Refractory material lining body for steel ladle and preparation method of refractory material lining body

A refractory material and lining technology, applied in the field of refractory materials, can solve the problems of large heat loss, crystallization, steel breakout, etc., and achieve the effect of simplified structure and simple and flexible preparation method

Active Publication Date: 2018-01-23
UNIV OF SCI & TECH BEIJING +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 2. Among lightweight thermal insulation materials, especially nano-sheets and fiberboards, although the thermal insulation performance is better, crystallization, strength reduction or pulverization will occur at a slightly higher temperature, resulting in structural damage, which will make the work The supporting force of the lining and safety lining is reduced, resulting in red envelopes or steel leakage, which is also one of the factors that cause the most accidents in steel mills
[0007] 3. The safety of the heavy permanent lining (safety lining) material is relatively good, and it can resist the erosion of high-temperature slag and molten steel to ensure the safety of the ladle, but the thermal conductivity is relatively high and the heat loss is large; while the medium and heavy materials , although the heat insulation performance is good, but in the case of damage to the working lining, it cannot resist the erosion of high-temperature slag, and it is easy to cause accidents such as steel breakout
[0009] Calcium hexaaluminate is a material with a magnetoplumbite structure and has a lamellar structure; the thermal conductivity between the lamellar structures is very low, which is also the main feature and advantage of calcium hexaaluminate materials. Although it has a high density, However, the thermal conductivity is very low; this property is very important for the safety and thermal insulation performance of the ladle
[0010] The lamellar structure endows the calcium hexaaluminate material with very good thermal insulation properties, but it also makes it difficult to sinter the calcium hexaaluminate material, so it is difficult to prepare a bulk density higher than 2.8g / cm 3 Calcium hexaaluminate materials above

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A refractory lining for ladles, the working lining is castable, the scheme is: 65% of dense calcium hexaaluminate raw materials, 30% of corundum and alumina micropowder, 5% of pure calcium aluminate cement, plus dispersant Wait for the right amount. The chemical composition of the castable is: Al 2 o 3 93%, CaO6.9%, the rest traces. The above percentages are all percentages by mass. Bulk density greater than 2.8g / cm 3 .

[0037] The permanent lining is castable, and the plan is: 95% of dense calcium hexaaluminate raw material, 5% of pure calcium aluminate cement, plus appropriate amount of dispersant. The chemical composition of the castable is: Al 2 o 3 90.5%, CaO9.0%, the rest traces. The above percentages are all percentages by mass. The bulk density is 3.0g / cm 3 .

[0038] In this example, the working lining has excellent corrosion resistance to molten steel, while the permanent lining has very good heat insulation performance and safety. The combined ref...

Embodiment 2

[0040] A refractory lining for ladles, the working lining is refractory bricks, the plan is: 100% dense calcium hexaaluminate raw materials with different particle ratios, plus an appropriate amount of binder, pressed and formed, and fired at a high temperature of 1450-1650 ° C to make. The chemical composition of the refractory brick is: Al 2 o 3 91.5%, CaO7.8%, the rest traces. The above percentages are all percentages by mass. Bulk density greater than or equal to 2.7g / cm 3 .

[0041] The permanent lining is castable, and the plan is: 65% of dense calcium hexaaluminate raw material, 10% of magnesium aluminum spinel raw material, 22% of corundum and activated alumina micropowder, 3% of pure calcium aluminate cement, and appropriate amount of dispersant . The chemical composition of the castable is: Al 2 o 3 90.6%, CaO6.3%, MgO3%, the rest traces. The above percentages are all percentages by mass. Bulk density greater than 2.8g / cm 3 .

[0042] In this example, the...

Embodiment 3

[0044] A refractory lining for ladles, the working lining is a prefabricated part, the scheme is: 75% of dense calcium hexaaluminate raw material, 20% of magnesium aluminum spinel raw material, 5% of pure aluminate cement, appropriate amount of dispersant . The chemical composition of the preform is: Al 2 o 3 86.2%, CaO7.7%, MgO6.0%, the rest traces. The above percentages are all percentages by mass. Bulk density greater than 2.7g / cm 3 .

[0045] The permanent lining is refractory bricks, and the plan is: 100% dense calcium hexaaluminate raw materials with different particle ratios, plus an appropriate amount of binder, pressed into shape, and fired at a high temperature of 1450-1650 °C. The chemical composition of the refractory brick is: Al 2 o 3 91.5%, CaO7.8%, the rest traces. The above percentages are all percentages by mass. Bulk density greater than 2.7g / cm 3 .

[0046] In this example, the working lining has excellent corrosion resistance to molten steel, wh...

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Abstract

The invention discloses a refractory material lining body for a steel ladle and a preparation method of the refractory material lining body. The refractory material lining body comprises a working lining and a permanent lining. The working lining is located on the inner side of the permanent lining, the working lining is made of a heavy calcium hexaluminate material to be used for resisting the high temperature, and the permanent lining adopts a medium-heavy or light calcium hexaluminate material to be used for conducting heat preservation and thermal insulation. The working lining and the permanent lining can be manufactured by adopting the methods of in-situ casting, a prefabricated member or a refractory brick. According to the refractory material lining body for the steel ladle, the problem that the steel ladle refractory material causes impurities in molten steel can be solved, no impurity can be led into the molten steel in the using process, meanwhile the impurities in steel canbe captured, and the molten steel can be purified and the quality is improved.

Description

technical field [0001] The invention belongs to the technical field of refractory materials, and in particular relates to a refractory lining for a ladle and a preparation method thereof. Background technique [0002] Ladle is a very important thermal equipment in the iron and steel metallurgy process, which mainly plays the role of receiving, transporting, refining and pouring molten steel. Due to the special working environment of the ladle, it is necessary to design the refractory lining of the ladle. Ladle refractory lining is generally divided into three parts: working lining, safety lining and thermal insulation lining. The working lining is generally alumina-magnesia-carbon bricks, magnesia-carbon bricks, corundum-spinel castables (prefabricated parts), corundum-based aluminum-magnesium castables (prefabricated parts), etc., which are resistant to slag and molten steel erosion. The safety lining usually adopts clay bricks, medium-heavy ordinary low-cement castables,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22D41/02
Inventor 陈俊红刘忠江李斌侯新梅杜珏玉冯广
Owner UNIV OF SCI & TECH BEIJING
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