Blocking remover composition for barite pollution of oil and gas well and preparation method thereof

A technology of barite and plugging agent, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of oil and gas wells without oil and gas production, affecting oil or gas recovery, increasing the specific gravity of drilling mud, etc., to achieve Safe and non-corrosion plugging removal, simple and convenient use conditions, and fast plugging removal speed

Inactive Publication Date: 2017-07-14
GANSU HEIMA PETROCHEM ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The barite powder used to increase the specific gravity of the drilling mud is insoluble in the drilling mud, and is prone to layered settlement during the drilling of oil and gas wells. After the barite precipitates, it will block the natural fractures and capillary pores in the formation. , the formation polluted by it will lead to poor oil and gas channels after the new well is put into production, affecting oil or gas recovery; if the barite pollution is serious, it will also cause oil and gas wells to have no oil and gas production
[0003] Due to the very stable chemical properties of barite, its solubility in water and strong acid and strong alkali solutions is very small, and it cannot be dissolved and removed by conventional strong acid and strong alkali chemical cleaning.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1; raw materials were weighed according to the following components and weight: hydroxyethylacetamide 16Kg, aminoacetamide 25Kg, 3-amino-1,2,4-triazole 13Kg, cinnamamide 16Kg, crown ether (18- Crown-6) 12Kg, sodium dihydroxytartrate 8Kg, ethosuximide 21Kg, ethyl salicylate 11Kg, p-hydroxyphenylacetic acid 2Kg, ammonia (40wt%) 25Kg and water 95Kg.

[0019] The method for preparing the above raw materials into a plugging remover composition for barite pollution in oil and gas wells: first add the liquid raw material components hydroxyethylacetamide and ethyl salicylate into water, and stir evenly to obtain the first liquid; Add the solid raw material components aminoacetamide, 3-amino-1,2,4-triazole, cinnamamide, crown ether (18-crown-6), sodium dihydroxytartrate, ethosuximide and p-hydroxyphenylacetic acid, Stir until fully dissolved to obtain the second liquid; finally add the pH adjuster ammonia water to adjust the pH of the second liquid to 10.2, and then prep...

Embodiment 2

[0020] Embodiment 2; Weigh raw materials according to the following components and weights: hydroxyethylacetamide 20Kg, aminoacetamide 20Kg, 3-amino-1,2,4-triazole 16Kg, cinnamamide 12Kg, crown ether (18- Crown-6) 10Kg, sodium dihydroxytartrate 9Kg, ethosuximide 19Kg, ethyl salicylate 14Kg, p-hydroxyphenylacetic acid 3Kg, ammonia (40wt%) 30Kg, water 110Kg.

[0021] The method for preparing the above-mentioned raw materials into a plugging remover composition for barite pollution in oil and gas wells: add ammonia water as a pH adjuster to adjust the pH of the second liquid to 10.6; the rest is the same as in Example 1.

Embodiment 3

[0022] Embodiment 3; Weigh raw materials according to the following components and weights: hydroxyethylacetamide 18Kg, aminoacetamide 22Kg, 3-amino-1,2,4-triazole 15Kg, cinnamamide 14Kg, crown ether (18- Crown-6) 14Kg, sodium dihydroxytartrate 6Kg, ethosuximide 17Kg, ethyl salicylate 15Kg, p-hydroxyphenylacetic acid 1Kg, ammonia (40wt%) 35Kg, water 100Kg.

[0023] The method for preparing the above-mentioned raw materials into a plugging remover composition for barite pollution in oil and gas wells: adding a pH adjuster, ammonia water, to adjust the pH of the second liquid to 11; the rest is the same as in Example 1.

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Abstract

The invention discloses a blocking remover composition for the barite pollution of an oil and gas well. The blocking remover composition is characterized by being prepared from the following raw materials in parts by weight: 16 to 20 parts of hydroxyethyl acetamide, 20 to 25 parts of amino acetamide, 13 to 16 parts of 3-amino-1,2,4-triazole, 12 to 16 parts of cinnamamide, 10 to 14 parts of crown ether (18-crown-6), 6 to 9 parts of sodium dihydroxytartrate, 17 to 21 parts of ethosuximide, 11 to 15 parts of ethyl salicylate, 1 to 3 parts of p-hydoxyphenylactic acid, 25 to 35 parts of ammonia liquor (40wt%), and 90 to 110 parts of water. The blocking remover can be used in a temperature range from a room temperature to 100 DEG C, and can solve the blocking and barite pollution of an oil and gas well within 4 to 8 hours. The dissolution rate of barite is greater than 90%, and the scale removing rate is more than 98%. During the de-blocking process, no corrosion happens, no dead angle exists, no scale or precipitate is generated, secondary blocking is avoided, the de-blocking speed is quick, the waste liquid does not need to be delivered to the ground, and the de-blocking is safe and corrosion-free.

Description

technical field [0001] The patent of the present invention relates to an auxiliary agent used in oil recovery in oil fields, in particular to a block-removing agent composition for barite contamination of oil and gas wells, and also relates to a preparation method of the block-removing agent composition for barite pollution of oil and gas wells. Background technique [0002] In the process of oil and natural gas exploration and development, any well that encounters high-pressure oil, gas, and water layers should use a heavier drilling agent that is higher than the density of the drilling fluid in the wellbore, and the amount should be close to the amount of drilling fluid in the wellbore. The weighting agent for density is barite powder. Barite powder is a commonly used mud weighting material. The main chemical composition of barite powder is barium sulfate (BaSO 4 ). Pure barite powder is white powder with a fineness of about 200 mesh and a density of 4.2g / cm 3 , used to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/528
CPCC09K8/528
Inventor 赵丽萍刘音希刘志新
Owner GANSU HEIMA PETROCHEM ENG
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