The invention relates to natural colloid compounded hydrogel and a preparation method and application thereof. The preparation method comprises the following steps: firstly, taking polyvinyl alcohol and nano colloid concentrated and extracted from seawater, adding water, stirring at 70-75 DEG C to obtain a dispersion initial solution, then adding MoS2 nanoflowers prepared by a hydrothermal synthesis method according to a solid-liquid ratio of 1: 1mg/ml, continuously stirring at 70-75 DEG C to obtain a uniform black dispersion liquid, adding hydrochloric acid, stirring, standing at room temperature, standing in a drying oven for 4 hours, so that the reaction is balanced, finally, freezing the jelly after standing in a refrigerator overnight, taking out the frozen jelly, unfreezing the frozen jelly to normal temperature, freezing the frozen jelly in the refrigerator, repeatedly freezing the frozen jelly for several times, soaking the frozen jelly in deionized water, and washing the frozen jelly to obtain a black opaque gel substance. According to the invention, the hydrogel prepared by graft polymerization by taking polyvinyl alcohol/natural nano colloid/MoS2 as a main raw material is obtained for the first time, and the hydrogel is used as a solar absorber for solar seawater desalination, so that an efficient seawater desalination yield can be obtained.