217results about How to "Improve photovoltaic performance" patented technology

Organic photosensitive optoelectronic devices are disclosed. The devises comprise photoconductive organic thin films in a heterostructure, which include an exciton blocking layer to enhance device efficiency. The use of fullerenes in the electron conducting layer has lead to devices with high efficiency. Single heterostructure, stacked and wave-guide type embodiments are disclosed. Devices having multilayer structures and an exciton blocking layer are also disclosed. Guidelines for selection of exciton blocking layers are provided.

The present invention generally relates to organic photosensitive optoelectronic devices. More specifically, it is directed to organic photovoltaic devices, e.g., organic solar cells. Further, it is directed to an optimized organic solar cell comprising multiple stacked subcells in series. High power conversion efficiency are achieved by fabrication of a photovoltaic cell comprising multiple stacked subcells with thickness optimization and employing an electron blocking layer.

The present invention provides method of treating semiconductor surfaces (e.g., CIGS) using various solvents (including ionic solvents and eutectics), and methods preparing photovoltaic cells comprising treated CIGS materials.

Organic photosensitive optoelectronic devices are disclosed. The devises are thin-film crystalline organic optoelectronic devices capable of generating a voltage when exposed to light, and prepared by a method including the steps of: depositing a first organic layer over a first electrode; depositing a second organic layer over the first organic layer; depositing a confining layer over the second organic layer to form a stack; annealing the stack; and finally depositing a second electrode over the second organic layer.

Organic photosensitive optoelectronic devices are disclosed. The devises are thin-film crystalline organic optoelectronic devices capable of generating a voltage when exposed to light, and prepared by a method including the steps of: depositing a first organic layer over a first electrode; depositing a second organic layer over the first organic layer; depositing a confining layer over the second organic layer to form a stack; annealing the stack; and finally depositing a second electrode over the second organic layer.

The invention discloses a preparation method of metal halide perovskite materials. The method comprises steps as follows: a. introducing crown ether materials into a metal halide perovskite pecursor solution; b. treating an obtained solution from step (a) with a solution method to obtain metal halide perovskite materials, wherein the crown ether materials are selected from at least one of crown ether, heteroatomic crown ether and crown ether derivatives. The invention also provides the metal halide perovskite materials prepared with the preparation method as well as a metal halide perovskite solar cell device based on the metal halide perovskite materials and a preparation method of the device. The photovoltaic property and the stability of the solar cell device prepared from the metal halide perovskite materials are improved significantly.

Compositions, synthesis and applications for furan, thiophene and selenophene derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymers, namely, poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-15), poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-16), poly[(4,8-bis(5-(2-ethyhexyl)furan-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-18) and poly[(4,8-bis(5-hexylfuran-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-24) are disclosed. Further, an organic solar cell constructed of a derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymer is discussed.

The present invention provides a maximum power point tracking method and device and a photovoltaic power generation system. The maximum power point tracking method comprises: sampling present voltage and present current of a photovoltaic array; obtaining present power based on the present voltage and the present current; using difference between the present power and power for previous sampling time as present perturbation power, and based on ratio of the present perturbation power to perturbation power for previous sampling time, obtaining gradient perturbation voltage step ratio; obtaining perturbation voltage step based on the gradient perturbation voltage step ratio and voltage difference between the present voltage and the voltage for previous sampling time; and controlling output voltage based on the perturbation voltage step.

Compositions, synthesis and applications for benzene, furan, thiophene, selenophene, pyrole, pyran, pyridine, oxazole, thiazole and imidazole derivatized anthra[2,3-b:6,7-b′]dithiophene (ADT) based polymers, namely, poly{5,11-bis(5-(2-ethylhexyl)thiophen-2-yl)anthra[2,3-b:6,7-b′]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl}, poly{5,11-bis(5-(2-ethylhexyl)furan-2-yl)anthra[2,3-b:6,7-b′]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl and poly{5,11-bis(5-(2-ethylhexyl)selenophen-2-yl)anthra[2,3-b:6,7-b′]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl} are disclosed. Further, an organic solar cell constructed of a derivatized anthra[2,3-b:6,7-b′]dithiophene (ADT) based polymer is discussed.

This invention is related to novel perylene diester derivatives represented by the general formula (I) or general formula (II) as described herein. The derivatives are useful in various applications, such as luminescent dyes for optical light collection systems, fluorescence-based solar collectors, fluorescence-activated displays, and / or single-molecule spectroscopy. The invention also relates to a luminescent medium, such as a luminescent film, that can significantly enhance the solar harvesting efficiency of thin film CdS / CdTe or CIGS solar cells. The luminescent medium comprises an optically transparent polymer matrix and at least one luminescent dye that comprises a perylene diester derivative. Over 16% of an efficiency enhancement to a CdS / CdTe solar cell and over 12% of an efficiency enhancement to a CIGS solar cell can be achieved.

Organic photosensitive optoelectronic devices are disclosed. The devises are thin-film crystalline organic optoelectronic devices capable of generating a voltage when exposed to light, and prepared by a method including the steps of: depositing a first organic layer over a first electrode; depositing a second organic layer over the first organic layer; depositing a confining layer over the second organic layer to form a stack; annealing the stack; and finally depositing a second electrode over the second organic layer.

The invention relates to a method for preparing a BiFeO3 ferroelectric thin film photovoltaic battery on a glass substrate, comprising the following steps of: selecting glass as a substrate; preparing a BiFeO3 ferroelectric thin film with a perovskite structure through a chemical solution deposition method; and preparing a top electrode with a size of 0.5*0.5 mm on the thin film through a physical sputtering method. Compared with the prior art, the method disclosed by the invention can be used for preparing the BiFeO3 ferroelectric and photovoltaic thin film with a perovskite structure, which has the advantages of high consistency and good repeatability on the glass substrate, by a low cost. The prepared thin film has the advantages of excellent photovoltaic property and single-directional conductive property of a diode. The BiFeO3 ferroelectric thin film can be applicable to the fields of a photovoltaic battery and an optical electronic device due to the excellent properties.

The invention relates to a method for preparing bismuth vanadate / bismuth ferrite heterojunction film solar cells on a glass substrate. The method comprises the following steps: selecting FTO (Fluorinedoped Tin Oxide) conductive glass as a base, preparing a perovskite-structure bismuth vanadate / bismuth ferrite heterojunction film with a chemical solution deposition method, and then preparing a top electrode on the film with a physical sputtering method to obtain the solar cells. The photovoltaic effect of the bismuth vanadate film can be increased and is reversed by utilizing an ultra-thin bismuth ferrite layer. The method can prepare the bismuth vanadate / bismuth ferrite heterojunction film with high consistency and good repeatability on the glass substrate with a low cost. The prepared heterojunction film has good photovoltaic properties, the diode direction of the heterojunction film is opposite to the diode direction of a pure bismuth vanadate film, and ultra-thin bismuth ferrite ferroelectric films and similar bismuth vanadate / bismuth ferrite heterojunction films have a wide application prospect in the fields of solar cells and photoelectric devices due to the good properties.

The invention provides a TiO2 nanotube array photoanode and a preparation method thereof. The photoanode is characterized by electrodepositing a silver film on the surface of the TiO2 nanotube array of the photoanode, wherein the microscopic surface topography of the silver film is randomly distributed dendrites; the primary dendrites are 6-15mu m long; the secondary dendrites are 600nm-3mu m long; and the space between the secondary dendrites is 100-300nm. The silver modified TiO2 nanotube array photoanode is obtained by reasonably controlling the concentration, electrodeposition temperature, deposition potential and deposition time of the silver nitrate electrolyte. The silver is used as the noble metal instead of gold and electrodeposition is used instead of the electron beam lithography technology to prepare the silver nanoparticle-TiO2 nanotube array structure as the solar cell photoanode, thus lowering the cost and shortening the preparation period. The short-circuit current density and open-circuit voltage of the silver nanoparticle-TiO2 nanotube array photoanode after being modified by the metal are greatly improved compared with the short-circuit current density and open-circuit voltage of the silver nanoparticle-TiO2 nanotube array photoanode before being modified by the metal.

The invention relates to a preparation method of a solar battery with a bismuth ferrite / sodium bismuth titanate-barium titanate heterostructure ferroelectric film. The preparation method comprises the following steps of: selecting SnO2 transparent conducting glass doped with fluorine (FTO for short) as a substrate, preparing the (Na0.5Bi0.5)0.94Ba0.06TiO3 and BiFeO3 ferroelectric film by a chemical solution deposition method, then preparing an electrode on the surface of the film by a physical sputtering method. Compared with the prior art, the preparation method has the advantages that the ferroelectric photoelectric film with high consistency and good repeatability is prepared on the FTO substrate by low cost. The prepared heterostructure film has more excellent photovoltaic performance than that of the pure BiFeO3, and can be applied in the fields of photoelectric batteries and photoelectronic devices.

The present invention provides an all-inorganic perovskite solar cell based on transition metal ions doped CsPbBr<3> and a preparation method and an application thereof. Specifically, the invention isthat conductive glass is first spin-coated with an electron transfer layer and subsequently spin-coated with a lead bromide solution mixed with transition metal ions, then is spin-coated with a cesium bromide solution repeatedly; the non-porous perovskite film with a high crystallinity and a large grain size is prepared; and finally the all-inorganic perovskite solar cell based on transition metal ions doped CsPbBr<3> is assembled by blade coating of carbon back electrode. The invention reduces the defect density in the perovskite film by doping transition metal ions, simultaneously the energy band structure is adjusted; the energy loss of charge migration is reduced; and the separation, extraction and transfer of photogenerated charges and charge recombination are reduced, thereby the photoelectric conversion efficiency and long-term operation stability of the cell are improved. The invention has the advantages such as simple and feasible preparation method, large optimization spaceof material combination, no noble metal back electrode or hole transporting layer and low cost.

The invention discloses a MoS2 / Si p-n junction solar cell device and a preparation method of the MoS2 / Si p-n junction solar cell device. The MoS2 / Si p-n junction solar cell device comprises a MoS2 / Si thin film layer, a Si substrate serving as a thin film layer carrier, a metal Pd front electrode and a metal In back electrode. The n-type MoS2 thin film is deposited on the surface of the p-type Si substrate, a p-n junction is formed, and the MoS2 / Si p-n junction solar cell device is developed. The method comprises the steps of preparation of the MoS2 / Si p-n junction and preparation of metal electrodes, wherein firstly the magnetron sputtering technology is adopted, the MoS2 thin film is deposited on the surface of the p-type Si substrate, then preparation of the metal Pd front electrode and the metal In back electrode is finished, and the integral cell device is formed. The performance testing result shows that the MoS2 / Si p-n junction solar cell device has the obvious photovoltaic characteristic, and under the lighting condition of 15 mW / cm<2>, the short circuit current is 3.16 mA / cm<2>, the open circuit voltage is 0.13 V, the fill factor is 0.46 and the conversion efficiency is 1.3%.

The invention belongs to the technical field of green renewable energy and relates to a semiconductor nanocrystalline sensitized solar cell and a preparation method thereof. The semiconductor nanocrystalline sensitized solar cell is characterized in that a photoanode is sensitized with silver sulfide nanocrystalline. The photoanode sensitized with the silver sulfide nanocrystalline is non-toxic, the prepared silver sulfide nanocrystalline solar cell is green, nontoxic, environment-friendly, simple in preparation process and has excellent photovoltaic property. In addition, due to the fact that silver sulfide has appropriate energy gap, excellent cell photoelectric property is achieved.

The invention relates to a novel D-A'-PI-A polymer metal complex sensitizer (as shown in a formula I) taking 8-hydroxyquinoline derivative Cu (II) as an auxiliary electron acceptor, a preparation method of the sensitizer and application of the sensitizer to dye-sensitized solar cells. The sensitizer takes derivates of IDT (indacenodithiophene) or CZ (carbazole) as electron donors (D), 8-hydroxyquinoline derivative Cu (II) complexes serve as A' and pi bridges respectively, cyanoacrylate serves as an electron acceptor (A) and an anchor group, and Yamamoto polymerization is performed to obtain sensitizers PIDT-QCu and PCZ-QCu. The D-A'-PI-A sensitizer taking high-electrophilicity 8-hydroxyquinoline derivative Cu (II) complexes as the auxiliary electron acceptor A' is synthesized successfully. According to photovoltaic performance tests, the sensitizer is excellent in photovoltaic performance and thermal stability and has a promising application prospect.

A solid-state hole transport composite material (ssHTM) is provided made from a p-type organic semiconductor and a dopant material serving as a source for either sodium (Na+) or potassium (K+) ions. The p-type organic semiconductor may be molecular (a collection of discrete molecules, that are either chemically identical or different), oligomeric, polymeric materials, or combinations thereof. In one aspect, the p-type organic semiconductor is 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD). The dopant material is an inorganic or organic material salt. A solid-state dye-sensitized solar cell (ssDSC) with the above-described ssHTM, is also provided.

The invention discloses a two-dimensional conjugated dibenzothiophene compound as well as a preparation method and application thereof. Specifically, the compound has a general structural formula shown as formula I in the description; in formula I, R1 is linear or branched alkyl of C6-C12; R2 is linear or branched alkyl sulphanyl or linear or branched alkoxy of C6-C12; R3 is linear or branched alkyl sulphanyl or linear or branched alkoxy of a hydrogen atom and C6-C12. The compound provided by the invention has a relatively wide visible region absorption range and proper energy levels, and can be utilized for preparation of a solar cell, and the energy conversion efficiency of the prepared solar cell exceeds 8%, so that the photovoltaic property of the compound is excellent; besides, the compound can be utilized for preparation of a high-quality thin film according to a solution processing method, and can be easier to purify than a polymer material, so that an electron-rich donor material of which the purity is very high can be prepared by utilizing the compound.

The invention discloses an organic solar cell with a cyclopentyl bithiophene derivative as an electron acceptor. The organic solar cell includes a substrate, a cathode, a cathode modification layer, an active layer, an anode modification layer, and an anode. The active layer is a blend membrane of an electron donor and an electron acceptor, wherein the electron donor is PBDB-T, and the electron acceptor is a cyclopentyl bithiophene derivative DFPCIC. By making use of the good molecular planarity and appropriate energy level structure characteristic of DFPCIC, the organic solar cell of the invention has high open-circuit voltage, short-circuit current density and fill factor, and has energy conversion efficiency (PCE) up to 10.14%. Meanwhile, the organic solar cell based on PBDB-T: DFPCIC exhibits excellent thermal stability. In addition, DFPCIC is easy to synthesize, and is beneficial to reducing the cost of the organic solar cell.

The invention discloses an antimony-base compound thin film solar cell and a manufacturing method of the antimony-base compound thin film solar cell and belongs to the manufacturing field of photoelectric material and thin film solar cells. The problems that in an existing compound thin film solar cell, needed material is little in the earth crust, high in price and toxic to the human body or complex in production technology are solved. The antimony-base compound thin film solar cell comprises a substrate, a back electrode layer, a P-type absorption layer, an N-type buffering layer, an oxide thin film window layer and metal gate electrodes in a sequential deposition mode. The P-type absorption layer is made of CuXSbybetaZ material, wherein beta is S or Se. The material of the P-type absorption layer is selected from high-abundance elements in the earth crust, wherein the material is rich in resource and environmentally friendly because no toxic components are contained, the range of the energy gap of the elements is about 0.5 ev-2.5 ev, the spectral response range is wide, the light absorption coefficient is up to 105 cm-1, and therefore the compound thin film solar battery composed of the material has excellent photovoltaic performance and is environmentally friendly, and low-cost production is expected to be achieved.

The invention belongs to the field of solar cells, and discloses an isoindigo based co-polymer solar cell material, and a preparation method and an application thereof. The co-polymer has the following structural formula (I). In the formula, both R1 and R2 represent a C1-C20 alkyl group and n is an integer ranging from 10 to 100. In the isoindigo based co-polymer solar cell material provided by the invention, benzo-dithiophene has easily modified photophysical properties, and the co-polymer of the benzo-dithiophene presents excellent photovoltaic performance; isoindigo contains centrosymmetric pyrrolidone cores, so that an alkylation reaction of N atoms becomes very easily, and solubility property and photoelectric properties of the polymer can be adjusted by adjusting groups on the N atoms. Besides, isoindigo has two carbonyl groups with relatively strong electron-withdrawing effect, so that an HOMO energy level and a LUMO energy level can be reduced, thereby facilitating the increase of an open-circuit voltage. The performance can improve energy conversion efficiency of solar energy, so that the problem of low efficiency of polymer solar cells is solved.

The invention relates to a cross-linking monomer having the structure Q-(L)n-P-(L′)m;-Q′, where Q and Q′ are polymerisable units, L and L′ are linkers providing direct or indirect electronic communication between Q and P and between P and Q′, and P is an electrofunctional unit, and also to polymers prepared from such monomers. Q for example may be a heteroaromatic ring such as thiophene, furan and pyrrole. The electrofunctional group may be, for example, porphyrin, substituted porphyrin, phthalocyanine or substituted phthalocyanine. The invention also relates to an electrofunctional material including a base material and a cross-linked polymer such as described.

The invention discloses a high-efficiency ternary organic solar cell which comprises a substrate, a cathode, a cathode modification layer, an active layer, an anode modification layer and an anode. The active layer includes a blend film of a polymer electron donor PBDB-T and two types of micro-molecular electron acceptors HF-PCIC and IEICO-4F. The morphology of the active layer is optimized via complementary absorption of the PBDB-T, HF-PCIC and IEICO-4F, especially IEICO-4F. The prepared ternary organic solar cell realizes excellent photoelectric response in the wide spectrum range of 300-1000nm, and compared with a binary organic solar cell based on PBDB-T:HF-PCIC, the short-circuit current density is improved by 7.2MA / cm2, and the highest power conversion efficiency PCE reaches 11.2% which is 8.82% higher than that of the binary cell. In addition, the ternary organic solar cell has a very low energy loss (0.59eV), so that the cell has a higher open-circuit voltage.