The invention discloses three-dimensional modified
graphene aerogel and a preparation method thereof and an application in
water treatment. The preparation method comprises the following steps: (1) enabling a precursor of h-CN to be placed in a
crucible, capping and calcining in an
air atmosphere, setting calcining temperature and time, and naturally cooling to a
room temperature, to obtain faintyellow
powder; weighing the faint yellow
powder obtained by calcining, adding alkaline solution, ultrasonic-dispersing, and placing in a water bath, heating and stirring; and after the reaction, afterwashing a milk
white substance obtained by centrifuging the solution in a high speed, freeze-
drying an obtained precipitate, to obtain h-CN
nanowire powder; and (2) using
graphene oxide aqueous dispersion as a precursor, and using the h-CN
nanowire powder as a
nitrogen doping agent, preparing three-dimensional h-CN / GO hydrogel through a hydrothermal method; and reducing the three-dimensional h-CN / GO hydrogel by using a
reducing agent, to obtain the three-dimensional h-CN / r-GO composite
aerogel. The prepared
graphene aerogel is large in specific surface area, large in pore volume, and excellent in pore channel structure, has strong adsorbability, and is capable of achieving rapid and efficient
selective adsorption to polarity and non-polarity organic pollutants.