Small oligothiophene organic molecule and preparation and application method thereof

An oligothiophene and small molecule technology, which is applied in the field of biomedicine and organic photoelectric materials, can solve the problems of energy conversion efficiency less than 2% and limited number of organic compounds, and achieve excellent thermal stability, improved solubility, and good absorption Effect

Inactive Publication Date: 2017-09-15
CENT SOUTH UNIV
View PDF3 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In 2010, Tyler's research group reported Pechmann organic small molecule photovoltaic materials, whose energy conversion efficiency is less than 2%.
However, the number of organic compounds that can be used as photovoltaic materials for organic small molecule solar cells in the prior art is limited, and it is difficult to meet the existing needs

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Small oligothiophene organic molecule and preparation and application method thereof
  • Small oligothiophene organic molecule and preparation and application method thereof
  • Small oligothiophene organic molecule and preparation and application method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] The specific reaction route is as follows:

[0056]

[0057] Proceed as follows:

[0058] 5-(5-Bromothiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thione (4)

[0059] Add 5-bromothiophene-2-carbohydrazide (0.8843g, 4.0mmol), potassium hydroxide (0.3366g, 6.0mmol), 35mL of absolute ethanol, CS to a round bottom flask 2 (0.5484 mL, 8.0 mmol), magnetically stirred and refluxed, 0.5 mL of carbon disulfide was added every 2.0 h, twice, and the reaction was stopped after 8.0 h. After the reaction was completed, the solvent was removed by rotary evaporation under reduced pressure, 30 mL of water was added, vigorously shaken, and the filtrate was obtained by filtration. Adjust the pH to about 2-3. A large amount of light yellow solid precipitated out. The light yellow solid 4 (0.843g, yield 80.1) %).

[0060] 1 The H NMR results are as follows: δ 7.63 (d, J = 4.0 Hz, 1H), 7.44 (d, J = 4.0 Hz, 1H).

[0061] 5-(5-Bromothiophen-2-yl)-3-hexyl-1,3,4-oxadiazole-2(3H)-thione(6)

[0062] 4 (1.0525 g, 4....

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
energy conversion efficiencyaaaaaaaaaa
Login to view more

Abstract

The invention discloses a small oligothiophene organic molecule and a preparation and application method thereof. The small oligothiophene organic molecule is a small oligothiophene organic molecule compound containing oxadiazole, which is high in thermal stability and solubility and has a relatively broad absorption spectrum in the ultraviolet-visible spectrum. When serving as a photovoltaic material and applied to a small organic molecule solar battery, the small oligothiophene organic molecule can embody a good photovoltaic conversion function and achieve good antibacterial effects and accordingly can serve as antibacterial drugs for bacteria such as Gram-positive bacteria and Gram-negative bacteria.

Description

Technical field [0001] The invention relates to an organic small molecule photovoltaic material and a preparation method and application thereof, in particular to an oligothiophene organic small molecule, a preparation method thereof, and application in organic small molecule solar cells or application in antibacterial drugs , Belongs to the field of organic photoelectric materials and biomedicine. Background technique [0002] In today's world, with the rapid progress of human civilization and the rapid development of society and economy, the demand for energy is increasing. However, people's excessive use of fossil fuels as conventional energy sources has led to an energy crisis, which has led people to search for and develop new energy sources. Solar energy has received more and more attention as a clean and environmentally friendly renewable energy. Solar cells that convert solar energy into electrical energy have become a hot spot for scientists. Organic photovoltaic mater...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C07D413/14H01L51/46H01L51/42A61P31/04
CPCC07D413/14H10K85/655H10K85/6565H10K30/00Y02E10/549
Inventor 彭红建栾向峰胡薏冰冯柳柳蒋历辉邹应萍
Owner CENT SOUTH UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap