Silk-based mask material with high adsorption and formaldehyde decomposing ability and preparation method thereof
A strong adsorption and silk technology, which is applied in the separation of raw materials, pulp beating methods, textiles and papermaking, etc., can solve the problems of rare reports, and achieve the effect of facilitating adsorption, improving dispersion performance, and improving compatibility
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Embodiment 1
[0025] (1) After fresh banana peel is cut into pieces, put in water and boil for 5 minutes, add sodium hydroxide, make the concentration of sodium hydroxide in the water bath be 10%, continue the constant temperature water bath treatment at 70 DEG C for 60 minutes, filter to obtain the filter residue, and The filter residue was etherified to obtain banana peel carboxymethyl cellulose with a purity of 85%.
[0026] (2) Add banana peel-based carboxymethyl cellulose into the silk protein solution, mix well, grind for 5 minutes in an ice bath at -5°C, and slowly add chloroform and acetic acid at a volume ratio of 2:3:1 In the acidic solution containing chloroform of ethyl ester and acetic acid, solidify into a spherical shape, take it out, fully wash it, and freeze-dry it to obtain silk protein / cellulose airgel particles;
[0027] (3) After the silk is degummed, cut it to a length of 0.1 cm, add deionized water to form a 0.5% short silk fiber solution, decompose and beat, add silk...
Embodiment 2
[0029] (1) After fresh banana peel is cut into pieces, it is placed in water and boiled for 5 minutes, sodium hydroxide is added to make the concentration of sodium hydroxide in the water bath 20%, and the constant temperature water bath treatment is continued at 80° C. for 90 minutes, and the filter residue is obtained by filtration. The filter residue is etherified to obtain banana peel-based carboxymethyl cellulose with a purity of 90%.
[0030] (2) Add banana peel-based carboxymethyl cellulose to the silk protein solution, mix well, grind for 10 minutes in an ice bath at 0°C, and slowly add chloroform and ethyl acetate at a volume ratio of 3:4:1 In the acidic solution containing chloroform of ester and acetic acid, solidify into a spherical shape, take it out, fully wash, and freeze-dry to obtain silk protein / cellulose airgel particles;
[0031](3) After degumming the silk, cut it to a length of 5 cm, add deionized water to form a 0.6% short silk fiber solution, disperse a...
Embodiment 3
[0033] (1) After fresh banana peel is cut into pieces, put in water and boil for 5 minutes, add sodium hydroxide, make the concentration of sodium hydroxide in the water bath be 15%, continue constant temperature water bath treatment at 75 ° C for 75 minutes, filter to obtain filter residue, and The filter residue was etherified to obtain banana peel carboxymethyl cellulose with a purity of 88%.
[0034] (2) Add banana peel-based carboxymethyl cellulose to the silk protein solution, mix well, grind for 6 minutes in an ice bath at -2°C, and slowly add chloroform and acetic acid at a volume ratio of 3:3:1 In the acidic solution containing chloroform of ethyl ester and acetic acid, solidify into a spherical shape, take it out, fully wash it, and freeze-dry it to obtain silk protein / cellulose airgel particles;
[0035] (3) After the silk is degummed, cut it to a length of 1 cm, add deionized water to form a 0.52% short silk fiber solution, disperse and beat, and add silk protein / c...
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Abstract
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