Modified graphene/polybutene composite masterbatch material and its preparation method and application

A technology of graphene and polybutene, which is applied in the field of modified graphene/polybutene composite masterbatch materials and its preparation, can solve the problem of affecting heating efficiency and comprehensive utilization of heat energy, limiting the performance of thermally conductive materials, and general mechanical properties and other problems, to achieve the effect of solving the low comprehensive utilization rate of heat energy, solving the low heating efficiency, and easy to disperse evenly

Active Publication Date: 2021-04-27
GUANGZHOU SPECIAL PRESSURE EQUIP INSPECTION & RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although polybutene has so many excellent properties, it also has many shortcomings, such as its soft material and general mechanical properties. Compared with PP-R and cross-linked polyethylene, polybutene pipes have low thermal conductivity, which limits its use as The use performance of heat-conducting materials, when used as heating pipes, directly affects heating efficiency and comprehensive utilization of heat energy

Method used

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  • Modified graphene/polybutene composite masterbatch material and its preparation method and application
  • Modified graphene/polybutene composite masterbatch material and its preparation method and application
  • Modified graphene/polybutene composite masterbatch material and its preparation method and application

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Embodiment 1

[0033] This embodiment provides 6 different modified graphene / polybutene composite masterbatch materials 1-6, which are prepared from the following raw materials in parts by weight.

[0034] Table 1

[0035]

[0036] Wherein, the composition and preparation method of the master batch material 4 and the master batch material 1 are basically the same, the only difference is that the raw material of the material 4 does not contain a nucleating agent.

[0037] The nucleating agent is dibenzylidene sorbitol, bis(p-methylbenzylidene) sorbitol, 2,2,- dimethylene bis(4,6-tert-butylphenol) phosphonate and its derivatives One of them, mixed with one of the diamide compounds, the preferred ratio of the two is (2-5:1), the structural formula of N,N'-bis(phenyl)glutaramide in the above embodiment is:

[0038]

[0039] In other embodiments, the diamide compound can also be selected from the general formula: R 1 -NH-C(O)-R-C(O)-NH-R 1 diamides.

[0040] The preparation method of de...

Embodiment 2-4、 comparative example 1-3

[0053] This embodiment provides the application of 6 kinds of modified graphene / polybutene composite masterbatch materials described in embodiment 1 in polybutene pipes.

[0054] After getting the modified graphene / polybutene composite masterbatch material described in Example 2-4 and Comparative Example 1-3 and pipe grade polybutene resin to stir evenly, join in the plastic pipe extruder and make polybutene vinyl composite pipe. The concrete components of embodiment 2-4 and comparative example 1-3 are as shown in table 3:

[0055] Table 3 Polybutylene Composite Pipe Components

[0056] Modified graphene / polybutene composite masterbatch material Pipe Grade Polybutene Resin Example 2 Masterbatch material 1-----5 parts by weight 100 parts by weight Example 3 Masterbatch material 2-----1 parts by weight 100 parts by weight Example 4 Masterbatch material 3-----100 parts by weight 100 parts by weight Comparative example 1 Masterbatch ...

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Abstract

A modified graphene / polybutene composite masterbatch material according to the present invention is characterized in that it is prepared from the following raw materials: 0.1-40 parts of modified graphene; 80-120 parts of polybutene resin; 0.1-1.1 parts of agent; 0.2-1.2 parts of nucleating agent; 0.1-1.2 parts of dispersant. The composite material is applied to polybutene pipes, and polybutene pipes are prepared by simply adding modified composite material components, which can greatly improve the mechanical properties of polybutene pipes and make them have higher thermal conductivity It solves the problems of low heating efficiency and low comprehensive utilization rate of heat energy when polybutene pipes are used as heating pipes.

Description

technical field [0001] The invention belongs to the field of plastic pipes, in particular to a modified graphene / polybutene composite masterbatch material and its preparation method and application. Background technique [0002] Polybutene is a semi-crystalline polyolefin polymer with a linear molecular structure synthesized from 1-butene as a raw material under the action of a catalyst. It has excellent characteristics such as non-toxic and tasteless, acid and alkali resistance, solvent resistance, high and low temperature resistance, and compatibility with other high molecular polymers. It is also known as "plastic gold" because of its high price. In view of so many excellent properties of polybutene, it is widely used in piping materials for heating systems and hot water, drainage pipes, seals, compression packaging films and wires and cables for underground mining, etc. Although polybutene has so many excellent properties, it also has many shortcomings, such as its soft...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/20C08K9/06C08K9/04C08K3/04C08J3/22
CPCC08J3/226C08J2323/20C08K9/04C08K9/06C08K3/042
Inventor 黄国家李茂东杨波杨麟尹宗杰辛明亮
Owner GUANGZHOU SPECIAL PRESSURE EQUIP INSPECTION & RES INST
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