Dump leaching processing method for waste furnace-constructing refractory materials of aluminum electrolytic bath
A technology for waste and refractory materials of aluminum electrolytic cells, which is applied in chemical instruments and methods, alkali metal fluorides, carbonate preparations, etc. cost effect
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Embodiment 1
[0017] A method for heap leaching treatment of waste furnace building refractory materials in aluminum electrolytic cells, the method steps are as follows:
[0018] A. Sorting the slag from the overhaul of the aluminum electrolytic cell, and selecting the waste refractory materials for furnace construction;
[0019] B. Use a jaw crusher to crush the waste refractory materials for furnace construction, and use a 50-mesh sieve to screen after the crushing is completed;
[0020] C. Perform one pre-leaching, one leaching, and four washings of the waste furnace building refractory materials with a particle size of 0.15cm to 0.8cm after crushing; After soaking for 3 days in a closed pre-leaching tank with a 2% NaOH solution, transfer the pre-soaked slag and the pre-soaked solution to the subsequent leaching tank, and send the ammonia gas generated by the pre-leaching into the sulfuric acid washing system Ammonium sulfate is produced as a by-product; the bulk specific gravity of pre...
Embodiment 2
[0024] A method for heap leaching treatment of waste furnace building refractory materials in aluminum electrolytic cells, the method steps are as follows:
[0025] A. Sorting the slag from the overhaul of the aluminum electrolytic cell, and selecting the waste refractory materials for furnace construction;
[0026] B. Use a jaw crusher to crush waste refractory materials for furnace construction, and then screen after crushing;
[0027] C. Perform one pre-leaching, one leaching, and four washings of the waste furnace refractories with a particle size of 0.3cm to 1cm after crushing; when the first batch of waste furnace refractories is processed, the first pre-leaching is to send the waste furnace refractories into In the closed pre-leaching tank, the NaOH solution with a mass concentration of 4% is used to spray and soak for 3 days, and then the pre-soaking residue and the pre-soaking liquid are transferred to the subsequent leaching tank. By-product ammonium sulfate; the he...
Embodiment 3
[0031] A method for heap leaching treatment of waste furnace building refractory materials in aluminum electrolytic cells, the method steps are as follows:
[0032] A. Sorting the slag from the overhaul of the aluminum electrolytic cell, and selecting the waste refractory materials for furnace construction;
[0033] B. Use a jaw crusher to crush waste refractory materials for furnace construction, and then screen after crushing;
[0034] C. Perform one pre-leaching, one leaching, and four washings of the waste furnace building refractory materials with a particle size of 1cm to 1.5cm after crushing; when the first batch of waste furnace building refractory materials is processed, the first pre-leaching is to send the waste furnace building refractory materials into In the closed pre-leaching tank, the NaOH solution with a mass concentration of 3% is used to spray and soak for 3 days, and then the pre-soaked slag and the pre-soaked liquid are transferred to the subsequent leach...
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