Development and application of a class of hole-transporting polymer materials based on carbazole-anthracene structure

A polymer material and hole transport technology, applied in the field of organic electronics, can solve the problems of low carrier mobility, difficult energy level adjustment, poor stability, etc., and achieve high carrier mobility, good Solution processability, good stability effect

Active Publication Date: 2019-06-14
南京和颂材料科技有限公司
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

[0004] Technical problem to be solved: In view of the shortcomings of existing hole transport materials such as poor stability, poor solubility, low carrier mobility, and difficult adjustment of energy levels, the present invention designs a class of hole transport materials based on the carbazole-anthracene structure. Polymer material, which has the advantages of good stability, good solubility, high carrier mobility, and easy regulation of energy levels

Method used

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  • Development and application of a class of hole-transporting polymer materials based on carbazole-anthracene structure
  • Development and application of a class of hole-transporting polymer materials based on carbazole-anthracene structure
  • Development and application of a class of hole-transporting polymer materials based on carbazole-anthracene structure

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example 1

[0038] (1) Synthesis of monomer M1

[0039]

[0040] 4,4'-Dibromo-2-nitro-1,1'-biphenyl (1)

[0041] Dissolve 4,4'-dibromo-1,1'-biphenyl (10.00g, 32.00mmol) in acetic acid (300ml), slowly add HNO at 100°C 3 Mixture with water (7.5ml). After heating at 100°C for 30 minutes, the initially formed precipitate dissolved. After the reaction, the solution was cooled, and a yellow powder was obtained after filtration. Recrystallization in ethanol gave the title product (9.30 g, 81%). 1 H NMR (400MHz, CDCl 3 ): δ8.03(d, J=1.3Hz, 1H), 7.75(m, 1H), 7.56(d, J=7.9Hz, 2H), 7.28(m, 1H), 7.16(d, J=7.9Hz , 2H).

[0042] 2,7-Dibromo-9H-carbazole (2)

[0043] 1 (10.00g, 28.00mmol) and triethyl phosphate (50ml) was heated to reflux for 18 hours, the excess triethyl phosphate was distilled off, and the product was purified by column chromatography (eluent: ethyl acetate: n-hexane = 5:95), the target product (4.66 g, 87%) was obtained. 1 H NMR (400MHz, CDCl 3 ): δ8.03 (s, 1H), 7.87 (d,...

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Abstract

The present invention develops a class of hole-transporting polymer materials based on carbazole-anthracene structure: its chemical structural formula is: wherein the value of n is 1-100; A is a unit with a π-conjugated structure, selected from one of the following units Species: R1 is one of the following groups: R2 is one of the following groups: The hole transport polymer material developed by the present invention has good stability, good solubility, high carrier mobility, Compared with the traditional hole transport material PEDOT:PSS in perovskite solar cells, the advantages of easy regulation and control of energy levels show obvious advantages, showing that it can be used in organic light-emitting diodes, organic thin-film transistors, organic solar cells, organic storage and other organic electronics fields. Potential and broad application prospects.

Description

technical field [0001] The invention relates to the field of organic electronics, in particular to the development of a class of hole-transporting polymer materials based on a carbazole-anthracene structure and its application in the field of organic electronics. Background technique [0002] In the development of organic electronics, the use of organic materials instead of traditional semiconductor materials to prepare organic electronic devices is a huge change in the development of modern electronics industry; organic electronic devices are light in weight, low in cost, bendable, and suitable for large-area preparation, and are comparable to inorganic semiconductor devices. , has obvious advantages, and has been widely used in the fields of curved surface display, radio frequency identification, light detection, new energy acquisition and storage, etc. Organic electronic devices include organic light-emitting diodes, organic thin-film transistors, organic solar cells, org...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G61/12H01L51/46
CPCC08G61/124C08G61/126C08G2261/95C08G2261/92C08G2261/411C08G2261/90C08G2261/91C08G2261/512C08G2261/1412C08G2261/3223C08G2261/3241H10K85/113Y02E10/549
Inventor 不公告发明人
Owner 南京和颂材料科技有限公司
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