Application of clay-resistant water reducing agent with high water reducing rate in concrete with high clay content
A concrete and high mud content technology, applied in the direction of sustainable waste treatment, solid waste management, climate sustainability, etc., can solve the problem of large loss of concrete slump, large loss of concrete slump over time, and reduction of polycarboxylic acid Dispersion and other issues
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Embodiment 1
[0054] An embodiment of the preparation method of the high water-reducing and mud-resistant water-reducing agent of the present invention comprises the following steps:
[0055] (1) Water, 3-buten-1-amine, H 3 PO 3 Add concentrated hydrochloric acid with a mass concentration of 37% into a 500ml four-neck glass flask with a stirrer, a thermometer, and a reflux condenser, fully stir and mix, heat up to 40°C, and slowly add formaldehyde solution with a mass concentration of 37%. The dropping time is controlled at 2 hours, and then the temperature is slowly raised to 75°C, and the reaction is continued for 2.5 hours to obtain the reaction monomer B;
[0056] (2) Water, APEG-CH 2 CH 2 NH 2 、H 3 PO 3 Add concentrated hydrochloric acid with a mass concentration of 37% into a 500ml four-necked glass flask equipped with a stirrer, a thermometer, and a reflux condenser, fully stir and mix, heat up to 40°C, slowly add a 37% formaldehyde aqueous solution dropwise, and drop The addi...
Embodiment 2
[0065] An embodiment of the preparation method of the high water-reducing and mud-resistant water-reducing agent of the present invention comprises the following steps:
[0066] (1) Water, 3-buten-1-amine, H 3 PO 3 Add concentrated hydrochloric acid with a mass concentration of 37% into a 500ml four-necked glass flask with a stirrer, a thermometer, and a reflux condenser, fully stir and mix, heat up to 45°C, and slowly add formaldehyde solution with a mass concentration of 37%. The dropping time is controlled at 1.5h, then the temperature is slowly raised to 85°C, and the reaction is continued for 1.5h to obtain the reaction monomer B;
[0067] (2) Water, HPEG-CH 2 CH 2 NH 2 、H 3 PO 3 Add concentrated hydrochloric acid with a mass concentration of 37% into a 500ml four-necked glass flask equipped with a stirrer, a thermometer, and a reflux condenser, fully stir and mix, heat up to 45°C, and slowly add formaldehyde solution with a mass concentration of 37%. The addition ...
Embodiment 3
[0076] An embodiment of the preparation method of the high water-reducing and mud-resistant water-reducing agent of the present invention comprises the following steps:
[0077] (1) Water, 3-buten-1-amine, H 3 PO 3 Add concentrated hydrochloric acid with a mass concentration of 37% into a 500ml four-necked glass flask with a stirrer, a thermometer, and a reflux condenser, fully stir and mix, heat up to 42°C, and slowly add formaldehyde solution with a mass concentration of 37%. The dropping time is controlled at 2 hours, and then the temperature is slowly raised to 80°C, and the reaction is continued for 2 hours to obtain the reaction monomer B;
[0078] (2) Water, TPEG-CH 2 CH 2 NH 2 、H 3 PO 3 Add concentrated hydrochloric acid with a mass concentration of 37% into a 500ml four-necked glass flask equipped with a stirrer, a thermometer, and a reflux condenser, fully stir and mix, heat up to 43°C, slowly add a 37% formaldehyde aqueous solution dropwise, drop The addition t...
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