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Heat conduction graphene slurry and preparation method thereof

A graphene and graphene aerogel technology, applied in epoxy resin coatings, polyurea/polyurethane coatings, coatings, etc., can solve the problems of weakening the heat dissipation performance of graphene, difficult sintering process, and unsuitable for high temperature processing. , to achieve the effect of improved flexibility, low temperature conditions and easy construction

Active Publication Date: 2018-07-20
山东利特纳米新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this scheme uses high-temperature burning to combine the upper group of silane with the substrate. The combination of silane coupling agent and graphene will weaken the heat dissipation performance of graphene, and the cost and energy consumption of high-temperature sintering are relatively high. In addition, the silane coupling agent belongs to Silicone is prone to cracking under high temperature baking, which makes the sintering process more difficult
As for the sealing material of electronic equipment, it is not suitable for high-temperature processing because it needs to be bonded with electronic devices such as batteries. Therefore, it is urgent to develop a graphene thermally conductive paste suitable for sealing applications of precision and miniature electronic equipment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] The graphene thermally conductive slurry of the present embodiment includes the following components and parts by weight thereof: 1 part of graphene, 0.5 part of graphene airgel anti-settling agent, 0.5 part of binder polyvinylidene fluoride, N-methyl 98 parts of pyrrolidone, wherein, the bulk density of the graphene airgel is 0.01g / cm 3 , porosity 89%, oil absorption 300g / g, electrical conductivity 1500S / m, specific surface area 1650m 2 / g.

[0020] The preparation method of the graphene heat conduction paste described in the present embodiment, comprises the steps:

[0021] (1) Add 0.5 parts of polyvinylidene fluoride to 98 parts of N-methylpyrrolidone, stir well to make a mixed solution;

[0022] (2) Add 1 part of graphene and 0.5 part of graphene airgel to the mixture;

[0023] (3) Use a high-shear disperser to stir the mixed liquid prepared in step (2), the stirring speed is 1000r / min, and the stirring time is 1h, to obtain a stably dispersed thermally conductiv...

Embodiment 2

[0025] The graphene thermally conductive slurry of the present embodiment comprises the following components and parts by weight thereof: 10 parts of graphene, 3 parts of graphene airgel anti-settling agent, 5 parts of binder epoxy resin, N-methylpyrrolidone 82 parts, wherein, the bulk density of the graphene airgel is 0.001g / cm 3 , porosity 99%, oil absorption 600g / g, electrical conductivity 2300S / m, specific surface area 2000m 2 / g.

[0026] The preparation method of the graphene heat conduction paste described in the present embodiment, comprises the steps:

[0027] (1) Add 5 parts of epoxy resin to 82 parts of N-methylpyrrolidone, stir well to make a mixed solution;

[0028] (2) Add 10 parts of graphene and 3 parts of graphene airgel to the mixture;

[0029] (3) Use a high-shear disperser to stir the mixed liquid prepared in step (2), the stirring speed is 8000r / min, and the stirring time is 10h to obtain a stably dispersed thermally conductive slurry with a solid conte...

Embodiment 3

[0031] The graphene thermally conductive slurry of the present embodiment includes the following components and parts by weight: 6 parts of graphene, 2 parts of graphene airgel anti-settling agent, 3 parts of binder polyurethane, and 89 parts of N-methylpyrrolidone , wherein, the bulk density of the graphene airgel is 0.007g / cm 3 , porosity 93%, oil absorption 500g / g, electrical conductivity 1800S / m, specific surface area 2000m 2 / g.

[0032] The preparation method of the graphene heat conduction paste described in the present embodiment, comprises the steps:

[0033] (1) Add 3 parts of polyurethane to 89 parts of N-methylpyrrolidone, stir evenly to make a mixed solution;

[0034] (2) Add 6 parts of graphene and 2 parts of graphene airgel to the mixture;

[0035] (3) Use a high-shear disperser to stir the mixed liquid prepared in step (2), the stirring speed is 6000r / min, and the stirring time is 5h, to obtain a stably dispersed heat-conducting paste, the solid content of w...

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Abstract

The invention discloses a heat conduction graphene slurry and a preparation method thereof, and belongs to the technical field of heat conduction graphene materials. The heat conduction graphene slurry comprises graphene, a binder, N-methylpyrrolidone and a graphene aerogel anti-settling agent. The preparation method comprises the following steps: adding the binder to the N-methylpyrrolidone, uniformly stirring the binder and N-methylpyrrolidone to prepare a mixed solution, adding the graphene and graphene aerogel anti-settling agent to the mixed solution, and finally stirring the obtained mixed solution by a high shear disperser to obtain the stably-dispersed heat conduction slurry. The graphene aerogel is introduced as the anti-settling agent, and the graphene is uniformly and stably dispersed in the slurry, so the heat conduction coefficient of the slurry is remarkably improved, and the adhesion and the flexibility of the slurry are also obviously improved, and the graphene can forma continuous heat conduction network in a film formed after the solidification of the slurry in order to perform an excellent heat conduction effect. The heat conduction graphene slurry has the advantages of simple process, easiness in construction, strong adhesion and good heat dissipation effect.

Description

technical field [0001] The invention relates to the technical field of graphene heat-conducting materials, in particular to a graphene heat-conducting slurry and a preparation method thereof. Background technique [0002] With the acceleration of the upgrading of electronic products and the development of miniature, highly integrated and high-performance electronic equipment, the demand for heat dissipation management of electronic products is increasing. At present, graphite paper is used because of its high heat dissipation efficiency, small footprint, and light weight. As sealing materials for electronic equipment such as notebook computers, flat panel displays, digital cameras, and mobile phones, it is beneficial to improve the performance of electronic products. However, graphite paper is made of high-carbon phosphorus flake graphite through chemical treatment and high-temperature expansion and rolling, and the cost is relatively high. [0003] Graphene, since its disco...

Claims

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Application Information

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IPC IPC(8): C09D127/16C09D163/00C09D175/04C09D7/45C09D7/61
CPCC08K3/04C08K7/24C09D127/16C09D163/00C09D175/04
Inventor 宋肖肖郑逸群苏阳刘同浩
Owner 山东利特纳米新材料有限公司
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