Composite polyurethane tread rubber and preparation method thereof
A technology of composite polyurethane and tread rubber, which is applied to special tires, tire parts, transportation and packaging, etc., can solve the problems of carcass deformation or tire blowout, incompatibility, under-vulcanization, etc., and improve compatibility Sex and interaction force, avoid plastic softening, overcome the effect of poor compatibility
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[0061] The preparation method of composite polyurethane tread rubber of the present invention may further comprise the steps:
[0062] (1) mixing mixing type polyurethane raw rubber, traditional rubber and metal oxide to obtain the first mixing product;
[0063] (2) kneading the first kneaded product with an unsaturated carboxylic acid to obtain a second kneaded product;
[0064] (3) mixing the second kneaded product with a plasticizer to obtain the first kneaded rubber;
[0065] (4) mixing the first rubber compound, the peroxide and a crosslinking assistant to obtain the second rubber compound;
[0066] (5) The second mixed rubber is vulcanized and molded to obtain a composite polyurethane tread rubber.
[0067] Concrete, the preparation method of composite polyurethane tread rubber comprises the steps:
[0068] (1) Add mixing type polyurethane raw rubber and traditional rubber into the internal mixer, pressurize, masticate, then add metal oxides into the internal mixer, p...
Embodiment 1
[0083] The present embodiment provides specific implementation, and the preparation method is as follows:
[0084] Formula: 90 parts by weight of polyether type mixing polyurethane raw rubber, 10 parts by weight of natural rubber, 15 parts by weight of zinc oxide, 20 parts by weight of methacrylic acid, 15 parts by weight of DBP as a plasticizer, and 15 parts by weight of peroxide The compound DBPH is 1.2 parts by weight, and the co-crosslinking agent is 1 part by weight of Taic.
[0085] (1) Internal mixing: Add 90 parts of polyether-type mixing polyurethane raw rubber and 10 parts of natural rubber into the internal mixer, and pressurize and masticate for 2 minutes; add 15 parts of zinc oxide into the internal mixer, pressurize Mixing for 2 minutes; during this mixing process, the temperature of the internal mixer is controlled at 60°C through the water cooling system; the temperature of the internal mixer is raised to 80°C, and 20 parts of methacrylic acid are added, and mi...
Embodiment 2
[0091] The present embodiment provides specific implementation, and the preparation method is as follows:
[0092] Formula: 90 parts by weight of polyether type mixing polyurethane raw rubber, 10 parts by weight of nitrile rubber, 10 parts by weight of magnesium oxide, 20 parts by weight of methacrylic acid, 15 parts by weight of plasticizer DOP, peroxide The odorless DCP is 1.2 parts by weight, and the auxiliary crosslinking agent Taic is 1 part by weight.
[0093] (1) Internal mixing: Add 90 parts of polyether-type mixing polyurethane raw rubber and 10 parts of nitrile rubber into the internal mixer, and pressurize and masticate for 2 minutes; add 10 parts of magnesium oxide into the internal mixer, pressurize Mixing for 2 minutes; during this mixing process, the temperature of the internal mixer is controlled at 60°C through the water cooling system; the temperature of the internal mixer is raised to 80°C, and 20 parts of methacrylic acid are added, and mixed for 8 minutes....
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