Near-infrared absorbing white material and preparation method thereof
A near-infrared and white technology, which is applied in the field of near-infrared-absorbing white substances and their preparation, can solve the problems of not revealing the structural formula of substances and the like
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no. 1 example
[0111] The first embodiment - preparation of copper pyrophosphate compound
[0112] In order to synthesize a copper pyrophosphate compound with a high whiteness, the reaction is carried out in a supersaturated aqueous solution state. Pour 530 ml of water into a 1 L beaker, pour 55 g of sodium pyrophosphate anhydride into it while maintaining the temperature at 60° C., and stir and dissolve it with a mechanical stirrer. 50 ml of water was poured into another beaker, and 68 g of copper chloride dihydrate was poured and stirred to dissolve while maintaining the temperature at 60°C.
[0113] While stirring the aqueous solution in which sodium pyrophosphate anhydride was dissolved, the copper chloride aqueous solution was slowly poured in, and then the aging reaction was carried out for a certain period of time. Filter and wash the white precipitate formed after the reaction, and redisperse it in 1kg of water, keeping the temperature at 60°C.
[0114] The precipitate aqueous solu...
no. 2 example
[0116] The second embodiment - preparation of copper pyrophosphate compound
[0117] 400 ml of water was poured into a 1 L beaker, and 68 g of potassium pyrophosphate anhydride was poured while maintaining a temperature of 60° C., and stirred and dissolved using a mechanical stirrer. 250 ml of water was poured into another beaker, and 103 g of copper sulfate pentahydrate was poured in while maintaining the temperature at 60° C., and stirred to dissolve.
[0118] The following process is the same as in Example 1, the acid treatment is carried out with phosphoric acid, and the pH is maintained at 3.5. After the reaction was completed, it was filtered, washed, and dried, and heat-treated at 750° C. to realize crystallization.
no. 3 example
[0119] The third embodiment - preparation of copper pyrophosphate compound
[0120] The copper pyrophosphate compound was synthesized by a general method, and it was used to compare the whiteness of the first embodiment and the second embodiment reacted in a supersaturated aqueous solution state. Pour 1000ml of water into a 2L beaker and pour 55g of sodium pyrophosphate at room temperature and stir to dissolve using a mechanical stirrer. 500 ml of water was poured into another beaker, and 68 g of copper chloride dihydrate was poured at room temperature, stirred and dissolved.
[0121] After the reaction was completed, it was filtered, washed and dried. The properties before and after heat treatment are shown in Table 1.
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