Decomposition resistant ps conductive masterbatch

A masterbatch and raw material technology, applied in the field of decomposition-resistant PS conductive masterbatch, can solve the problems of product production and product quality defects, product stress cracking, inability to use antistatic products, etc., to broaden the application field, excellent high temperature resistance and Physical and mechanical properties, the effect of effective ESD protection

Active Publication Date: 2022-07-12
浙江三和塑料有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although the cheap PS conductive masterbatch has reduced the production cost for many manufacturers, polystyrene (PS), an amorphous random polymer, is brittle due to the rigidity of the molecular chain, and it is easy to cause stress cracking of the product. Toughening is a rubber elastomer added with EPDM or styrene-butadiene-styrene, but whether it is a linear or star-shaped rubber elastomer, because of its molecular structure and inherent physical propert

Method used

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  • Decomposition resistant ps conductive masterbatch

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Effect test

Example Embodiment

[0026] Example 1

[0027] A decomposition-resistant PS conductive masterbatch, comprising the following raw materials in parts by weight: 10 parts of superconducting carbon black, 46 parts of high-impact polystyrene PS, a toughening agent (consisting of 10 parts of ethylene butyl acrylate and 15 parts of drawing grade polystyrene) ethylene compound) 25 parts, reinforcing agent (by CaCO 3 and SiO 2 According to the weight ratio of 1:1, 8 parts, 0.8 parts of vinyltriethoxysilane, 1.2 parts of antioxidants, 1 part of EBS, and 8 parts of EMA; the preparation method of the decomposition-resistant PS conductive masterbatch comprises the following steps :

[0028] S1, take by weighing each raw material according to the above-mentioned weight portion ratio;

[0029] S2, adding high-impact polystyrene PS, superconducting carbon black, reinforcing agent, coupling agent, antioxidant, EBS, EMA into the mixing equipment in turn and mixing at 50° C. for 20 minutes to obtain Mixture A;

...

Example Embodiment

[0032] Example 2

[0033] A decomposition-resistant PS conductive masterbatch, comprising the following raw materials in parts by weight: 7 parts of superconducting carbon black, 52 parts of high-impact polystyrene PS, a toughening agent (consisting of 10 parts of ethylene butyl acrylate and 15 parts of drawing grade polystyrene) ethylene compound) 25 parts, reinforcing agent (by CaCO 3 and SiO 2 According to the weight ratio of 3:1, 7 parts, 0.4 part of coupling agent, 0.8 part of antioxidant, 0.8 part of EBS, 3 parts of EMA;

[0034] The preparation method of the decomposition-resistant PS conductive masterbatch comprises the following steps:

[0035] S1, take by weighing each raw material according to the above-mentioned weight portion ratio;

[0036]S2, adding high-impact polystyrene PS, superconducting carbon black, reinforcing agent, coupling agent, antioxidant, EBS, and EMA into the mixing equipment in turn and mixing at 55° C. for 30 minutes to obtain Mixture A;

...

Example Embodiment

[0039] Example 3

[0040] A decomposition-resistant PS conductive masterbatch, comprising the following raw materials in parts by weight: 10 parts of superconducting carbon black, 53 parts of high-impact polystyrene PS, a toughening agent (made of 8 parts of ethylene butyl acrylate and 17 parts of drawing grade polystyrene) ethylene compound) 25 parts, reinforcing agent (by CaCO 3 and SiO 2 According to the weight ratio of 4:1, 6 parts, 0.3 part of coupling agent, 1 part of antioxidant, 0.7 part of EBS, 4 parts of EMA;

[0041] The preparation method of the decomposition-resistant PS conductive masterbatch comprises the following steps:

[0042] S1, take by weighing each raw material according to the above-mentioned weight portion ratio;

[0043] S2. Add high-impact polystyrene PS, superconducting carbon black, reinforcing agent, coupling agent, antioxidant, EBS, and EMA to the mixing equipment in turn and mix at 60° C. for 15 minutes to obtain Mixture A;

[0044] S3, set ...

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Abstract

The invention discloses a decomposition-resistant PS conductive masterbatch. The decomposition-resistant PS conductive masterbatch includes the following raw materials by weight percentage: 5-10% of superconducting carbon black, 30-60% of high-impact polystyrene, toughened 18 to 30% of antioxidants, 3 to 9% of reinforcing agents, 0.2 to 0.8% of coupling agents, 0.2 to 1.2% of antioxidants, 0.2 to 1.2% of EBS, and 3 to 8% of EMA. In the present invention, superconducting carbon black is used as the conductive carrier, high impact polystyrene PS is used as the base material, and compound toughening agent, reinforcing agent, coupling agent, antioxidant, EBS and EMA are respectively used as lubricants. , dispersant and compatibilizer are compounded according to the appropriate ratio, and the obtained decomposition-resistant PS conductive masterbatch has excellent high temperature resistance and physical and mechanical properties; the decomposition-resistant PS conductive masterbatch can not only be used in polycarbonate and other needs The antistatic materials produced by high temperature co-extrusion can also be used in corresponding conductive and antistatic packaging materials such as electronics, electrical appliances, communications, aerospace, etc., to achieve safe and effective ESD protection for packaged electronic products.

Description

technical field [0001] The invention relates to the technical field of plastic conductive masterbatch, in particular to a decomposition-resistant PS conductive masterbatch. Background technique [0002] PS conductive masterbatch, the product uses polystyrene resin as matrix, conductive carbon black with high oil absorption value and ultra-fine particle size as conductive interface, block copolymer thermoplastic elastomer to increase toughness, dispersant, internal and external lubricants Adjusting the melt index of the masterbatch, combined with rigid particle reinforcement and compatibilizer compatibilization, a high-conductivity masterbatch developed by a specific process of single and twin-screw multi-polymerization and secondary extrusion, the product's melting strip resistance reaches 10 3~4 Ω, the forming resistance reaches 10 5~9 Ω, can establish a safe and effective ESD protection. [0003] The inexpensive PS conductive masterbatch reduces the production cost for m...

Claims

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Application Information

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IPC IPC(8): C08L51/04C08L23/08C08L23/06C08K13/02C08K3/04C08K3/26C08K3/36C08K5/5425C08J3/22C08L69/00B29B9/06B29B9/12B29C48/92
CPCC08J3/226B29B9/06B29B9/12B29C48/92C08J2451/04C08J2423/08C08J2423/06C08K13/02C08K3/04C08K2003/265C08K3/36C08K5/5425C08K2201/001C08J2369/00
Inventor 吴中心陈洪林傅剑琼
Owner 浙江三和塑料有限公司
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