Composition for hard mask
A composition and hard mask technology, applied in the direction of photosensitive materials for opto-mechanical devices, etc., can solve the problem of inability to ensure the etching resistance of photoresist layers or photoresist patterns, photoresist Layer or photoresist pattern consumption or increase in etching volume, etc., to achieve excellent flatness, high resolution, high photolithography process effect
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[0181] The etching resistance, solubility, and planarity of the hard mask layer or hard mask formed from the composition in Table 1 were evaluated by the evaluation method described later. The evaluation results are shown in Table 2 below.
[0182] (1) Etching resistance evaluation
[0183] Using the spin coating method, the compositions of Examples and Comparative Examples were coated on silicon wafers, and baked at 200°C for 60 seconds to form a thickness of membrane. Coat the photoresist for ArF on each formed film, after 60 seconds of baking at 110 ℃, use the exposure equipment of ASML (XT: 1450G, NA 0.93) company to expose respectively, and then use TMAH (2.38wt % aqueous solution) were developed separately to obtain a 60nm line and space pattern.
[0184] The obtained patterned coupons were further cured at 110 °C for 60 s using CHF 3 / CF 4 The mixed gas dry-etched the test piece for 20 seconds, observed the cross-section with FE-SEM, measured the etching rate, and...
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