A method for producing light tar by catalytic co-refining of low-rank coal and methane

A methane catalysis and low-rank coal technology, which is applied in the petroleum industry and the preparation of liquid hydrocarbon mixtures, etc., can solve the problems of energy consumption and economic cost increase, and achieve the effects of reducing hydrogen production costs, simplifying the process, and high process integration

Active Publication Date: 2020-08-04
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Application Information

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Problems solved by technology

However, the hydrogen production reaction of methane reforming is an endothermic reaction, and additional catalysts need to be introduced, which increases energy consumption and economic costs.

Method used

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  • A method for producing light tar by catalytic co-refining of low-rank coal and methane
  • A method for producing light tar by catalytic co-refining of low-rank coal and methane
  • A method for producing light tar by catalytic co-refining of low-rank coal and methane

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029]The selected coal is Inner Mongolia lignite, and its industrial analysis and elemental analysis data are shown in Table 1. The coal particle size is 40-60 mesh, the fluidization gas (gas inlet C) used by the return pneumatic valve 4 is methane, and the loosening gas (gas inlet B) is nitrogen. By adjusting the rotation speed of the screw feeder and the return pneumatic valve The gas flow rate in valve 4 is such that the feed rate of coal particles is 10g / min; methane enters from gas inlet A, and the flow rate is set at 2000mL / min; the temperature in the down-bed is set at 700°C, and the pressure is 0.1MPa; 12 in HZSM-5 (SiO 2 with Al 2 o 3 The molar ratio is 50:1) particles, the particle size is 20-40 mesh, and the temperature is set at 600°C; the temperature of the circulating cooling water passing through the tar condensation device 13 is about 5°C; a certain amount of hot semi-coke is passed through the two-way return After the pneumatic valve 10, return to the rise...

Embodiment 2

[0031] In this example, the same experimental method as in Example 1 is adopted, except that after passing through the riser reactor 9, the temperature of the high-temperature semi-coke is raised to 1000±10°C.

Embodiment 3

[0033] In this example, the same experimental method as in Example 2 is adopted, the difference is that the fixed bed 12 is filled with nickel-supported HZSM-5 (Ni / HZSM-5) as a catalyst, and its specific preparation method is comparative example 4 unanimous.

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Abstract

The invention belongs to the fields of energy and chemical industry, particularly provides a method for producing light tar by catalyzing and corefining low-rank coal and methane, and mainly solves the technical problem that the quality of pyrolytic tar of low-rank coal is increased is solved so as to increase the content of light aromatic hydrocarbon with important application values in tar. A down reactor, which is a riser coupling reactor, is adopted as a main body reaction unit, and the main body reaction unit is high in heat and mass transfer efficiency, simple in technological process, high in integration level and continuous and reliable in operation; high-temperature semicoke is taken as a catalyst, and methane is cracked into hydrogen, so that hydrogenation pyrolysis of coal is realized, the yield of tar and the content of light aromatic hydrocarbon inside tar are improved, and the cost of the catalyst and the hydrogen source is obviously reduced; moreover, the high-temperature semicoke is taken as a solid heat carrier, so that the heat efficiency of the process is greatly improved; moreover, an new approach for efficient clean utilization is developed for methane-rich rawmaterial gas such as traditional fossil energy coal and natural gas.

Description

technical field [0001] The invention belongs to the field of energy and chemical industry, and in particular relates to a method for producing light tar by catalytic co-refining of low-rank coal and methane. Background technique [0002] Aromatic compounds, especially single-ring aromatics such as benzene, toluene and xylene, which have important synthetic significance, are indispensable organic chemical basic raw materials and play an important role in the development of the national economy. At present, the production of aromatics mainly comes from petrochemical industry. According to the "2015 Domestic and Foreign Oil and Gas Industry Development Report" statistics, in 2015, my country's dependence on foreign crude oil reached 60.6%. Therefore, relying solely on petrochemicals to produce aromatics will face enormous pressure, and it is imperative to seek alternative or supplementary raw materials. my country is a typical country with "more coal and less oil". Adopting t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G1/06
CPCC10G1/06
Inventor 侯宝林王贵金张涛
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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