Method for preparing amorphous/amorphous nano multilayer film with improved plasticity

A nano-multi-layer, amorphous layer technology, applied in the direction of coating, superimposed layer plating, metal material coating technology, etc., can solve the problem of reducing the essential characteristics of amorphous alloys, the shear transition zone is not easy to aggregate, and the shear band Difficult nucleation and other problems, to achieve the effect of easy implementation, simple operation, and improved plasticity

Active Publication Date: 2018-09-28
苏州博志金钻科技有限责任公司
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Problems solved by technology

[0004] The existing methods to overcome the brittleness of amorphous alloys mainly include: (1) Using the size effect of amorphous alloys to reduce the sample size below a certain critical size, at this time, it is difficult to nucleate the shear band and the shear transition zone is difficult Gather into shear bands and show uniform plastic deformation, but this method generally needs to reduce the sample size to below 100 nanometers, so it is difficult to achieve
(2) Amorphous / crystalline multilayer film, the crystal can hinder the expansion of the shear band and make it shift to improve the plasticity of the amorphous alloy, but this method significantly reduces the essential properties of the amorphous alloy (such as long-range sequence)

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  • Method for preparing amorphous/amorphous nano multilayer film with improved plasticity
  • Method for preparing amorphous/amorphous nano multilayer film with improved plasticity
  • Method for preparing amorphous/amorphous nano multilayer film with improved plasticity

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Embodiment Construction

[0027] A kind of method of the present invention prepares the amorphous / amorphous nanometer multi-layer thin film that plasticity improves, is in magnetron sputtering process, adopts slow rate deposition process, changes Ni by controlling sputtering time 50 Nb 50 layer and Zr 61 Cu 17.5 Ni 10 Al 7.5 Si 4 The thickness of the single layer of the layer, the Ni 50 Nb 50 / Zr 61 Cu 17.5 Ni 10 Al 7.5 Si 4 multilayer film. The plasticity of a multilayer film with a single layer thickness of 5 nanometers prepared by this process is significantly improved compared with two single-layer films. It specifically includes the following steps:

[0028] 1) The single-sided polished single-crystal silicon substrate is ultrasonically cleaned with alcohol and acetone respectively, and after being blown dry by a hair dryer, it is placed on the substrate table of an ultra-high vacuum magnetron sputtering device to prepare for coating; in the best embodiment of the present invention I...

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Abstract

The invention discloses a method for preparing an amorphous/amorphous nano multilayer film with improved plasticity. According to the method, a first amorphous layer is deposited by adopting a magnetron sputtering method, then a second amorphous layer is deposited on the first amorphous layer, and alternate depositing is carried out so as to form the amorphous/amorphous nano multi-layer film. Themethod has the advantages that the prepared multi-layer film is clear in interface, the multi-layer film with improved plasticity can be easily obtained by controlling the thickness of a single-layerfilm body, and therefore the possibility can be provided for preparing an amorphous/amorphous nano multi-layer film material with controllable mechanical property.

Description

technical field [0001] The invention belongs to the technical field of nanometer metal thin film materials, in particular to a method for preparing amorphous / amorphous nanometer multilayer thin films. Background technique [0002] Amorphous alloy, also known as metallic glass, is a new type of amorphous material synthesized by modern rapid solidification metallurgy technology and has the excellent properties of general metal and glass. The essential properties of materials are determined by the atomic structure and chemical bonds. Metallic glass is mainly composed of metal elements and metal bonds while maintaining a long-range disordered amorphous structure. This combination of "metal" and "glass" endows metallic glass with other materials Excellent properties that cannot be possessed, such as good toughness, opacity, etc. In addition, in a sense, the amorphous structure is defect-free and does not contain structural defects such as dislocations, twins and grain boundaries...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/16C23C14/35C23C28/02
CPCC23C14/165C23C14/352C23C28/021C23C28/026C23C28/40
Inventor 王飞李佳乐黄平
Owner 苏州博志金钻科技有限责任公司
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