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High-performance water-based two-component finish paint composition as well as preparation method and use thereof

A water-based two-component, high-performance technology, used in anti-corrosion coatings, polyurea/polyurethane coatings, coatings, etc. sagging and other issues

Inactive Publication Date: 2018-11-23
NIPPON PAINT CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] First, the latent heat of water volatilization in water-based coatings is large, which is greatly affected by air humidity, and is prone to pinholes and sags;
[0005] Second, the surface tension of water in water-based coatings is high, which has high requirements on the construction process and substrate, and shrinkage cavities are more likely to appear;
[0006] Third, for systems with high performance requirements, water-insoluble resins are generally used, resulting in the final film-forming material being heterogeneous film-forming, and the fullness and gloss are often difficult to meet high requirements
[0015] Ordinary isocyanate curing agent, because it is relatively hydrophobic, cannot be well dispersed in the water phase when it is mixed with the main paint, which will cause poor luster and plumpness of the paint film, and prone to shrinkage; The isocyanate modified by acid salt will increase the hydrophilicity, improve the reflection state of the isocyanate and the main paint in water after mixing, and it is easy to achieve a better paint film appearance. Due to the introduction of the hydrophilic structure of the curing agent, it is easy to cause paint film The water resistance and chemical resistance are reduced, and when the coating film is thicker, it is prone to pinholes

Method used

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  • High-performance water-based two-component finish paint composition as well as preparation method and use thereof
  • High-performance water-based two-component finish paint composition as well as preparation method and use thereof
  • High-performance water-based two-component finish paint composition as well as preparation method and use thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] In a container with a stirrer, add 2 parts of deionized water and add with stirring -2.5 parts of DISPERSANT-2010 dispersant, 30 parts of Neocryl XK-540 water-based acrylic resin, 0.2 parts of BYK 024 defoamer, 0.2 parts of BYK 346 silicone wetting agent, 30 parts of TIPURE R706, adjust the pH to 7.5-8.5, sanding to a fineness of ≤5 μm; add 30 parts of Neocryl XK-540 water-based acrylic resin, 0.1 part of BYK 331 silicone leveling agent, 0.7 part of BYK093 defoamer, 0.5 part of RHEOLATE 299 thickener, 0.1 part of preservative BESTCIDE-600, 3 parts of deionized water, and 0.1 part of triethanolamine to adjust the pH to 7.5-8.5. Stir well and strain through a 10 micron strainer to obtain the top coat.

[0065] Under nitrogen protection, control the water content of 45 parts of propylene glycol methyl ether acetate solvent to ≤0.05%, add 55 parts of Bayhydur XP2655 isocyanate and stir evenly to obtain a curing agent; mix and stir the topcoat and the curing agent evenly t...

Embodiment 2

[0068] In a container with a stirrer, add 5 parts of deionized water, add 4 parts of TEGO Dispers 757W dispersant, 0.5 parts of BYK 011 defoamer, 0.2 parts of BYK 346 silicone wetting agent, RAVEN 5000 carbon black 2 parts under stirring Use 0.05 parts of triethylamine to adjust the pH to 7.5-8.5, and sand to a fineness of ≤5 μm; add 75 parts of Macrynal SM 6810 water-based acrylic resin, 0.4 parts of Surfynol 440 wetting agent, and Tego Wet 280 under stirring 0.4 part of wet agent, 0.5 part of BYK 011 defoamer, 0.5 part of RHEOLATE 299 thickener, 10 parts of deionized water, adjust the pH to 7.5-8.5 with 0.1 part of triethylamine, stir well, and filter with 10 micron filter , to get the topcoat.

[0069] Under nitrogen protection, control the water content of 40 parts of 3-methoxybutyl propionate solvent to ≤0.05%, add 60 parts of Desmodur N3900 isocyanate and stir evenly to obtain a curing agent; mix and stir the topcoat and the curing agent evenly The high-performance wate...

Embodiment 3

[0072] In a container with a stirrer, add 4 parts of deionized water, add 1 part of TEGO Dispers 750W dispersant, 0.1 part of Foamstar ED2522 defoamer, 0.2 part of Tego Wet 500 wetting agent, 8 parts of BAYFERROX OXIDEYELLOW 3920 pigment under stirring , adjust the pH to 7.5-8.5 with 0.05 part of dimethylethanolamine adjustment agent, sand mill to fineness ≤ 5 μm; add 74 parts of Bayhydrol A2646 water-based acrylic resin, 0.4 part of Surfynol 440 wetting agent, and TegoWet 280 wetting agent under stirring 0.4 parts, 0.2 parts of Foamstar ST 2438 defoamer, 0.4 parts of Additol VXW6388 thickener, 3 parts of propylene glycol butyl ether, 8 parts of deionized water, adjust the pH to 7.5-8.5 with 0.1 part of dimethylethanolamine, and use a small amount of deionized Adjust the viscosity with water to pass. Stir well and strain through a 10 micron strainer to obtain the top coat.

[0073] Under the protection of nitrogen, control the water content of 25 parts of 3-methoxybutyl propi...

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PUM

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Abstract

The invention discloses a high-performance water-based two-component finish paint composition, which is prepared finish paint and a curing agent, wherein the finish paint is prepared from the following components in parts by weight: 60-75 parts of water-based hydroxyl acrylic resin, 0.3-1.1 parts of a flatting agent, 0.3-1 part of an antifoaming agent, 1-4 parts of a dispersing agent, 2-30 parts of pigment, 5-15 parts of deionized water, 0-0.5 part of a pH regulating aid and 0-11.6 parts of other additives; the curing agent is prepared from the following components in parts by weight: 55-75 parts of isocyanate, 25-45 parts of a solvent and 0-1 part of a water removal agent. The finish paint composition provided by the invention has good construction performance and paint film property, andis lower in content of volatile organic compounds (VOCs), thus being used for finish paint for buses.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a high-performance water-based two-component topcoat composition, a preparation method and an application. Background technique [0002] With the rapid development of China's economy, environmental problems have become increasingly prominent, and people's calls for environmental protection are also increasing. To this end, in recent years, local governments have successively issued environmental protection regulations to regulate VOC emissions in the coating and painting process. For the painting of vehicles such as buses and large-scale equipment, the 2K topcoats currently used are mainly solvent-based coatings. The current GB24409 standard for this type of product is VOC≤630g / L, which is ≤150g / L compared to water-based 2K topcoats. Even VOC levels ≤100g / L are too high. Therefore, in terms of reducing VOC emissions, the water-based 2K topcoat is a very good choice. [0003] ...

Claims

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Application Information

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IPC IPC(8): C09D175/04C09D5/08C09D7/20
CPCC09D5/08C09D7/20C09D175/04C08K3/04
Inventor 祁康法宋其亮
Owner NIPPON PAINT CHINA
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