The compound sulphur-fixing agent realizes the in-depth sulphur fixing of the coal when the barbecue coal is prepared by the low sulphur coal type, effectively solves the problem of odor generation easily during the combustion of the barbecue coal; the components are simple and easy to acquire, low in cost, and suitable for industrial production.

Description

technical field [0001] The invention belongs to the technical field of coal cleaning, and relates to a deep composite sulfur-fixing agent suitable for low-sulfur separate roasting coal, which can achieve the purpose of removing peculiar smell and clean utilization during coal combustion. Background technique [0002] Barbecue coal is prepared from coal with low sulfur content. Although the sulfur content is low, it will inevitably release a certain amount of toxic and harmful gases such as sulfur dioxide and hydrogen sulfide during the combustion process. If measured by industrial use, it is indeed It reaches the industrial index, but in terms of food safety, it causes the food processed with barbecue coal to have a relatively large odor and is toxic. Therefore, a sulfur fixation scheme for low-sulfur barbecue coal should be proposed to reduce the release of toxic and harmful gases such as sulfur dioxide and hydrogen sulfide as much as possible during the combustion of barbe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L9/10
CPCC10L9/10
Inventor 张俊文丁国栋石磊
Owner 兰州兰煤节净能源有限公司
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