Sulfone polymer composition and application thereof

A technology of polymer and composition, applied in the field of thermoplastic molding composition, can solve the problems of pressure embrittlement, shorten the service life of products, etc., and achieve the effect of inhibiting yellowing, avoiding crystal points and bubbles

Inactive Publication Date: 2017-10-17
KINGFA SCI & TECH CO LTD +1
View PDF6 Cites 6 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, sulfone polymers are sensitive to additives. When there are too many types of additives or the amount of additives is too large, the product is prone to deformation, twisting, and pressure cracking, which will reduce the service life of the product.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Sulfone polymer composition and application thereof
  • Sulfone polymer composition and application thereof
  • Sulfone polymer composition and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] Add 5.586kg (30mol) of 4,4'-dihydroxybiphenyl, 8.787kg (30.6mol) of 4,4' -Dichlorodiphenyl sulfone, then add 32.62kg of sulfolane, stir and heat up to 100°C to dissolve the monomer until the solution is transparent, add 3.396kg (32.039mol) salt-forming agent Na 2 CO 3 And 132.6g (0.961mol) salt-forming agent K 2 CO 3 , then add 2L of xylene, continue to stir and heat up until the salt-forming reaction begins, the azeotrope generated by the water and xylene in the system is blown out by the protective gas, condensed and dropped to the water separator for stratification, and the upper layer The xylene was refluxed into the system again; the temperature was maintained in the range of 200°C to 210°C, and when the amount of collected water was close to the theoretical value (540g), the reflux was continued for another 20 minutes, and no water drops were observed, which proved that the salt formation was complete, and then Distill and release xylene, and gradually raise th...

Embodiment 2

[0055] The preparation process conditions are the same as in Example 1 to prepare polyphenylene sulfone PPSU, add the additives PEPQ and 1330 to the PPSU resin powder in a weight ratio of 1:1, mix with a high-speed mixer for 10 minutes to ensure uniform mixing, and then extrude with a single screw Melt granulation by machine to obtain plastic particles of sulfone polymer composition, wherein the total content of additives is 3000ppm by weight in the sulfone polymer composition. Then use an injection molding machine to melt and prepare a color plate. The crystal point, air bubbles and yellowing performance index tests were carried out with the prepared transparent swatches, and the results are shown in Tables 4-6.

Embodiment 3

[0057] The preparation process conditions are the same as in Example 1 to prepare polyphenylene sulfone PPSU, add the additives PEPQ and 1010 to the PPSU resin powder in a weight ratio of 99:1, mix with a high-speed mixer for 10 minutes to ensure uniform mixing, and then extrude with a single screw Melt granulation with a machine to obtain plastic particles of the sulfone polymer composition, wherein the total content of additives is 500 ppm by weight in the sulfone polymer composition. Then use an injection molding machine to melt and prepare a color plate. The crystal point, air bubbles and yellowing performance index tests were carried out with the prepared transparent swatches, and the results are shown in Tables 4-6.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a sulfone polymer composition and application thereof. The sulfone polymer composition comprises one of polysulfone, polyether sulfone and polyphenylene sulfone, phosphite additive and hindered phenol additive, heat resistance of the phosphite additive and the hindered phenol additive is characterized by heat weightlessness analysis (TGA), weightlessness at 360 DEG C is not higher than 10%, and the hindered phenol additive accounts for 1-50% of total sum of the phosphite additive and the hindered phenol additive. The sulfone polymer composition can be applied in the field of food safety, household electrical appliances, medical health, electronics, aerospace or energy chemical industry.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a sulfone polymer composition and a thermoplastic molding composition composed of it and its application. Background technique [0002] Sulfone polymers are special high-temperature-resistant transparent thermoplastic engineering plastics, mainly including three types: polysulfone PSU, polyethersulfone PES and polyphenylene sulfone PPSU. It has excellent mechanical properties, high rigidity, wear resistance, high strength, high thermal stability, and a high glass transition temperature of about 190°C. It maintains excellent mechanical properties even at high temperatures. The long-term use temperature is 160°C, and the short-term use temperature is 190°C. It is resistant to hydrolysis, good dimensional stability, small molding shrinkage, non-toxic, radiation-resistant, flame-resistant, and self-extinguishing. , has excellent electrical properties and chemical stability...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L81/06C08K5/526C08K5/524C08K5/3492C08K5/13C08K5/134
Inventor 代惊奇高红军陈锐斌龙杰明孙学科曹民
Owner KINGFA SCI & TECH CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap