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Aqueous fluororubber emulsion adhesive and preparation method thereof

A technology of rubber emulsion and water-based fluorine, which is applied in adhesives, adhesive additives, epoxy resin glue, etc., and can solve problems that have not been reported in research

Active Publication Date: 2018-07-24
哈尔滨精鑫科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] It can be seen that the research on the modification of water-based fluororubber emulsion is mainly in the field of coating, and there is no report on the research on modified fluororubber water-based emulsion adhesive.

Method used

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  • Aqueous fluororubber emulsion adhesive and preparation method thereof
  • Aqueous fluororubber emulsion adhesive and preparation method thereof
  • Aqueous fluororubber emulsion adhesive and preparation method thereof

Examples

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specific Embodiment approach 1

[0028] A water-based fluororubber emulsion adhesive. The water-based fluororubber emulsion adhesive is mainly made of water-based fluororubber emulsion, water-based epoxy resin, amine curing agent, acid absorbing agent, and emulsion film-forming aid. The parts by weight of non-volatile parts are respectively 100 parts of water-based fluororubber, 20 parts of water-based epoxy resin E-20 emulsion, 8 parts of water-based alicyclic amine curing agent EA50B, 1.5 parts of acid absorbing agent magnesium oxide aqueous dispersion, emulsion film-forming assistant Agent N,N-dimethylacetamide 4 parts.

[0029] The preparation method of a kind of water-based fluororubber emulsion adhesive described in the present embodiment comprises the following steps:

[0030] Step 1. Take a certain quality of water-based fluororubber emulsion, water-based epoxy resin, amine curing agent, acid absorbing agent, and emulsion film-forming aid respectively according to the weight and number of non-volatile...

specific Embodiment approach 2

[0044] A water-based fluororubber emulsion adhesive. The water-based fluororubber emulsion adhesive is mainly made of water-based fluororubber emulsion, water-based epoxy resin, amine curing agent, acid absorbing agent, and emulsion film-forming aid. The parts by weight of non-volatile parts are 100 parts of water-based fluororubber, 15 parts of water-based epoxy resin H220A, 8 parts of aliphatic polyamine H220B, 1 part of acid absorbent zinc oxide aqueous dispersion, and ethylene glycol butadiene as emulsion film-forming aid 2 parts ether.

[0045] The preparation method of a kind of water-based fluororubber emulsion adhesive described in the present embodiment comprises the following steps:

[0046] Step 1. Take a certain quality of water-based fluororubber emulsion, water-based epoxy resin, amine curing agent, acid absorbing agent, and emulsion film-forming aid respectively according to the weight and number of non-volatile parts, and set aside;

[0047] Step 2. Pour the w...

specific Embodiment approach 3

[0060] A water-based fluororubber emulsion adhesive, the water-based fluororubber emulsion adhesive is mainly made of water-based fluororubber emulsion, water-based epoxy resin, amine curing agent, acid absorbing agent, and its non-volatile parts by weight They are 100 parts of water-based fluororubber, 18 parts of water-based phenolic epoxy resin BH652 emulsion, 9 parts of water-based epoxy curing agent BH560, and 1.5 parts of aqueous dispersion of acid absorbing agent magnesium oxide.

[0061] The preparation method of a kind of water-based fluororubber emulsion adhesive described in the present embodiment comprises the following steps:

[0062] Step 1. Take a certain quality of water-based fluororubber emulsion, water-based epoxy resin, amine curing agent, and acid absorbing agent respectively according to the weight and number of non-volatile parts, and set aside;

[0063] Step 2. Pour the water-based fluororubber emulsion and water-based epoxy resin weighed in step 1 into...

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Abstract

The invention discloses an aqueous fluororubber emulsion adhesive and a preparation method thereof and belongs to the technical field of adhesive preparation. The aqueous fluororubber emulsion adhesive mainly comprises 95-105 parts of an aqueous fluororubber emulsion, 10-30 parts of an aqueous epoxy resin, 3-9 parts of an amine curing agent, 1-3 parts of an acid-absorbing agent and 0-5 parts of anemulsion film forming aid on the basis of the non-volatile mass. The amine curing agent is a water-soluble or water-dispersible amine curing agent. The acid-absorbing agent comprises one or more of light magnesium oxide, zinc oxide, calcium oxide, calcium hydroxide and corresponding aqueous dispersions. The emulsion film forming aid comprises one or more of ethylene glycol, ethylene glycol butylether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol butyl ether, dipropylene glycol monopropyl ether, N, N-dimethylacetamide and N-methylpyrrolidone. The aqueous fluororubber emulsion adhesive has the strength same to that of the solvent type fluororubber adhesive and VOC content of 1-4%.

Description

technical field [0001] The invention belongs to the technical field of adhesive preparation, and in particular relates to a water-based fluorine rubber emulsion adhesive and a preparation method thereof. Background technique [0002] In recent years, with people's increasingly strong requirements for environmental protection, no volatile organic compounds (VOC) or low VOC systems have become the research direction of new materials. Traditional fluororubber adhesives are made by dissolving fluororubber compound in solvents such as esters and ketones, and adding modifiers such as tackifier resins and curing agents to prepare adhesives with excellent properties such as high temperature resistance, oil resistance, and aging resistance. Adhesives and coating products, these products are widely used in the adhesion between fluorine tape, fluorine tape and anodized aluminum alloy, fluorine tape and chrome-plated steel, glass cloth and anodized aluminum alloy, high silica cloth and ...

Claims

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Application Information

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IPC IPC(8): C09J127/12C09J163/00C09J163/04C09J11/04C09J11/06C08G59/50
CPCC08G59/5006C08G59/506C08K2003/2206C08K2003/222C08K2003/2296C08L2312/00C09J11/04C09J11/06C09J127/12C08L63/00C08L63/04C08K3/22C08K5/20C08K5/06C08K5/17
Inventor 荣立平刘晓辉杨国腾李欣赵颖王刚张大勇朱金华米长虹周红霞
Owner 哈尔滨精鑫科技有限公司
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