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An antibacterial air filter membrane based on polyacrylonitrile/graphene oxide/tea polyphenol composite and its preparation method

A technology of polyacrylonitrile and air filter membrane, which is applied in the direction of chemical instruments and methods, separation methods, membranes, etc., can solve the problem of large gaps and cannot effectively filter small air particles, and achieve excellent permeability, increase filtration effect, Good antibacterial performance

Inactive Publication Date: 2020-01-24
ENERGY RES INST CO LTD HENAN ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the fiber diameter of traditional filter materials is at the micron level, and the gaps are too large to effectively filter tiny particles in the air. Studies have shown that as the fiber diameter decreases, the filtration performance of the material gradually increases. When the fiber diameter is at the nanometer level can significantly improve the filter performance of the material for PM2.5

Method used

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  • An antibacterial air filter membrane based on polyacrylonitrile/graphene oxide/tea polyphenol composite and its preparation method
  • An antibacterial air filter membrane based on polyacrylonitrile/graphene oxide/tea polyphenol composite and its preparation method

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Effect test

Embodiment 1

[0024] An antibacterial air filter membrane based on polyacrylonitrile / graphene oxide / tea polyphenol composite, with non-woven fabric as the substrate, and the surface of the substrate is deposited with polyacrylonitrile / graphene oxide / tea polyphenol composite The composite film, the mass ratio of polyacrylonitrile, graphene oxide, and tea polyphenols is 16:4:8, the thickness of the substrate is 0.07mm, and the thickness of the composite film is 0.03mm.

[0025] The method for preparing the antibacterial air filter membrane based on polyacrylonitrile / graphene oxide / tea polyphenol composite comprises the following steps:

[0026] 1) Preparation of graphene oxide DMF dispersion: Add 50 g of DMF solution to 50 g of graphene oxide aqueous dispersion with a concentration of 2 mg / ml to obtain a mixed dispersion, and place the mixed solution in a rotary evaporator to rotate to its peak value. The quality does not change significantly (the quality difference of the last two rotary-eva...

Embodiment 2

[0032] An antibacterial air filter membrane based on polyacrylonitrile / graphene oxide / tea polyphenol composite, with non-woven fabric as the substrate, and the surface of the substrate is deposited with polyacrylonitrile / graphene oxide / tea polyphenol composite composite film, the mass ratio of polyacrylonitrile, graphene oxide and tea polyphenol is 30:10:16. The thickness of the base material is 0.07mm, and the thickness of the composite film is 0.03mm.

[0033] The method for preparing the antibacterial air filter membrane based on polyacrylonitrile / graphene oxide / tea polyphenol composite comprises the following steps:

[0034] 1) Preparation of graphene oxide DMF dispersion: Add 50 g of DMF solution to 50 g of graphene oxide aqueous dispersion with a concentration of 2 mg / ml to obtain a mixed dispersion, and place the mixed solution in a rotary evaporator to rotate to its peak value. The quality does not change significantly (the quality difference of the last two rotary-evap...

Embodiment 3

[0039] An antibacterial air filter membrane based on polyacrylonitrile / graphene oxide / tea polyphenol composite, with non-woven fabric as the substrate, and the surface of the substrate is deposited with polyacrylonitrile / graphene oxide / tea polyphenol composite The composite film, the mass ratio of polyacrylonitrile, graphene oxide, and tea polyphenols is 16:4:4, the thickness of the substrate is 0.07mm, and the thickness of the composite film is 0.03mm.

[0040] The method for preparing the antibacterial air filter membrane based on polyacrylonitrile / graphene oxide / tea polyphenol composite comprises the following steps:

[0041] 1) Preparation of graphene oxide DMF dispersion: Add 50 g of DMF solution to 50 g of graphene oxide aqueous dispersion with a concentration of 2 mg / ml to obtain a mixed dispersion, and place the mixed dispersion in a rotary evaporator to rotate to its mass No change (take the quality difference of the last two rotary steamed mixtures in the sampling in...

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Abstract

The invention discloses an antibacterial air filter membrane based on a polyacrylonitrile / graphene oxide / tea polyphenol compound. The antibacterial air filter membrane takes a non-woven fabric as a base material, and a composite membrane formed by the polyacrylonitrile / graphene oxide / tea polyphenol compound is deposited on the surface of the base material; the mass ratio of polyacrylonitrile to graphene oxide to tea polyphenol is (16 to 30) : (4 to 10) : (1 to 16). Meanwhile, the invention provides a corresponding preparation method. A microscopic structure of the antibacterial air filter membrane provided by the invention is as follows: polyacrylonitrile (PAN) nano-fibers form a staggered net-shaped structure aggregate, and the diameter is about 50 to 300nm; the graphene oxide (GO) is dispersed between the PAN fibers and between crossed points of the fibers; the diameter distribution of the GO is relatively great, and is in a micron grade; a structure that the nano-fibers is combinedwith a micron layered object is formed by the GO and the PAN. By adopting the structure disclosed by the invention, the thickness of the filter membrane can be improved and the porosity of the filtermembrane is kept; the filtering efficiency of the filter membrane is improved, and the pressure drop of the filter membrane is effectively kept; the filter membrane has the effect of filtering PM2.5 (Particulate Matter 2.5) in the air and has good antibacterial performance.

Description

technical field [0001] The invention relates to an antibacterial air filter membrane based on a polyacrylonitrile / graphene oxide / tea polyphenol compound and a preparation method thereof. Background technique [0002] In recent years, with the development of industrialization and urbanization, air pollution has become increasingly serious. Among them, PM2.5, a tiny particle in the air, stays in the air for a long time and travels a long distance, and can pass through the upper and lower respiratory tracts of the human body, and finally deposits in the lungs of the human body, and even enters the blood through the lungs, posing a major threat to the human body , can cause respiratory disease, heart disease, etc., and can also put pregnant women at risk of premature delivery. The air filter membrane can effectively remove tiny particles in the air, and can be applied to respirators, indoor air purifiers, industrial gas purification, etc. Therefore, the increasingly serious en...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D71/42B01D71/06B01D71/02B01D69/12B01D67/00B01D46/54
CPCB01D46/543B01D67/0079B01D69/12B01D71/021B01D71/06B01D71/42B01D2323/39B01D2325/48
Inventor 雷廷宙张艳彩张修强任素霞董莉莉吴清林何晓峰岳增合石杰
Owner ENERGY RES INST CO LTD HENAN ACADEMY OF SCI
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