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High salinity wastewater treatment method and treatment system

A technology for high-salt wastewater and a treatment method, applied in the field of water treatment, can solve the problems of increasing the operation and maintenance cost of the process system, decreasing the membrane flux of the separation membrane element, and scrapping the membrane separation element, so as to reduce the investment in fixed assets and the number of membrane modules. The effect of reducing and preventing scaling

Inactive Publication Date: 2018-10-09
CHNA ENERGY INVESTMENT CORP LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if this method is used to treat high-salt wastewater from power plants and coal chemical industries, slightly soluble inorganic salts (such as calcium sulfate, magnesium hydroxide, calcium carbonate, magnesium sulfate, etc.) will block the micropore channels of the membrane separation element, reducing the membrane flux of the separation membrane element. , and even make the membrane separation element scrapped and have to be replaced with a new separation membrane, thus increasing the operation and maintenance cost of the process system
[0008] There is no better method and system for treating high-salt wastewater from power plants and coal chemical industry in the prior art methods. Therefore, a low-cost, high-resource reuse and high-salt wastewater treatment that can prevent fouling of membrane separation elements is developed. The method and processing system have important practical significance and market application value

Method used

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  • High salinity wastewater treatment method and treatment system
  • High salinity wastewater treatment method and treatment system
  • High salinity wastewater treatment method and treatment system

Examples

Experimental program
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Effect test

Embodiment 1

[0059] combine figure 1 , This embodiment is used to illustrate the treatment method of high-salt wastewater of the present invention.

[0060] (1) 6.67T / h that 20T / h, calcium sulfate supersaturation is 150% high-salinity waste water and step (3) obtain, calcium sulfate supersaturation is 400% concentrated water after mixing as mixed influent ( Calcium sulfate supersaturation is 212%) carry out normal temperature crystallization treatment with the total flow rate of 26.67T / h, wherein, normal temperature crystallization treatment is in the polyacrylamide (purchased from Nalco Company, trade mark is 8103PLUS, the same below) in the presence of calcium sulfate crystals (outflow) and 26.67T / h, calcium sulfate supersaturation is 100% normal temperature crystallization effluent;

[0061] (2) Adopting an ultrafiltration membrane with a pore diameter of 6 μm under 0.5MPa, the normal temperature crystallization effluent with 26.67T / h and calcium sulfate supersaturation of 100% is subj...

Embodiment 2

[0064] combine figure 2 , This embodiment is used to illustrate the treatment method of high-salt wastewater of the present invention.

[0065] (1) 20T / h, calcium sulfate supersaturation be 150% high-salt waste water and the 10T / h that step (3) obtains, calcium sulfate supersaturation are 300% concentrated water after mixing as mixed influent (sulfuric acid Calcium supersaturation is 200%) carry out normal temperature crystallization treatment with the total flow rate of 30T / h, wherein, normal temperature crystallization treatment is carried out under the polyacrylamide existence of the calcium hydroxide of 6% by weight and 65ppm, obtains calcium sulfate crystal (outflow ) and 30T / h, calcium sulfate supersaturation is 100% normal temperature crystallization effluent;

[0066] (2) Using an ultrafiltration membrane with a pore size of 6 μm, the 30T / h, calcium sulfate supersaturation of 100% normal temperature crystallization effluent is subjected to ultrafiltration at 0.8MPa t...

Embodiment 3

[0069] combine image 3 , This embodiment is used to illustrate the treatment method of high-salt wastewater of the present invention.

[0070] (1) 20T / h, calcium sulfate supersaturation is 150% high-salinity waste water and the 20T / h that step (3) obtains, calcium sulfate supersaturation is 200% concentrated water after mixing as mixed influent (sulfuric acid) Calcium supersaturation is 175%) carry out normal temperature crystallization treatment with the total flow rate of 40T / h, wherein, normal temperature crystallization treatment is carried out under the polyacrylamide presence of the sodium hydroxide of 7% by weight and 80ppm, obtains calcium sulfate crystal (outflow ) and 40T / h, calcium sulfate supersaturation is 100% normal temperature crystallization effluent;

[0071] (2) Using an ultrafiltration membrane with a pore size of 6 μm, the 40T / h, calcium sulfate supersaturation of 100% normal temperature crystallization effluent is subjected to ultrafiltration at 0.6MPa ...

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Abstract

The invention relates to the field of water treatment, and discloses a high salinity wastewater treatment method and treatment system. The method includes the following steps: (1) mixing high salinitywastewater and at least a part of concentrated water after membrane concentration treatment, and carrying out normal temperature crystallization treatment on the mixed intake water to obtain sparingly soluble salts and normal temperature crystallization exit water; (2) carrying out filtering treatment on at least a part of the normal temperature crystallization exit water to obtain filtered exitwater; and (3) carrying out membrane condensation treatment on the filtered exit water which is taken as membrane condensation intake water to obtain concentrated water and product water, and returning at least a part of the concentrated water to the normal temperature crystallization treatment. The method can fully reduce water quality requirement for an upstream high salinity wastewater pretreatment unit. The changes of the upstream high salinity wastewater pretreatment unit have wider applicability, and can effectively prevent fouling of a membrane separation element and greatly reduce thefixed assets investment of a whole process system.

Description

technical field [0001] The invention relates to the field of water treatment, in particular to a treatment method and system for high-salt wastewater. Background technique [0002] Most power plants and coal chemical plants in my country use limestone wet desulfurization technology to remove SO from flue gas. 2 , the desulfurization wastewater generated during operation has become one of the most difficult wastewater to treat in coal-fired power plants due to its complex composition and many types of pollutants. At present, the chemical precipitation method (commonly known as triple box precipitation) is mainly used in China to treat desulfurization wastewater. The treated water has a high salt content, and it is easy to cause secondary pollution after direct discharge. At the same time, due to the small amount of desulfurization wastewater and high salt content, the process system for further treatment of desulfurization wastewater in power plants and coal chemical plants ...

Claims

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Application Information

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IPC IPC(8): C02F9/04C02F103/18
CPCC02F1/001C02F1/44C02F1/441C02F1/444C02F1/52C02F1/5245C02F1/56C02F5/08C02F9/00C02F2001/5218C02F2103/18
Inventor 李国涛钟振成熊日华程子洪陈权张微尘李小端霍卫东卫昶
Owner CHNA ENERGY INVESTMENT CORP LTD
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