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Preparation method and application of parathion-methyl adsorption material

A technology of methyl parathion and adsorption materials, which is applied in chemical instruments and methods, adsorption water/sewage treatment, and other chemical processes, and can solve problems such as increased sludge production, inability to balance sulfur and phosphorus adsorption effects with cost, etc. , to achieve the effect of low chemical consumption, solving the incompatibility between removal effect and operating cost, and high removal efficiency

Active Publication Date: 2018-02-23
QINGDAO TECHNOLOGICAL UNIVERSITY
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  • Description
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Problems solved by technology

[0006] In order to solve the above problems, the present invention has the advantages of high removal efficiency and low cost by synthesizing high-efficiency modified iron-manganese-based adsorption materials, and solves the problem that the adsorption effect and cost of methyl parathion cannot be balanced
[0007] In order to achieve the above object, the present invention provides a kind of methyl parathion adsorption material, including iron manganese oxide modified simultaneously with ethylenediaminetetraacetic acid and cetyltrimethylammonium bromide; The iron-manganese oxide is coated on the surface of the filter material to remove methyl parathion in the form of filtration, and remove methyl parathion in the form of filtration, which solves the problem of increased sludge production caused by direct addition to water, and has removal efficiency High, low cost and other advantages

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  • Preparation method and application of parathion-methyl adsorption material
  • Preparation method and application of parathion-methyl adsorption material

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Embodiment 1

[0023] A kind of methyl parathion adsorption material, including iron manganese oxide modified simultaneously with ethylenediaminetetraacetic acid and cetyltrimethylammonium bromide; the modified iron manganese oxide is coated on On the surface of the filter material, methyl parathion is removed by filtration, which solves the problem of increased sludge production caused by direct addition to water, and has the advantages of high removal efficiency and low cost.

[0024] A preparation method for preparing the above-mentioned methyl parathion adsorption material, comprising preparing iron oxide, preparing manganese oxide, and mixing and modifying; wherein the mixing and modifying step is mixing iron oxide and manganese oxide and adding ethylenediamine Modified with tetraacetic acid and cetyltrimethylammonium bromide. Specifically include the following steps:

[0025] (1) Accurately weigh 6.50g FeSO 4 ·7H 2 O, and dissolved in 500mL deionized water, configured as a solution....

Embodiment 2

[0031] Steps (1)~(4) are identical with embodiment 1;

[0032] Step (5) is filling the obtained iron-manganese-based modified filter material in the filter reactor. The filter tank is cylindrical, with an inner diameter of 3.5 cm and a height of 15 cm. The filtration flow rate of the filter is 3.5m / h, the influent methyl parathion concentration is 0.125mg / L, the effluent concentration is 0.008mg / L, and the removal rate is 93.6%.

[0033] pass figure 1 It can be seen that the removal effect of the iron-manganese-based modified filter material prepared by the present invention on the filtration and removal of methyl parathion is that the concentration gradient of methyl parathion in the influent changes between 0.04~0.155 mg / L, and the filtration rate is 3.5 mg / L. m / L, its removal rate ranges from 90 to 98%; figure 2 It can be seen that when using non-modified conventional quartz sand, manganese sand, and zeolite filter materials, the concentration gradient of methyl parathi...

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Abstract

The invention relates to the field of feed water treatment, in particular to a preparation method and application of a parathion-methyl adsorption removal material in a drinking water source. The parathion-methyl adsorption material comprises iron and manganese oxides which are modified by using ethylenediamine tetraacetic acid and hexadecyl trimethyl ammonium bromide at the same time; the surfaceof a filter material is coated with the modified iron and manganese oxides, and parathion-methyl is removed in a filtering mode, so that the problem is solved that the sludge generation amount is increased due to the fact that the adsorption material is directly put into water, and the adsorption material has the advantages of high removal efficiency, low cost and the like.

Description

technical field [0001] The invention relates to the field of water supply treatment, in particular to a preparation method and application of a material for adsorbing and removing methyl parathion in drinking water sources. Background technique [0002] With the rapid development of social economy, ensuring the safety of drinking water has become an important research topic. As a phosphorus-containing pesticide, methyl parathion is widely used in the process of agricultural development, resulting in excessive methyl parathion content in some drinking water sources. For such water sources, the removal of parathion-methyl becomes the core of the water purification process. At present, the technologies for removing methyl parathion mainly include biodegradation, enhanced coagulation, and adsorption separation. [0003] The biodegradation of methyl parathion does not require chemical agents and saves drug consumption. However, as a biodegradable pollutant, methyl parathion nee...

Claims

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Application Information

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IPC IPC(8): B01J20/22B01J20/28B01J20/30C02F1/28C02F101/34C02F101/38
CPCB01J20/06B01J20/22B01J20/28026C02F1/28C02F2101/34C02F2101/38C02F2101/40
Inventor 蔡言安毕学军
Owner QINGDAO TECHNOLOGICAL UNIVERSITY