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Single-component water-based black paint for automobile and preparation method thereof

A single-component, water-based technology, applied in the field of coatings, can solve the problems of film compactness, raw material miscibility, fluidity, loss of fluidity, unbalanced acid and alkali resistance, etc., and improve the compatibility of raw materials. Sexual problems, improve liquidity, stabilize the effect of good effect

Active Publication Date: 2018-07-13
GUANGDONG YATU CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Patent document CN104312399B discloses a high-blackness blue-phase black topcoat and its preparation method. The high-blackness blue-phase black topcoat is compounded with hydroxyl acrylic resin, hydroxyl polyester resin and various additives. Excellent performance, good leveling, good weather resistance, good hardness, and good scratch resistance; patent document CN106800874A discloses a water-based two-component polyurethane topcoat and its preparation method, but the curing agent in the topcoat Contains both hydrophilic and hydrophobic polyisocyanate curing agents, and the content of water-based hydroxyl acrylic dispersion in component A is high, and the acid and alkali resistance of the product is unbalanced
[0005] The general water-based one-component black paint on the market is generally resistant to water at 40°C for 3-5 days and then wrinkles and delaminates obviously. After being stored at 40°C for 1-3 days, water will be separated obviously, and at the same time, it will be condensed after being placed at 0°C for 1-3 days. , loss of liquidity, and insufficient blackness and blue phase, unable to meet the needs of the high-end market
The reason for this problem is that an important problem in the process of preparing water-based paint is how to make the oil-soluble polymer soluble in water. The solutions mainly include salt-forming method, alcoholysis method, and the method of introducing non-ionic hydrophilic groups. etc. Through the above methods, its defects can be improved, but it is often difficult to give full consideration to properties such as paint film compactness, raw material miscibility, and fluidity.

Method used

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  • Single-component water-based black paint for automobile and preparation method thereof
  • Single-component water-based black paint for automobile and preparation method thereof
  • Single-component water-based black paint for automobile and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Preparation of dispersant

[0042] Dispersant described in the present embodiment is hyperbranched polyurethane oligomer, and its preparation method is as follows:

[0043] Step S1, add 40 parts by weight of diisocyanate aqueous solution with a mass fraction of 45% to the container, then add 2 parts by weight of dibutyltin dilaurate, stir, and control the temperature at 40 ° C, add 2 parts by weight of p-hydroxyanisole and 30 Parts by weight of an aqueous solution of hydroxyethyl methacrylate with a mass fraction of 50%, reacted for 2.5 hours to obtain an intermediate solution;

[0044]In step S2, the temperature of the intermediate solution obtained in step S1 is raised to 60°C, and 35 parts by weight of a hyperbranched polyester aqueous solution with a mass fraction of 30% is added, reacted for 2.5 hours, and the resulting mixture is added to deionized water, and stirred until the liquid becomes clear Color and solid powder, filtered, air-dried, that is.

[0045] Am...

Embodiment 2

[0047] The single-component water-based black paint for automobiles is obtained by mixing components A, B and C in a weight ratio of 4:4:0.05:

[0048] Wherein A component is made up of the composition of following parts by weight:

[0049]

[0050]

[0051] B component is: aliphatic polyurethane dispersion;

[0052] C component is: Tego TEGO3060 rheological agent.

[0053] Wherein, described dispersant is the hyperbranched polyurethane oligomer that embodiment 1 makes, and described aliphatic polyurethane dispersion is by weight ratio 35:64 by aliphatic anionic polyurethane, N-ethyldiisopropylamine and water: 1 composition.

[0054] The preparation method of the single-component water-based black paint for automobiles is as follows:

[0055] Step 1: Preparation of component A:

[0056] Add methyl glycol, substrate wetting agent, and dispersant to water and mix evenly, and stir for 10 minutes at a speed of 500 rpm, then add high-pigment carbon black, and stir for 30 ...

Embodiment 3

[0059] The single-component water-based black paint for automobiles is obtained by mixing components A, B and C in a weight ratio of 4:5.9:0.1:

[0060] Wherein A component is made up of the composition of following parts by weight:

[0061]

[0062] B component is: aliphatic polyurethane dispersion;

[0063] C component is: Tego TEGO3060 rheological agent.

[0064] Wherein, described dispersant is the hyperbranched polyurethane oligomer that embodiment 1 makes, and described aliphatic polyurethane dispersion is by weight ratio 35:64 by aliphatic anionic polyurethane, N-ethyldiisopropylamine and water: 1 composition.

[0065] The preparation method of the single-component water-based black paint for automobiles is similar to that of Example 2.

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Abstract

The invention relates to single-component water-based black paint for an automobile and a preparation method thereof. The single-component water-based black paint for the automobile is prepared by mixing three components A, B and C according to the weight ratio of 4 to (4 to 7) to (0.05 to 0.2), wherein the component A is prepared from the following components in parts by weight: 3 to 7.5 parts ofhigh-pigment carbon black, 15 to 35 parts of water, 3 to 10 parts of methyl ethylene glycol, 0.3 to 2.5 parts of base material wetting agent and 1.5 to 7.5 percent of dispersant; the component B is an aliphatic polyurethane dispersion body; the component C is a rheological agent. According to the single-component water-based black paint for the automobile, the compatibility problem of raw materials is remarkably improved, and the flowability, storage stability, luster, blackness and a blue phase are improved.

Description

technical field [0001] The invention belongs to the technical field of coatings, and in particular relates to a single-component water-based black paint for automobiles and a preparation method thereof. Background technique [0002] Paint, formerly known as paint, refers to a substance that can be applied to the surface of an object, firmly combined with the volume, and forms a solid film with a certain strength. The coating of an automobile body is a multi-layer system, usually including an electrophoretic deposition primer layer, a middle paint layer, Topcoat layer, etc. The topcoat, as the last layer of coating, must have several functions: 1. Good appearance: including high fullness, high gloss, good leveling, no shrinkage cavity, no prickly heat, etc.; 2. Excellent protection performance: including good hardness, good flexibility, good weather resistance, good water resistance, good salt spray resistance, etc.; 3. Excellent construction: including good wettability, not ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/04C09D7/65C09D7/61
CPCC08L2205/025C08L2205/035C09D175/04C08L75/04C08L75/14C08L83/12C08K3/04C08K5/053
Inventor 冯兆华阮伟明伍祺卓李耀明陈容爱
Owner GUANGDONG YATU CHEM
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