Preparation method of water-resistant adhesive used for bonding metal member
A technology for metal components and water-resistant adhesives, applied in the direction of adhesives, adhesive types, non-polymer adhesive additives, etc., can solve the problems of limited epoxy resin application, poor impact resistance, insufficient toughness, etc., and achieve excellent mechanical properties , good durability, simple and easy preparation method
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Embodiment 1
[0029] A kind of water-resistant adhesive of the present embodiment for bonding metal components, expressed in parts by weight, comprises 80-210 parts of hydrogenated bisphenol A type epoxy resin base material, 25-58 parts of diaminodiphenylmethane curing agent, Propylene oxide o-tolyl ether 6-15 parts, filler 13-25 parts, ethylene propylene rubber 9-17 parts, DOPO flame retardant 6-12 parts.
[0030] Preparation method of the present invention, concrete steps are:
[0031] (1) First prepare the raw materials for hydrogenated bisphenol A epoxy resin, expressed in parts by weight, take 3-4 parts of sodium hydroxide, 19-31 parts of epichlorohydrin, and 9-13 parts of hydrogenated bisphenol A, Methyl isobutyl ketone is added to the reaction kettle in a certain proportion, and a catalyst is added, then a constant temperature water bath of 50-60°C is stirred; then condensed and refluxed for 24 hours;
[0032] (2) After the reaction is completed, add deionized water and mix thorough...
Embodiment 2
[0037] A kind of water-resistant adhesive for metal member bonding of the present embodiment is expressed in parts by weight, 150 parts of the hydrogenated bisphenol A type epoxy resin base material, 40 parts of diaminodiphenylmethane curing agent, propylene oxide 6 parts of o-cresyl ether, 10 parts of filler, 8 parts of ethylene propylene rubber, and 9 parts of DOPO flame retardant.
Embodiment 3
[0039] A kind of water-resistant adhesive for bonding metal components of the present embodiment, expressed in parts by weight, 200 parts of the hydrogenated bisphenol A type epoxy resin base material, 48 parts of diaminodiphenylmethane curing agent, propylene oxide 7 parts of o-cresyl ether, 14 parts of filler, 12 parts of ethylene propylene rubber, and 12 parts of DOPO flame retardant.
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