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Catalytic Combustion Evaluation Device and Test Method for Volatile Organic Compounds

An organic compound, catalytic combustion technology, applied in the combustion method, combustion type, measurement device and other directions, can solve the problems of less catalyst loading, too ideal reaction state, unable to load honeycomb monolithic catalyst, etc., to achieve accurate test data, The effect of good data repeatability and large loading volume

Active Publication Date: 2021-01-01
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

From the introduction of the two laboratory evaluation devices, P21 and P25, it can be judged that the temperature measurement of the P21 device has defects. Since VOCs will release a lot of heat during catalytic combustion, when the thermocouple is in the catalyst bed, the measured The temperature is higher than the preheating temperature of the material, and the test data cannot directly assist the industrial design; in addition, the loading amount of the catalyst is too small, and it can be judged that the catalyst must be broken before loading, and the device cannot be filled with the honeycomb monolithic catalyst, which is not conducive to the interpretation of the test results. industrial transformation
The P22 device is an intrinsic kinetic device. On the one hand, the catalyst must be broken, and on the other hand, it is always in the constant temperature zone of the reactor. The reaction state is too ideal and cannot simulate the actual industrial situation.

Method used

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  • Catalytic Combustion Evaluation Device and Test Method for Volatile Organic Compounds
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  • Catalytic Combustion Evaluation Device and Test Method for Volatile Organic Compounds

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Experimental program
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Effect test

Embodiment 1

[0045] Such as figure 1 As shown, the volatile organic compound catalytic combustion evaluation device of the present invention includes a reactor 3, the reactor 3 is connected to the gas mass flow meter 1 and the metering pump 2 respectively, the reactor 3, the heat exchanger 4, the condenser 6, the gas Liquid separator 7, wet flow meter 9, drying pipe 10, gas chromatograph 11 are connected to computer 12 in sequence, heat exchanger 4 is connected to blower 5, gas-liquid separator 7 is connected to liquid storage tank 8, and exhaust head 13 is respectively It is connected with the wet flow meter 9 and the drying pipe 10.

[0046] Such as figure 2As shown, the inside of the reactor 3 is provided with a sprayer 14 , a heating plate 15 and a steel wire mesh 18 sequentially from left to right, and the outside of the reactor 3 is connected with a temperature measuring instrument 16 and a pressure measuring instrument 17 respectively.

[0047] The number of temperature measuring...

Embodiment 2

[0054] On the VOCs catalytic combustion evaluation device of the present invention, 3 kg of honeycomb monolithic catalysts are loaded, and the evaluation test is carried out to toluene according to the test method of Example 1, and the evaluation data are shown in Table 4.

[0055] Table 4 Toluene purification results

[0056]

Embodiment 3

[0058] On the VOCs catalytic combustion evaluation device of the present invention, 3.5 kg of the catalyst prepared by filling the irregular carrier was carried out, and the evaluation test was carried out to toluene according to the test method of Example 1, and the evaluation data are shown in Table 5.

[0059] Table 5 Toluene purification results

[0060]

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Abstract

The invention belongs to the technical field of catalyst evaluation and particularly relates to a volatile organic compound catalytic combustion evaluation device and a test method. The volatile organic compound catalytic combustion evaluation device comprises a reactor, the reactor is respectively connected to a gas mass flow meter and a metering pump, the reactor, a heat exchanger, a condenser, a gas-liquid separator, a wet flow meter, a drying pipe and a gas chromatograph are orderly connected to a computer, the heat exchanger is connected to a blower, the gas-liquid separator is connected to a liquid storage tank and an exhaust head is respectively connected to the wet flow meter and the drying pipe. The device has a large filling amount, can be filled with a whole honeycomb-type monolith catalyst, can acquire test data having high authenticity, is conducive to conversion from a laboratory device into an industrial device, is provided with the heat exchanger, fully utilizes heat and reduces laboratory power consumption.

Description

technical field [0001] The invention belongs to the technical field of catalyst evaluation, and in particular relates to a catalytic combustion evaluation device and test method for volatile organic compounds. Background technique [0002] With the increasingly stringent environmental protection, chemical and petrochemical process waste gas containing volatile organic compounds (VOCs), petroleum, chemical product storage tank gas, printing and paint production waste gas, extraction waste gas, wood carbonization waste gas, pharmaceutical factory waste gas, and automobile exhaust And more and more use incineration treatment or catalytic combustion treatment. Compared with the traditional condensation method, absorption method, adsorption method and biological method, the combustion method has a lower impact on VOC S The treatment is more thorough and complete, and it has become the first choice for the treatment of complex pollutant components and high-concentration waste gas...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N30/02F23G7/07
CPCF23G7/07F23G2209/14G01N30/02G01N2030/025
Inventor 王昊白志敏赵庆鲁姜建波齐焕东薛红霞余汉涛梁卫忠
Owner CHINA PETROLEUM & CHEM CORP
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