Carbonized supercapacitor electrode material, preparation method and use thereof
An electrode and composite material technology, which is used in the manufacture of hybrid capacitor electrodes and hybrid/electric double-layer capacitors to achieve the effect of simple and easy operation, excellent electrochemical performance, and large capacitance in the carbonization process.
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example 1
[0027] The washed celery was vacuum freeze-dried in a freeze dryer for 48 hours. Place the completely dried sample in a tubular resistance furnace, heat it up to 500°C under nitrogen protection, and carbonize it at a constant temperature for 3 hours. , and then cooled to room temperature, rinsed and dried with hydrochloric acid to prepare a porous activated carbon material, such as figure 1 shown. Put the porous activated carbon material and aniline in a 1mol / L dilute hydrochloric acid solution according to the mass ratio (1:1) and mix them thoroughly, and add persulfuric acid with the molar mass of aniline to the above solution drop by drop under the condition of ice-water bath Ammonium solution, stirring while adding dropwise until the ammonium persulfate solution is added dropwise, then continue to stir the solution for 12 hours and then filter, rinse the product with deionized water for several times until the filtrate pH=7, then vacuum dry the product, porous activated c...
example 2
[0030] The washed celery was vacuum freeze-dried in a freeze dryer for 48 hours. Place the completely dried sample in a tubular resistance furnace, heat it up to 500°C under nitrogen protection, and carbonize it at a constant temperature for 3 hours. , and then cooled to room temperature, rinsed and dried with hydrochloric acid, the porous activated carbon material was prepared. Put the porous activated carbon material and aniline in a 1mol / L dilute hydrochloric acid solution according to the mass ratio (1:1) and mix them thoroughly. Ammonium sulfate solution, stirring while adding dropwise until the ammonium persulfate solution is added dropwise, then continue to stir the solution for 12 hours and then filter, rinse the product with deionized water for several times until the filtrate pH=7, then vacuum dry the product to obtain porous activity Carbon / polyaniline composite. Put the prepared porous activated carbon / polyaniline composite material into a high-temperature tube f...
example 3
[0033]The cleaned lotus pods were vacuum freeze-dried in a freeze dryer for 48 hours. Place the completely dried sample in a tubular resistance furnace, heat it up to 500°C under nitrogen protection, and carbonize it at a constant temperature for 3 hours. , and then cooled to room temperature, rinsed and dried with hydrochloric acid to prepare a porous activated carbon material. Put the porous activated carbon material and aniline in a 1mol / L dilute hydrochloric acid solution according to the mass ratio (1:1) and mix them thoroughly, and add persulfuric acid with the molar mass of aniline to the above solution drop by drop under the condition of ice-water bath Ammonium solution, stirring while adding dropwise until the ammonium persulfate solution is added dropwise, then continue to stir the solution for 12 hours and then filter, rinse the product with deionized water for several times until the filtrate pH=7, then vacuum dry the product, porous activated carbon / polyaniline ...
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