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Composite polyethylene film containing chitosan and production method of composite polyethylene film

A polyethylene film and chitosan technology, which is applied in the field of packaging materials, can solve the problems that the composite structure packaging cannot be well realized, the composite film cannot play a bacteriostatic effect, and the contents are rotted, etc. The effect of improving elongation, good antibacterial performance and stable structure

Inactive Publication Date: 2018-08-17
汕头市汇诚包装材料实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In addition, due to the rich nutrients in food or facial masks, under improper storage conditions, the contents have potential microbial growth, resulting in the risk of spoilage of the contents. The use of antibacterial materials can help reduce such risks, such as the use of chitosan Sugar is used as a biological antibacterial material to improve its antibacterial ability; chitosan is used to enhance the antibacterial ability of polyethylene film, which is usually achieved by coating chitosan solution on polyethylene film. And the specifications have high requirements. In order to meet the coating fastness, it is usually coated on the corona treated surface of the polyethylene film. Because the coated chitosan layer is in the middle of the two films, the composite film as a whole cannot play a very good role. good antibacterial effect
Moreover, the composite film prepared by this method has relatively large limitations in heat resistance and heat sealing performance, and is not suitable for sealing bags, boiling water or steam heat sterilization as airtight packaging, and can only meet simple packaging of single-layer fruits and vegetables. , complex composite structure packaging cannot be well realized

Method used

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  • Composite polyethylene film containing chitosan and production method of composite polyethylene film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] (1) Preparation of corona layer: add linear low density polyethylene with a mass fraction of 49%, 50% low density polyethylene, and 1% fluorine-containing resin into a mixer and stir evenly, and proceed at a melting temperature of 165~180°C Blending and extruding to form a corona layer molten material, and then the corona layer molten material enters the co-extrusion die head to co-extrude with the middle layer molten material and the inner layer molten material from other extruders;

[0029](2) Preparation of the middle layer: Add 49% linear low-density polyethylene, 50% low-density polyethylene, and 1% silicone into a mixer and stir evenly, and blend at a melting temperature of 165~180°C Extrude to form the middle layer molten material, which then enters the co-extrusion die and co-extrudes with the corona layer molten material and inner layer molten material from other extruders;

[0030] (3) Preparation of inner layer: 26% metallocene linear low density polyethylene...

Embodiment 2

[0033] (1) Preparation of corona layer: add linear low density polyethylene with a mass fraction of 49%, 50% low density polyethylene, and 1% fluorine-containing resin into a mixer and stir evenly, and proceed at a melting temperature of 165~180°C Blending and extruding to form a corona layer molten material, and then the corona layer molten material enters the co-extrusion die head to co-extrude with the middle layer molten material and the inner layer molten material from other extruders;

[0034] (2) Preparation of the middle layer: add 80% ethylene-butylene copolymerized linear low-density polyethylene, 19% low-density polyethylene, 0.5% silicone, and 0.5% fluorine-containing resin into a mixer and stir evenly, and Blending and extrusion is carried out at a melting temperature of 165~180°C to form a middle layer molten material, and then the middle layer molten material enters the co-extrusion die head together with the corona layer molten material and the inner layer molte...

Embodiment 3

[0039] (1) Preparation of corona layer: add linear low density polyethylene with a mass fraction of 49%, 50% low density polyethylene, and 1% fluorine-containing resin into a mixer and stir evenly, and proceed at a melting temperature of 165~180°C Blending and extruding to form a corona layer molten material, and then the corona layer molten material enters the co-extrusion die head to co-extrude with the middle layer molten material and the inner layer molten material from other extruders;

[0040] (2) Preparation of the middle layer: add 80% ethylene-butylene copolymerized linear low-density polyethylene, 19% low-density polyethylene, 0.5% silicone, and 0.5% fluorine-containing resin into a mixer and stir evenly, and Blending and extrusion is carried out at a melting temperature of 165~180°C to form a middle layer molten material, and then the middle layer molten material enters the co-extrusion die head together with the corona layer molten material and the inner layer molte...

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Abstract

The invention relates to the field of packaging materials, in particular to a composite polyethylene film containing chitosan and a production method of the composite polyethylene film. The compositepolyethylene film is characterized in that each of the corona layer and the middle layer of the composite polyethylene film is the co-mixture of linear low-density polyethylene, low-density polyethylene and processing aid, the inner layer of the composite polyethylene film is a co-mixture formed by, by mass percentage, 26-48% of metallocene linear low-density polyethylene, 40-62% of linear low-density polyethylene, 9-17% of low-density polyethylene, 2-3% of modified chitosan powder, 0.03-0.1% of slip agent, 0.1-0.5% of inorganic anti-sticking agent, 0.3-1% of talcum powder master batch and 0.3-1% of processing auxiliaries, and submicroscopic composition is formed between the adhering faces of optional two of the corona layer, the middle layer and the inner layer of the composite polyethylene film. The composite polyethylene film is good in antibacterial ability, high in tensile strength, high in elongation at break, high in heat sealing strength, excellent in impact resistance and suitable for being used as double-edge and three-edge packages or box sealing film layers.

Description

Technical field [0001] The invention relates to the field of packaging materials, and in particular to a composite polyethylene film containing chitosan and a manufacturing method thereof. Background technique [0002] In some preservation technologies that need to ensure the freshness of the contents, it is often necessary to seal the sealed packaging with boiling or steam heat sterilization, such as ordinary or modified atmosphere packaging food packaging boxes, bilateral packaging of facial masks, The three-side sealed packaging bags are heat sterilized to maintain the commercial sterility of the contents. Generally, during the thermal sterilization process, it is necessary to avoid the deformation of the film caused by thermal expansion of the packaging contents, and it is necessary to ensure that the film itself and the packaging box body of other materials, as well as the joint surface between the two film bodies, maintain sufficient adhesion. The sealing strength is ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/32B32B27/06B32B27/18B32B33/00C08L23/08C08L23/06C08L27/12C08L5/08C08L83/04B29C47/06B29C47/56B29C47/92B29C69/02B29L7/00B29C48/92
CPCB29C48/0018B29C48/08B29C48/18B29C48/49B29C48/92B29C2948/92704B29L2007/00B32B27/08B32B27/18B32B27/32B32B33/00B32B2307/7145B32B2439/40B32B2439/70C08L23/06C08L23/0815C08L2203/16C08L2205/025C08L2205/03C08L2205/035C08L2207/066C08L27/12C08L5/08C08L83/04
Inventor 刘雁飞
Owner 汕头市汇诚包装材料实业有限公司
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