The invention discloses an application of a compound in a
solar cell, the
structural formula of the compound is (G1) n-R-(G2) m, G1 is selected from at least one of a Si-containing group, a
phosphate group, a
phosphate group, a carboxyl group, a
carboxylic ester group, a sulfonic group or an
aldehyde group; r is selected from at least one of aromatic rings or aromatic heterocyclic rings; g2 is selected from at least one of
halogen, an N-containing group, an S-containing group, an O-containing group or a P-containing group; n > = 1, m > = 1. The invention also provides a
solar cell and a preparation method thereof. The invention also provides a laminated
solar cell. According to the invention, the compound is applied to the solar
cell, the defects of the lower interface of the
perovskite absorption layer can be passivated, the interface recombination is reduced, the surface
work function of the first carrier transmission layer can be adjusted, the
energy level of the first carrier transmission layer is enabled to be better matched with the
energy level of the
perovskite absorption layer, and the transmission and collection of carriers at the interface are improved.