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Organic solar battery based on ultrasonic annealing process and preparation method thereof

A technology of solar cells and annealing process, which is applied in the direction of circuits, photovoltaic power generation, electrical components, etc., can solve the problems of reducing the energy conversion efficiency of devices and weak light absorption of the photoactive layer, so as to improve the energy conversion efficiency and the active layer The effect of smooth, high charge separation efficiency

Active Publication Date: 2018-10-23
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the above-mentioned problem that it is difficult to achieve better crystallization of the photoactive layer on the nanometer scale and the serious agglomeration of electron acceptors causes weak light absorption of the photoactive layer and reduces the energy conversion efficiency of the device. Propose an organic solar cell based on ultrasonic annealing process and its preparation method

Method used

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  • Organic solar battery based on ultrasonic annealing process and preparation method thereof
  • Organic solar battery based on ultrasonic annealing process and preparation method thereof
  • Organic solar battery based on ultrasonic annealing process and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0042] like Figure 1-3 As shown, make the control device A:

[0043] The device structure is: ITO, ZnO(30nm), P3HT:(tbt)2Ir(acac):PC71BM(100nm), MoO3(15nm), Ag(100nm);

[0044] The specific preparation is as follows:

[0045] Step 1: Clean the ITO glass substrate layer 1:

[0046] Step 1.1: Set the parameters of the ultrasonic instrument: temperature 30°C, time 15min, power 70w;

[0047] Step 1.2: Wipe the surface of the ITO glass substrate layer 1 with a dust-free cloth dipped in acetone until no particles are observed with the naked eye;

[0048] Step 1.3: Place the scrubbed ITO glass substrate layer 1 on a polytetrafluoroethylene substrate holder, and then put it into a beaker of deionized water with detergent for the first step of ultrasonic cleaning;

[0049] Step 1.4: Take out the substrate holder, rinse it with acetone and put it into a beaker filled with acetone for the second step of cleaning;

[0050]Step 1.5: The third step of ultrasonic cleaning the ITO glass...

Embodiment 2

[0061] like Figure 1-3 As shown, make device B:

[0062] The device structure is: ITO, ZnO (30nm), P3HT: (tbt) 2 Ir(acac):PC 71 BM (100nm), MoO 3 (15nm), Ag(100nm);

[0063] The preparation process is:

[0064] Step 1: Clean the ITO glass substrate layer 1:

[0065] Step 1.1: Set the parameters of the ultrasonic instrument: temperature 30°C, time 15min, power 70w;

[0066] Step 1.2: Wipe the surface of the ITO glass substrate layer 1 with a dust-free cloth dipped in acetone until no particles are observed with the naked eye;

[0067] Step 1.3: Place the scrubbed ITO glass substrate layer 1 on a polytetrafluoroethylene substrate holder, and then put it into a beaker of deionized water with detergent for the first step of ultrasonic cleaning;

[0068] Step 1.4: Take out the substrate holder, rinse it with acetone and put it into a beaker filled with acetone for the second step of cleaning;

[0069] Step 1.5 carries out the third step ultrasonic cleaning to the ITO glass...

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Abstract

The invention discloses an organic solar battery based on an ultrasonic annealing process. The battery based on n inverted structure is composed of a substrate layer, a transparent conductive cathodeITO, a cathode buffer layer, a photoactive layer, an anode buffer layer, and a metal anode that are arranged successively from bottom to top. The weight percentage of an electron donor to an electronacceptor to a phosphor small molecule material is 1 to 1 to 0.03. The phosphor small molecule material is (tbt)2Ir(acac), so that the energy level matching and energy transmission of the active layerare realized well. In addition, the preparation method employs the ultrasonic annealing process, so that the active layer materials are separated further, agglomeration is reduced, and the active layer becomes smooth. Meanwhile, the material separation has a tendency by the ultrasonic wave sent out by a single side and an ordered microstructure is formed, so that the higher charge separation efficiency and improved charge balancing are realized and thus the energy conversion efficiency of the device is improved.

Description

technical field [0001] The invention belongs to the field of organic polymer photovoltaic devices or organic semiconductor thin-film solar cells, and in particular relates to an organic solar cell based on an ultrasonic annealing process and a preparation method thereof. Background technique [0002] The energy issue has always been the biggest hot issue in the world. The development of the world and the progress of mankind are inseparable from energy. However, the rapid development of industry in today's world and the increasing demand for energy in human civilization have made countries all over the world increasingly dependent on energy, making the development of the earth's available resources and the search for innovative new renewable energy sources the top priority of the human century. . Renewable energy solar energy has been widely concerned, because solar energy itself is harmless, clean, inexhaustible, inexhaustible and so on. Studying solar photovoltaic power g...

Claims

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Application Information

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IPC IPC(8): H01L51/42H01L51/48
CPCH10K71/40H10K30/30Y02E10/549
Inventor 钟建冯耕李沁雪袁莹颖胥靖何伊玫
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA