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Composite special type filler combination method

A special and filler technology, applied in the direction of adding inorganic compounds, can solve the problems of increasing retention rate, reducing paper quality, weakening paper strength, etc., so as to improve filler retention rate, reduce retention aid dosage, and increase paper whiteness degree of effect

Inactive Publication Date: 2008-09-10
GUANGDONG IND TECHN COLLEGE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Generally, the single-pass retention rate of the filler in the fourdrinier paper machine is about 15%, and the retention rate of the white water is only about 40% after multiple reuses. A large amount of filler will flow away with the water, which not only wastes raw materials, but also increases the water treatment load.
At the same time, there is no binding force between the filler and the fiber, so it is not possible to add too much filler, otherwise it will easily cause powder and hair loss after the paper is formed, which will weaken the strength of the paper and reduce the quality of the paper.
Specialty fillers require increased retention due to their high cost and low usage

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] (1) Disperse the special filler (titanium dioxide) into a dispersion suspension with a mass concentration of 1%, and mix it with a fully dissolved polymer aqueous solution (starch aqueous solution) with a mass concentration of 1%. The mass ratio of the special filler to the starch aqueous solution 20:1 to give a mixture.

[0022] (2) Mix the above mixture with acidic electrolytic solution sulfuric acid; acidic electrolytic solution sulfuric acid: the volume ratio of the mixture is 5:1, then stir for 30 minutes, the rotating speed is 200 rpm, after standing overnight, remove the supernatant, the lower layer is white The layer material is the composite special filler, and the obtained composite special filler is in the form of particles visible to the naked eye. Adding 15% (mass percentage) of the composite special filler (titanium dioxide) of the present invention to paper with a weight of 60 grams increases the whiteness of the paper by 30% and the tensile strength by 1...

Embodiment 2

[0024] (1) Disperse the special filler (silicon dioxide) into a dispersion suspension with a mass concentration of 30%, and mix it with a fully dissolved polymer aqueous solution (oxidized starch aqueous solution) with a mass concentration of 10%, and then mix the special filler with the oxidized starch The mass ratio of the aqueous solution was 5:1 to obtain a mixture.

[0025] (2) Then the mixture is mixed with the acidic electrolytic solution ammonium nitrate solution, ammonium nitrate: the volume ratio of the mixture is 1: 1, stir evenly, then after standing still, remove the supernatant liquid, the lower white layer substance is the composite special filler, obtained Composite special fillers are in granular form visible to the naked eye. Add 15% (mass percentage) composite special filler (silicon dioxide) of the present invention in 60 grams of paper, the paper whiteness increases by 20%, the tensile strength increases by 25%, and the filler retention rate increases by 2...

Embodiment 3

[0027] (1) Disperse the special filler (calcined kaolin) into a dispersed suspension with a mass concentration of 25%, pour into a fully dissolved polymer aqueous solution (chitosan aqueous solution) with a mass concentration of 25%, special filler and chitosan aqueous solution The mass ratio of the mixture is 1:5, and after mixing uniformly, a mixture is obtained.

[0028] (2) Pour the above mixture into the acidic electrolyte solution ammonium chloride solution, the ammonium chloride: mixture volume ratio is 10:1, stir while pouring (stirring for 30 minutes, rotating speed 200 rpm), let stand overnight Finally, the supernatant liquid is removed, and the white layer substance in the lower layer is the composite special filler, and the obtained composite special filler can be seen as granular with the naked eye. Adding 15% (mass percentage) of the composite special filler (calcined kaolin) of the present invention to paper with a weight of 60 grams increases the whiteness of t...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention discloses a complex method for compounding a special filling, comprising the following steps that: the special filling is dispersed into a dispersed suspending liquid with a mass concentration ranging from 1 to 30 percent, the dispersed suspending liquid is mixed with a macromolecule water solution with a mass concentration ranging from 1 to 25 percent to obtain a mixture, the mixture and an acidic electrolyte bath solution are mixed evenly, or a fatty acid is added into the mixture and is mixed evenly to obtain a solution, and then the solution and the acidic electrolyte bath solution are mixed evenly; after let stand, an upper layer of clear solution is eliminated, a lower layer of white substance is the special compounded filling. The complex method can improve the hydrophilicity of the special filling and the fiber, increases the use amount of the special filling and obviously improves the intensity of the paper. The complex method can improve the retention of the filling, increase the whiteness of the paper, reduces the waste water processing load and further saves the fiber use amount.

Description

technical field [0001] The invention belongs to the field of chemical synthesis, in particular to a compounding method of special fillers used in papermaking and filling process. Background technique [0002] The fillers used in papermaking are generally white mineral pigments. Due to the unique morphological characteristics of these pigments, they have high light scattering ability and absorption. When used as paper fillers, they can improve paper printability, increase opacity, increase smoothness, and increase whiteness. degree and save fiber. Commonly used paper-making fillers are talcum powder, calcium carbonate and china clay. Special fillers are a type of fillers with very high whiteness, very fine particle size, good filling effect, and very expensive prices, including calcined kaolin, silica, titanium dioxide and some polymer fillers. Due to the high price, the amount added is Rarely, it is generally used in low-quantity paper grades (such as newsprint, cigarette ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H17/67D21H17/68
Inventor 颜进华
Owner GUANGDONG IND TECHN COLLEGE
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