Application of synthetic calcium carbonate as high paper filler and preparation method of high paper filler

A papermaking filler, calcium silicate technology, applied in the field of papermaking, can solve the problems of short mixing time of filler and fiber, unable to meet the requirements of paper index, unable to add traditional filler, etc., to achieve good suspension, improve opacity, improve non-toxicity The effect of transparency

Inactive Publication Date: 2017-10-24
内蒙古普诺思新材料科技有限公司
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  • Abstract
  • Description
  • Claims
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AI Technical Summary

Problems solved by technology

Although this method solves the shortcomings of traditional fillers with high density and fast settling speed, the mixing time of fillers and fibers is too short, which is not conducive to the full physical filling of fillers in fibers. A large amount of fillers are gathered on the surface, causing the phenomenon of "powder falling" on the paper surface
[0006] 3. At present, conventional fillers used in the papermaking field generally have a relatively high density. Even if a relatively high filler filling ratio is satisfied in the process, the thickness of fixed quantitative paper will be affected by the addition of a large amount of fillers, so that it cannot meet the index of paper Requirements, so in the case of paper thickness requirements, it is impossible to add too much traditional filler

Method used

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  • Application of synthetic calcium carbonate as high paper filler and preparation method of high paper filler
  • Application of synthetic calcium carbonate as high paper filler and preparation method of high paper filler
  • Application of synthetic calcium carbonate as high paper filler and preparation method of high paper filler

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preparation example Construction

[0046] Preparation of synthetic calcium silicate powder:

[0047] Adopt liquid phase dynamic hydrothermal synthesis method, comprise the following steps:

[0048] A, raw material preparation: prepare lime emulsion and sodium silicate solution, described lime emulsion is obtained after digesting and diluting active quicklime by calcining limestone, wherein the concentration of lime emulsion is controlled so that the CaO concentration is 140-220g / L, and the silicon The sodium silicate solution is obtained by diluting high-purity quartz sand with alkali, and the obtained sodium silicate solution is controlled to contain SiO 2 35-140g / L;

[0049] B. Hydrothermal synthesis of calcium silicate: control of CaO / SiO in sodium silicate solution and lime emulsion 2 The molar ratio is 0.95-1.05, the water-solid mass ratio (5-15): 1, mix evenly, heat up to 75-100°C, control the temperature rise and reaction time to 1-2.5h, and the stirring speed is 100-400rpm;

[0050] C. Preparation o...

Embodiment 1

[0055] The plant pulp board adopts bleached kraft softwood pulp board, and the mass ratio of bleached kraft softwood pulp board to synthetic calcium silicate powder filler is controlled to be 50:50.

[0056] Take the bleached kraft softwood pulp board and disintegrate it with a hydraulic pulper, send it to the pulp storage tank before knocking, and adjust the mass fraction concentration of the pulp to 6.0%; beat it with a disc refiner to a Canadian standard freeness of 275mL Finally, adjust the slurry concentration to a mass fraction of 4.0%, and send it to the slurry storage tank after knocking;

[0057] The synthetic calcium silicate powder is made into an emulsion in water under the action of a high-speed disperser, and the synthetic calcium silicate powder is prepared into a calcium silicate slurry with a concentration of 5%-15%. After passing through the sieving equipment, the synthetic calcium silicate powder filler is driven into the pulp storage tank after beating, and...

Embodiment 2

[0062] The plant pulp board adopts bleached kraft softwood pulp board and bleached hardwood pulp board, and the mass ratio of plant pulp board to synthetic calcium carbonate powder filler is 48:52, of which bleached kraft softwood pulp board and bleached hardwood pulp board The mass ratio of the plates was 15:33.

[0063] Disintegrate and disperse the bleached kraft softwood pulp board and the bleached hardwood pulp board with a hydraulic pulper respectively, and send them to two pulp storage tanks before knocking, and adjust the mass fraction concentration of the pulp to 4.5%; After beating the above two kinds of wood pulp to Canadian standard freeness of 265mL (softwood pulp) and 300mL (hardwood pulp), adjust the pulp concentration to a mass fraction of 4.0%, and send it to the pulp storage tank after beating;

[0064] The synthetic calcium silicate powder is made into an emulsified liquid in water under the action of a high-speed disperser. After passing through the sieving...

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Abstract

The synthetic calcium carbonate, as the application of papermaking filler, belongs to the papermaking technical field. The plant pulp fiber material is as the skeleton, synthetic calcium silicate power is as the filler, and the high paper filler is produced by paper-making technics. The synthetic calcium silicate power is as the hydrated calcium aluminate, and the object composition includes C-S-H polymer gel and tobermorite, and the brightness of synthetic calcium silicate power is greater than or equal to 90%, the specific surface area is greater or equal to 120 square meters per gram, the bulk density is from 0.12 grams per centimeter to 0.30 grams per centimeter, the oil-absorbed value is 120-200 milliliters per milligram, and the average grain diameter is (D50) from 12 microns to 40 microns . Meanwhile, the invention also discloses the preparation method of synthetic calcium carbonate: the synthetic calcium silicate power is the paper filler, then under the premise that paper properties are guaranteed, the usage of plant fiber can be decreased at the greatest extent. Replacing the traditional paper filler by synthetic calcium silicate power can not only reduce the usage of plant filler at the greatest extent, but also increase the retention rate of calcium carbonate, decrease the waste of filler and improve the paper ash content.

Description

technical field [0001] The invention belongs to the technical field of papermaking, and relates to papermaking fillers and high-filler papers, in particular to the application of synthetic calcium silicate as papermaking fillers and a papermaking method for high-filler papers. Background technique [0002] At present, in the field of conventional paper production, taking cultural paper as an example, a large amount of plant fiber pulp is used as the paper skeleton, and about 10%-25% of calcium carbonate or calcium carbonate is added to the plant fiber through the flow delivery system. Traditional mineral fillers such as talcum powder and a small amount of chemical additives complete papermaking. This kind of paper has high printing performance, writing performance and other performance, and has played an indispensable role in the development of human culture and spiritual civilization and the continuation of history. The use of fillers in the paper industry is to achieve th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H17/68
CPCD21H17/68
Inventor 徐鹏齐建军
Owner 内蒙古普诺思新材料科技有限公司
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