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Spraying-free toughened nylon 6 material and preparation method thereof

A spray-free, nylon technology, applied in the field of polymer material modification, can solve the problems of prolonging the production cycle, surrounding environmental pollution, waste of resources, etc., and achieve the effects of promoting uniform dispersion, improving compatibility, and improving fluidity

Active Publication Date: 2018-06-05
NANJING LIHAN CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, spraying paint on the surface of the product will bring additional problems: First, the paint itself has a strong smell, which seriously affects the health of the operators during the painting operation and also pollutes the surrounding environment
Second, it is difficult to peel off the paint coating of plastic products treated by spray painting, and cannot be recycled and reused, resulting in waste of resources
The third is that the painting process is complex and often requires multiple production processes, resulting in extended production cycles and increased production costs
In this patent, the compatibilizer involved is maleic anhydride grafted polyolefin elastomer, which cannot solve the problem of flow marks and weld marks on the surface of injection-molded products caused by the fluidity of the material.

Method used

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  • Spraying-free toughened nylon 6 material and preparation method thereof
  • Spraying-free toughened nylon 6 material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] A spray-free toughened nylon 6 material, in terms of mass percentage, its raw material is composed of the following components: 59.4% nylon 6 resin, 15% toughening agent, 12% plasticizer, 6% maleic anhydride grafted polypropylene, 0.6% oxidized polyethylene wax, 0.5% flow modifier, 0.5% antioxidant, 1.0% lubricant, 5% metal masterbatch; the nylon 6 is medium viscosity nylon 6; the toughening agent is horse Maleic anhydride grafted POE, the grafting rate is 0.8%; the plasticizer is caprolactam; the maleic anhydride grafted polypropylene, the grafting rate is 0.8%; the flow modifier is trimellitic anhydride ; The antioxidant is a mixture of antioxidant 1098 and antioxidant 168, the mass ratio of the two is 1:1; the lubricant is OP wax; the active ingredient of the metal masterbatch is aluminum pink.

[0042] The dried nylon 6, toughener, plasticizer, maleic anhydride grafted polypropylene, dispersant, flow modifier, antioxidant, lubricant and metal masterbatch according ...

Embodiment 2

[0044]A spray-free toughened nylon 6 material, in terms of mass percentage, its raw material is composed of the following components: 76.9% nylon 6 resin, 10% toughening agent, 7% plasticizer, 3% maleic anhydride grafted polypropylene, 0.2% dispersant, 0.2% flow modifier, 0.2% antioxidant, 0.5% lubricant, 2% metal masterbatch; the nylon 6 is medium viscosity nylon 6; the toughening agent is maleic anhydride Grafted POE, its graft rate is 0.8%; Described plasticizer is caprolactam; Described maleic anhydride grafted polypropylene, graft rate is 0.8%; Described flow modifier is trimellitic anhydride; The antioxidant is a mixture of antioxidant 1098 and antioxidant 168, the mass ratio of the two is 1:1; the lubricant is OP wax; the active ingredient of the metal masterbatch is silver powder.

[0045] The dried nylon 6, toughening agent, plasticizer, maleic anhydride grafted polypropylene, oxidized polyethylene wax, flow modifier, antioxidant, lubricant and metal masterbatch in th...

Embodiment 3

[0047] A spray-free toughened nylon 6 material, in terms of mass percentage, its raw material consists of the following components: 71.2% nylon 6 resin, 12% toughening agent, 8% plasticizer, 4% maleic anhydride grafted polypropylene, 0.5% oxidized polyethylene wax, 0.3% flow modifier, 0.2% antioxidant, 0.8% lubricant, 3% metal masterbatch; the nylon 6 is medium viscosity nylon 6; the toughening agent is horse Maleic anhydride grafted POE, the grafting rate is 0.8%; the plasticizer is caprolactam; the maleic anhydride grafted polypropylene, the grafting rate is 0.8%; the flow modifier is trimellitic anhydride The antioxidant is a mixture of antioxidant 1098 and antioxidant 168, the mass ratio of the two is 1:1; the lubricant is OP wax; the active ingredient of the metal masterbatch is zinc pink.

[0048] The dried nylon 6, toughening agent, plasticizer, maleic anhydride grafted polypropylene, oxidized polyethylene wax, flow modifier, antioxidant, lubricant and metal masterbatc...

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Abstract

The invention discloses a spraying-free toughened nylon 6 material and a preparation method thereof and belongs to the technical field of modification of high molecular materials. The material is prepared from 59.4 to 76.9 percent of nylon 6 resin, 10 to 15 percent of a toughening agent, 7 to 12 percent of a plasticizer, 3 to 6 percent of maleic anhydride grafted polypropylene, 0.2 to 0.6 percentof oxidized polyethylene wax, 0.2 to 0.5 percent of a flowing modifier, 0.2 to 0.5 percent of an antioxidant, 0.5 to 1.0 percent of a lubricant and 2 to 5 percent of metal master batch. According to the spraying-free toughened nylon 6 material disclosed by the invention, the maleic anhydride grafted polypropylene, the oxidized polyethylene wax, the flowing modifier and the plasticizer are added, the dispersity of the metal master batch in nylon 6 matrix resin and the compatibility between the metal master batch and the nylon 6 matrix resin are improved and the flowability of the material is improved, so that the problem in the prior art that flowing marks and welding marks are formed on the surface by a spraying material in a product injection molding process is avoided; the prepared spraying-free material has a metal texture which is the same as that in a traditional paint spraying technology and the problem that appearance of the spraying-free material is not good in actual application is solved.

Description

technical field [0001] The invention belongs to the field of polymer material modification, and in particular relates to a spray-free toughened nylon 6 material and a preparation method thereof. Background technique [0002] Nylon 6 (PA6, also known as polycaprolactam) is widely used in many fields such as automobiles, electronic appliances, and chemical building materials because of its high mechanical strength, wear resistance, self-lubrication, and good electrical insulation. When downstream products are used as both structural parts and exterior parts, it is often necessary to spray paint on the surface to make the parts have a good appearance, thereby improving the quality of the product. But spraying paint on the surface of the product will bring additional problems: the first is that the paint itself has a strong smell, which seriously affects the health of the operator during the painting operation and pollutes the surrounding environment. The second is that it is d...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L51/06C08L23/30C08K13/02C08K5/1539C08K5/20C08K5/526C08K3/08
CPCC08K2003/0806C08K2003/0812C08K2003/0893C08L77/02C08L2205/025C08L2205/035C08L51/06C08L23/30C08K13/02C08K5/1539C08K5/20C08K5/526C08K3/08
Inventor 张伟吴玉成孙圳袁锦瑶
Owner NANJING LIHAN CHEM CO LTD
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