The application discloses a
perovskite solar cell containing a double-layer trifluoroacetate modification layer and a preparation method thereof. The
perovskite solar cell comprises, from bottom to top, a conductive glass, an
electron transport layer, an
electron transport layer modification layer, a
perovskite layer, a perovskite modification layer, a
hole transport layer and an
electrode; the
electron transport layer modification layer and the perovskite modification layer are one of
methylamine trifluoroacetate, formamidine trifluoroacetate,
dimethylamine trifluoroacetate, ethylamidine trifluoroacetate,
ethylenediamine trifluoroacetate and
guanidine trifluoroacetate. The application simultaneously fills and modifies defects of the
electron transport layer and the perovskite layer, passivates
oxygen defects in the
tin oxide and
ion vacancies in the perovskite layer through
hydrogen bonds and chemical interactions, and solves the problems of the
perovskite solar cell, such as many defects in the
electron transport layer and the perovskite layer, low efficiency and poor stability.