Method for preparing corrosion prevention coating with titanium in blast furnace slag

A technology of blast furnace slag and titanium layer, which is applied in the field of anti-corrosion steel, can solve the problems of secondary processing utilization increasing process cost and affecting the quality of titanium deposition layer, so as to achieve the effect of improving quality and avoiding disproportionation reaction

Inactive Publication Date: 2018-03-16
NORTH CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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Problems solved by technology

And the method for preparing titanium deposition layer on the surface of the metal substrate also mostly uses the chloride of the alkali metal in molten state as the electrolyte, and it is easy to obtain dendritic or powdery crystals under the molten salt system, which affects the quality of the titanium deposition layer.
And after the titanium metal is prepared, the secondary processing and utilization of the titanium metal increases the cost of the process

Method used

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  • Method for preparing corrosion prevention coating with titanium in blast furnace slag
  • Method for preparing corrosion prevention coating with titanium in blast furnace slag
  • Method for preparing corrosion prevention coating with titanium in blast furnace slag

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Embodiment 1

[0028] Analytical pure NaCl, analytical pure KCl, analytical pure NaF, and titanium-containing blast furnace slag with a titanium dioxide content of 20 wt% were ground and refined with an agate mortar, and then dried in a vacuum oven at 473K for 24 hours to remove the reagents. Residual moisture, then sealed and stored for later use;

[0029] Fully mix 78.963g of NaCl, 62.005g of KCl, 89.032g of NaF and 10g of titanium-containing blast furnace slag, pour them into a corundum crucible, and then put it into a resistance for heating. When the temperature displayed on the furnace reaches the set temperature of 730°C ( At this time, the temperature in the furnace is 800°C), and then the molten salt is kept warm for 4 hours, so that the titanium-containing blast furnace slag can reach a state of dissolution equilibrium.

[0030] Polish the carbon steel sheet with metallographic sandpaper (360#, 600#, 800#, 1500#) in order from coarse to fine, and then microwave it in sodium hydroxid...

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Abstract

The invention provides a method for preparing a titanium layer on the surface of low-carbon steel with a fused salt electrodeposition method by using titanium in blast furnace slag. Fused salt compositions adopted in the method include NaCl, KCl, NaF and titanium-containing blast furnace slag. The invention further provides a preparation method of corrosion prevention steel. The preparation methodincludes the following steps that the fused salt electrodeposition method is used for depositing the titanium layer on the steel surface; and fused salt compositions adopted in the fused salt electrodeposition method include NaCl, KCl, NaF and titanium-containing blast furnace slag. According to the method, the titanium-containing blast furnace slag, the NaCl, the KCl and the NaF are used as a fused salt system; and when the fused salt electrodeposition method is used for preparing the titanium deposition layer, titanium ions can better exist in the fused salt system in a low-valent oxidationstate, no disproportionated reaction happens in the fused salt electrodeposition process, and therefore the quality of the titanium deposition layer can be improved, and dendritic or powdered crystals can be basically avoided. The fused salt electrodeposition method is used for preparing the titanium corrosion prevention coating, and thus the corrosion resistance of a steel substrate can be improved obviously.

Description

technical field [0001] The invention belongs to the technical field of anti-corrosion iron and steel, and in particular relates to a molten salt composition for preparing a titanium layer by a molten salt electrodeposition method and a preparation method for anti-corrosion iron and steel. Background technique [0002] At present, in the process of preparing titanium metal by molten salt electrodeposition, most of them are based on the preparation of titanium metal powder. The methods for preparing titanium deposits on the surface of metal substrates mostly use molten alkali metal chlorides as electrolytes. Dendritic or powdery crystals are easily obtained in this molten salt system, which affects the quality of titanium deposits. And after the titanium metal is prepared, the secondary processing and utilization of the titanium metal increases the cost of the process. The titanium source used is titanium-containing blast furnace slag, saving resources. Contents of the inve...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D3/66
CPCC25D3/66
Inventor 梁精龙李慧严红燕霍东兴李运刚王冬斌杨宇张汉鑫郑天新张立生王斌王蓝卿于米满王晶
Owner NORTH CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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