Low-temperature cold starting operation system for proton exchange membrane fuel cell

A proton exchange membrane, fuel cell technology, applied in fuel cells, fuel cell additives, fuel cell heat exchange, etc., can solve the problems of slow start, difficult start, insufficient reaction heat to dissolve ice, etc. The effect of a short cold start time

Pending Publication Date: 2018-10-12
ZHANGJIAGANG RES INST OF HYDROGEN ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Because the water produced by the chemical reaction will remain inside the proton exchange membrane fuel cell, in the low temperature environment below the freezing point, the liquid water inside the proton exchange membrane fuel cell will freeze, and the reaction heat generated when the proton exchange membrane fuel cell starts is not enough Melt ice, which affects the start-up of the proton exchange membrane fuel cell operating system. In the harsh low temperature environment, the proton exchange membrane fuel cell operating system may have problems such as slow start, difficult start or start-up failure.

Method used

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  • Low-temperature cold starting operation system for proton exchange membrane fuel cell
  • Low-temperature cold starting operation system for proton exchange membrane fuel cell
  • Low-temperature cold starting operation system for proton exchange membrane fuel cell

Examples

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example 1

[0035] Environmental conditions: specific heat of graphite 710 J / (kg K); calorific value of hydrogen 1.4×10 8 J / kg; battery stack mass 200kg; ambient temperature -30°C; temperature after heating up 0°C; heat dissipation rate 5%.

[0036] Hydrogen consumption = (temperature after heating - ambient temperature) × specific heat of graphite × mass of battery stack ÷ calorific value of hydrogen × (1+ heat dissipation rate).

[0037]Hydrogen consumption=30×710×200÷(1.4×10 8 )×1.05=0.032kg.

example 2

[0039] Environmental conditions: ambient temperature -20°C; temperature after heating up 0°C; hydrogen consumption flow rate 0.048kg / min; graphite specific heat 710 J / (kg K); hydrogen calorific value 1.4×10 8 J / kg; battery stack mass 200kg; heat dissipation rate 5%.

[0040] Among them: the hydrogen consumption flow is determined according to the hydrogen supply capacity of the hydrogen supply system for the fuel cell system, and the working hydrogen consumption under the rated power of the fuel cell is determined, taking a 36kw fuel cell as an example.

[0041] Hydrogen consumption = (temperature after heating - ambient temperature) × specific heat of graphite × mass of battery stack ÷ calorific value of hydrogen × (1+ heat dissipation rate).

[0042] Hydrogen consumption=20×710×200÷(1.4×10 8 )×1.05=0.022kg.

[0043] Cold start time = hydrogen consumption ÷ hydrogen flow.

[0044] Cold start time=0.022÷0.048=0.46 min=28 s.

[0045] That is: from the ambient temperature -...

example 3

[0047] Environmental conditions: ambient temperature -10°C; temperature after heating up 0°C; hydrogen consumption flow rate 0.048kg / min; graphite specific heat 710 J / (kg K); hydrogen calorific value 1.4×10 8 J / kg; battery stack mass 200kg; heat dissipation rate 5%.

[0048] Among them: the hydrogen consumption flow is determined according to the hydrogen supply capacity of the hydrogen supply system for the fuel cell system, and the working hydrogen consumption under the rated power of the fuel cell is determined, taking a 36kw fuel cell as an example.

[0049] Hydrogen consumption = (temperature after heating - ambient temperature) × specific heat of graphite × mass of battery stack ÷ calorific value of hydrogen × (1+ heat dissipation rate).

[0050] Hydrogen consumption=10×710×200÷(1.4×10 8 )×1.05=0.011kg.

[0051] Cold start time = hydrogen consumption ÷ hydrogen flow.

[0052] Cold start time=0.011÷0.048=0.23 min=14 s;

[0053] That is: from the ambient temperature -...

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Abstract

The invention discloses a low-temperature cold starting operation system for a proton exchange membrane fuel cell. The system comprises: the feed end of the proton exchange membrane fuel cell is connected with an electricity generating hydrogen gas input pipe and an electricity generating air input pipe, wherein the electricity generating hydrogen gas input pipe is communicated with a hydrogen gasbottle through a hydrogen gas input header pipe, the electricity generating air input pipe is communicated with an air compressor through an air input header pipe, a refrigerant circulating pipe is arranged between the feed end and discharge end of the proton exchange membrane fuel cell, the discharge end of the proton exchange membrane fuel cell is connected with an air and waste gas pipe, a hydrogen gas circulating pipe, a condensate water discharge pipe and a heating waste gas pipe, and the proton exchange membrane fuel cell structurally comprises a pair of end plates, wherein a pluralityof monocells, which are arranged in a mutual series connection mode, and a plurality of heating units are arranged between the pair of end plates, and each heating unit is arranged between a pair of adjacent monocells. The system has the advantages that the system can be started in the condition of ultralow temperature, consumes less hydrogen gas during cold starting and is short in cold startingtime.

Description

technical field [0001] The invention relates to the technical field of proton exchange membrane fuel cells, in particular to proton exchange membrane fuel cells. Background technique [0002] Proton exchange membrane fuel cell is an electrochemical power generation device that uses hydrogen and oxygen as raw materials to electrochemically react to generate water and convert chemical energy into electrical energy at the same time. It has the characteristics of cleanness, high efficiency, energy saving and environmental protection, and high energy conversion rate. [0003] The current proton exchange membrane fuel cell operating system includes: a proton exchange membrane fuel cell. The two ends of the proton exchange membrane fuel cell are the feed end and the discharge end respectively. The power generation hydrogen input pipe of the solenoid valve, the power generation air input pipe with the power generation air solenoid valve, the power generation hydrogen input pipe is c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/04302H01M8/04492H01M8/04007H01M8/04089
CPCH01M8/04007H01M8/04089H01M8/04302H01M8/04492Y02E60/50
Inventor 倪中华严岩吕青青丁桓展郁永斌魏蔚唐健
Owner ZHANGJIAGANG RES INST OF HYDROGEN ENERGY CO LTD
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