303 results about "Sodium benzenesulfonate" patented technology

The invention relates to a composite phosphating solution of P-Ca-V on the surface of a magnesium alloy and a method for chemical conversion treatment. The solution is characterized in that each liter of the composite phosphating solution comprises the following compositions: 4 to 20 milliliters of 85 percent phosphoric acid of, 5 to 30 grams of sodium dihydrogen phosphate, 10 to 40 grams of calcium nitrate, 0.5 to 10 grams of benzene sulfonic acid sodium salt, 0.5 to 5 grams of ammonium metavanadate, and the balance being water. The method comprises the following steps: pre-degreasing, degreasing, secondary water washing, acid washing, secondary water washing, alkaline etching, secondary water washing, chemical transformation, secondary water washing, pure water washing, and drying. Taking an AZ91D magnesium alloy as an example, 48 hours after a corrosion resistance salt spray test after the treatment by the method of the invention, the corrosion area of the AZ91D magnesium alloy is less than 1 percent; the paint film adhesive force is at 0 level by a grid method and is obviously superior to the performance of a chromate conversion coating; and the formed chemical conversion coating does not contain crystal water. The composite phosphating solution has the synergistic reaction of Ca and V, as well as the functions of a corrosion inhibitor and a wetting agent of the benzene sulfonic acid sodium salt.

A dual-component surfactant of biether biphenylsulfonate is 2.2-bis (4-alkoxy-3- sodium phenylsulfonate) propane. Its preparing process includes such steps as adding biphenol A and the aqueous solution of NaOH into reactor, reaction at 50-78 deg.C, sequentially adding absolute alcohol and long-chain alkyl bromine into reactor, reacting at 50-78 deg.C for 12-36 hr, evaporating alcohol, washing the resultant, recrystallizing, drying to obtain biether compound, adding it into reactor, using dichloromethane as solvent, dripping chlorosulfonic acid, reaction at 15-35 deg.C for 1-3 hr, neutralizing resultant, salting out, filtering and drying. Its advantages are high surface activity, and high foam stability.

The preparation process of ferric alkyl aryl sulfonate includes the following steps: reflux reaction between anhydrous ferric trichloride or ferric trichloride hexahydrate and alkyl aryl sulfonic acid in alcohol solution, eliminating solvent and hydrogen chloride gas at high temperature and low pressure to produce coarse product; washing with ethyl ether to eliminate excessive p-toluene sulfonic acid, and re-crystallizing in mixed solvent of methanol and acetonitrile to obtain purified ferric alkyl aryl sulfonate. The present invention provides also one other process for preparing ferric long chain (benzene) sulfonate. The present invention has low material cost and high product purity, and the product is used in electronic industry.

A liquid detergent consists of aliphatic alcohol polyethenoxy ether sodium sulfate 5-15 proportion, lauryl sodium benzenesulfonate 2-10 proportion, fatty acid diethanolamine 1-8 proportion, hydrogen peroxide 2-6 proportion, ammonia water 0.5-5 proportion and water 40-92 proportion. It spends 30 s-6 mins in eliminating various mechanical and edible stains, blood stain, ball-pen ink, beverage stain and tea stain. It shortens washing time to 4-8 mins and costs 0.5-0.8 yuan/kg and is economical.

The present invention provides a ceramic diaphragm comprising a diaphragm substrate having a surface coated with a polymer-coated functional ceramic powder. The polymer coating the surface of the ceramic powder is polystyrene sulfonic lithium (PSSLi) and a polyethylene glycol methacrylate hydrocarbon microporous diaphragm. The diaphragm substrate is a polyolefin microporous diaphragm. The polyethylene glycol methacrylate (PEGMA) has an average molecular weight of 400 to 5000 g/mol. The method provided by the invention comprises firstly activating the ceramic powder by using a silane coupling agent; then introducing a halogen functional group to graft the ceramic powder with a halogen initiator; adding sodium benzenesulfonate monomer (SSNa) and polyethylene glycol methacrylate (PEGMA) for apolymerization reaction; then adding the mixture to a lithium ion aqueous solution for ion exchange to obtain the polymer-coated functional ceramic powder; and finally stirring the polymer-coated functional ceramic powder to form a ceramic slurry and form the polymer-coated ceramic diaphragm by coating. The method provided by the present invention greatly improves the dispersibility and the functionality of lithium ions.

The invention discloses an aerated brick added with compound attapulgite particles. The aerated brick added with compound attapulgite particles is prepared by the following raw materials by weight: 30-40 parts of the compound attapulgite particles, 20-30 parts of fly ash, 4-6 parts of cement, 2-4 parts of shell powder, 0.1-0.3 part of sodium sulfate, 1-2 parts of hydroxypropyl methyl cellulose, 0.4-0.6 part of sodium sulfite, 0.7-0.9 part of diethylene glycol, 0.01-0.03 part of melamine, 2-4 parts of sodium chloride, 3-5 parts of calcium oxide, 0.3-0.4 part of dimethyl sodium benzenesulfonate and 0.08-0.14 part of zinc powder.

The invention discloses a high-strength aerated concrete building block produced by using electrolysis manganese residues and a preparation method thereof. The building block is made of: (1) basic raw materials, (2) additives and (3) a solvent, wherein the basic raw materials include 48-58 percent by weight of electrolysis manganese residues, 20-30 percent by weight of silica sand, 5-10 percent by weight of cement and 15-25 percent by weight of quicklime; based on the total amount of the basic raw materials, the additives include 0.05-0.12 percent by weight of aluminum powder, 1-5 percent by weight of water glass, 0.005-0.01 percent by weight of sodium benzene sulfonate washing powder and 0.1-0.4 percent of an aid; the solvent is water; and the weight ratio of water to a water material of the basic raw materials is 0.6-0.7. The preparation method comprises the following steps of: pretreating the raw materials, and forcibly stirring according to a certain proportion as required to obtain slurry; and standing and performing steam curing with a still kettle to obtain a product. The aerated concrete building block produced with the method has the advantages of low volume weight, high strength, simple process, convenience in operating, freeness from pollution, high electrolysis manganese residue consumption and convenience in mechanical production.

The invention relates to a process for synthesizing single-purpose carboxylic styrene butadiene latex for well cementing in oil and gas field by using butadiene and phenylethene as main monomer, using carboxylates or/and sulfonic acid, sulfonate containing unsaturated bond as functional monomer, and using composite emulsifying agent system. The invention realizes a C8-C20 alkyl sodium sulfate, C8-C20 sodium alkyl benzene sulphonate- non-ionic emulsifier, wherein the polymerization temperature is preferably between 50-90 deg. C.

The invention discloses a dyeing production process for a full-cotton knitted fabric. The dyeing production process comprises the following steps: (1) pretreatment, (2) neutralization, (3) deoxygenization, (4) dyeing, (5) neutralization, (6) soaping, and (7) formation, wherein the step (1) comprises the steps of adding water into a dye vat, heating to 40-50 DEG C, adding pretreatment liquid into the dye vat, uniformly stirring, carrying out temperature-maintenance treatment for 3-5 minutes, adding a gray fabric into the water in a water bath ratio of (1 to 8)-10, heating to 90-100 DEG C, and washing with clean water for 1-2 times; and the pretreatment liquid contains the following substances in parts by weight: 3-5 parts of a penetrating agent, 3-7 parts of hydrogen peroxide, 4-8 parts ofcaustic soda liquid, 4-7 parts of a degreaser, 3-8 parts of a stabilizer, 5-8 parts of tetraacetyl ethylenediamine, 2-8 parts of butyl acetate, 1-3 parts of sodium sulfate, 1-3 parts of 4-(2-nonanoyloxyethoxycarbonyloxy)sodium benzenesulfonate and 1-5 parts of tris(hydroxymethyl)methylglycine. The dyeing production process has the advantages of high dyeing rate and uniformity in dyeing.

The invention relates to a preparation method of cation dyeable POY (Polyester Pre-Oriented Yarn). The method comprises the following steps: firstly, mixing dimethyl isophthalate-5-sodium benzenesulfonate, ethylene glycol, a catalyst and an anti-ether agent, performing transesterification, and adding the ethylene glycol and a complex ion modifier for preparation after the transesterification is ended; secondly, mixing terephthalic acid, the ethylene glycol, the catalyst, a stabilizer and a delustering agent, performing esterification reaction, adding a product obtained by preparation after theesterification reaction into a reaction system already reaching a reaction endpoint of the esterification reaction, and performing condensation polymerization to obtain a spinning melt; finally, metering, extruding, cooling, oiling and winding the spinning melt to obtain the cation dyeable POY. The method reduces the generation of impurities in a production process, thereby reducing pressure riseof a spinning assembly and a filter, prolonging the service life, ensuring the continuity and safety of the whole production flow, and achieving a good economic value and promotion value.

The present invention relates to reclaiming of non-ferro metals, especially to a process for extracting high-purity Zn from casting zincilates. The casting zincilates are casted into anode sheets, pure aluminum plates are selected as cathodes, and then they are electrolyzed in electrolysing solution to obtain zincium of high-purity at the cathode plates finally, wherein per litre of said electrolysing solution contains 1-3 mol ammine, 1-3 mol ammonium chloride, 0.075-0.3 g additive agent and 40-60 g zincium ions therein, in which said additive agent in per litre electrolysing solution is a mixture composed of 0.05-0.2 g gelatine and 0.025-0.1 g sodium dodecylbenzene sulfonate. By casting the casting zincilates directly into anode sheets and adopting Zn-NH3-NH4Cl-H2O system for performing electrorefining to prepare high-purity zincium, the process is greatly shortened, the energy consumption is saved, and the cost of investment is depressed. The obtained cathode zincium has a high purity (>=99.9%) and is easy to peel off, with low intensity of labor and reduced attrition of cathode plates. The electrolysing solution my be circle-utilized, without pollutions to the environment.

The invention discloses an ultra-thin electrolytic copper foil and a preparation method thereof. The method comprises the following steps that an anode plate and a cathode roller are arranged and aresoaked in a copper electrolyte; an additive is added into the copper electrolyte and uniformly mixed; a direct current is exerted between the anode plate and the cathode roller and electrolysis is performed to prepare the copper foil on the surface of the cathode roller; and the additive comprises sodium dodecyl benzene sulfonate, sodium 3-mercaptopropanesulphonateand hydroxyethyl cellulose and collagen, and the concentration of sodium dodecyl benzene sulfonate is 20-70 mg/L, the sodium 3-mercaptopropanesulphonateand hydroxyethyl cellulose with the concentration of 30 -60 mg/L, and the concentration of the hydroxyethyl cellulose is 20-50 mg/L, the concentration of the collagen is 100-180 mg/L, and the molecular weight of the copper foil is 2000-4000. According to the preparation method, through introducing the additive with a specific ratio, crystal grains can be further refined during direct current electrolysis, and the ultra-thin copper foil with the thickness of less than 6 micronscan be prepared while ensuring that the copper foil has good tensile strength and flatness; and the process is simple and convenient, and facilitates the industrial large-scale production.

The invention discloses 4.5 micrometer electrolytic copper foil for a lithium ion battery, a preparation method and an additive. The 4.5 micrometer electrolytic copper foil is prepared from polyquaternium-10, polyquaternium-7, polyquaternium-51, dithiobis-1-propanesulfonic acid disodium salt, sodium alcohol mercaptan sulfonate, gelatin, alkaline safranine dye, N-butyl thiourea, mercaptoimidazole sodium benzenesulfonate and polyethylene glycol acetal. The 4.5 micrometer electrolytic copper foil for the lithium ion battery, the preparation method and the additive have the beneficial effects thatby means of the coupling reaction of the additive, nucleating surface energy is reduced, the growth speed of crystal nuclei is restrained, pinholes and micro-defects are removed, the nucleating quantity is increased, grains are refined, the structure of the copper coil is homogenized, and the tensile strength and the ductility are effectively improved; and industrialization of the copper foil which has the tensile strength of 35-40 kgf/mm<2> and the uniform double-face structure (Rz of the smooth and rough faces is 1.0-2.0 micrometers) and is free of defects and ultrathin (the thickness is 4.5 micrometers) is achieved, and industrialization of high-energy-density power battery copper foil products is effectively achieved.

The invention belongs to the technical field of preparation of functional nano-materials, relates to a preparation method of nano-hierarchical structure nickel hydroxide and particularly relates to a method for hydrothermal synthesis of nickel hydroxide hierarchical structure microspheres assembled by nano-sheets. The method disclosed by the invention comprises the following steps of: mixing a nickel acetate (Ni(CH3COO)2) water solution with a polyethylene sodium benzenesulfonate water solution, placing in a high-pressure reaction kettle lined with polytetrafluoroethylene to perform hydrothermal reaction, cooling, then performing centrifugal separation, washing with water, washing with ethanol, and then drying. The nickel hydroxide hierarchical structure prepared by the method disclosed by the invention is good in monodispersity and uniform in appearance, the diameter is 1.5-3mu m, and the hierarchical structure is assembled by flaky nano-units in a spiral layer-by-layer superimposition way and belongs to a multi-stage mesoscopic structure. The structure material combines larger surface area and excellent anti-agglomeration stability, and has great application prospects in the fields of battery electrode materials, catalysis, air sensitivity and the like. The method disclosed by the invention has the advantages of simple process, no need of adding a precipitating agent, convenience in operation and good repeatability, and is expected to realize industrial production.

The invention discloses an aqueous epoxy resin emulsion. The aqueous epoxy resin emulsion is prepared from, by mass, 5-10% of epoxy resin, 5-10% of diisocyanate, 2-8% of polyether polyol, 0.5-2% of dibutyltin dilaurate, 2-8% of cyclohexanedimethanol, 1-2% of propylene glycol methyl ether acetate, 2-4% of triethylamine, 1-3% of sodium benzenesulfonate, 5-10% of butanone, 1-3% of hydroxyl-terminated polyether modified organosilicon or hydroxyl-terminated fluorine-containing organic polymer and 50-60% of deionized water. Organosilicon and the fluorine-containing organic polymer are adopted to modify the epoxy resin, so the aqueous epoxy resin emulsion keeps the excellent performances of original coatings, has reduced surface tension and stable performances, and can be widely applied. The invention also discloses a preparation method of the aqueous epoxy resin emulsion, and a cathode electrophoresis coating prepared through adopting the aqueous epoxy resin emulsion.

The invention relates to a preparing method for an ordinary-pressure positive-ion dyeable polyester fiber. The preparing method includes the steps that dimethyl isophthalate-5-sodium benzenesulfonate,ethylene glycol, a catalyst and an anti-ether agent are mixed to be subjected to an ester exchange reaction, the reaction is end, then ethylene glycol and sodium ethylene glycol are added, modulationis carried out, then terephthalic acid, ethylene glycol and a catalyst are mixed, and the mixture is subjected to an esterification reaction; the modulated product after the ester exchange reaction is end and polyethylene glycol are added into an esterification reaction system reaching the end point of the esterification reaction, condensation polymerization is carried out, and spinning melt is obtained; the spinning melt is measured, extruded, cooled, subjected to oil applying, stretched, subjected to heat setting and wound, and the ordinary-pressure positive-ion dyeable polyester fiber is prepared. According to preparing method, generation of impurities in the polyester-fiber production process is reduced, pressure rising of a spinning assembly and a filter is reduced accordingly, the service cycle of the polyester fiber is prolonged, the continuity and the safety of the whole production process are guaranteed, and the preparing method has the good economic value and popularizationvalue.

The invention provides a method for synthesizing surface functional group modified carbon quantum dots and an application of the surface functional group modified carbon quantum dots in nano oil displacement, which comprises the following steps: by using anhydrous citric acid as a carbon source, carrying out a hydrothermal method to obtain a carboxyl modified carbon quantum dot solution, and purifying to obtain a carboxyl modified carbon quantum dot solid; reacting the carboxyl modified carbon quantum dots and sodium p-chloromethylbenzenesulfonate in a polytetrafluoroethylene reaction kettle for 3 h after the pH value of the solution is adjusted to be weakly alkaline, and generating sulfonic group modified carbon quantum dots; reacting the carboxyl modified carbon quantum dot with ammoniawater, and purifying to obtain an amido-modified carbon quantum dot; and reacting the amido-modified carbon quantum dot with sodium hypochlorite in an ice-water bath for 3 hours, adding NaOH to reactfor 8 hours, and purifying to obtain the surface amino-modified carbon quantum dot. The obtained surface functional groups (carboxyl, sulfo, acylamino and amino groups) are used for modifying the carbon quantum dots to carry out a rock core displacement experiment, and the oil displacement rate can be greatly improved.

The invention relates to the technical field of communication fiber coloring solidification, in particular to optical fiber coloring ink capable of being solidified by LED. The ink is characterized by being prepared from, epoxy acrylic resin or urethane acrylate, Isopropyl tri(dioctylpyrophosphate) titanate, polyacrylic acid, 3-Aminopropyltriethoxysilane, cellulose nitrate, isopropyl alcohol, 2-Isopropylthioxanthone, sodium benzenesulfonate, benzophenone, oleic acid, a compound photosensitizer, 4-Methoxyphenol, an antifoaming agent BYK088 and a flatting agent BYK344, wherein, the compound photosensitizer is obtained by uniformly mixing a photosensitizer 184, a photosensitizer 1173 and a compound photosensitizer 907 with a mass ratio of (1 to 3):1(1 to 2). The invention further discloses a preparing method of the optical fiber coloring ink capable of being solidified by LED. The optical fiber coloring ink capable of being solidified by LED has the advantages of more energy conservation, faster coloring speed, better environment protection, longer service life of a curing light of a coloring device and lower coloring noise.