Method for preparing biomass fuel by catalyzing rice straw

A technology for biomass fuel and rice straw, which is applied in the directions of biofuel, waste fuel, chemical instruments and methods, etc., can solve the problems of difficult alcoholysis of straw, incapability of large-scale production of catalyst reuse efficiency, reduction in activity, etc. Agglomerate size, increasing chance of collisions for effective chemical reactions, effect of increasing yield

Inactive Publication Date: 2018-11-30
ANHUI SHENGBAO NEW ENERGY TECH CO LTD
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Problems solved by technology

Moreover, the color of the catalyst after the reaction changes from white to off-white, which may be caused by carbon on the surface of the catalyst; the occurrence of agglomeration affects the reuse of Al 2 (SO 4 ) 3 18H 2 O catalyst activity, compared to fresh Al 2 (SO 4 ) 3 18H 2 O solid catalyst, reused Al 2 (SO 4 ) 3 18H 2 O activity decreased
[0004] According to the above-mentioned problems, the present invention mainly solves the problem that the production of methyl levulinate from biomass cannot be produced on a large scale due to the difficult alcoholysis of straw and the low efficiency of catalyst reuse.

Method used

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Embodiment

[0023] A method for catalytically preparing biomass fuel from rice straw, comprising the following steps: using rice straw as the main raw material, pretreating the rice straw for the first time to obtain straw powder, and then subjecting the straw powder to the second pretreatment to obtain straw suspension Liquid II;

[0024] Dissolve the catalyst aluminum sulfate octadecahydrate in water at 70°C to make a saturated solution, add carrier particles I to fully absorb the saturated solution, dry it in an oven after the absorption is completed, repeat the absorption of the saturated solution again, repeat 3 to 4 times, and obtain the carrier after completion Particle II, the carrier particle III is obtained by coating the carrier particle II;

[0025] Finally, mix the straw suspension II, carrier particles III, methanol solution, and water in a ratio of 15:4:5:20, put them in a high-temperature closed reaction kettle, and heat-preserve alcoholysis at 180°C for 1.2h, and then fil...

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Abstract

The invention discloses a method for preparing biomass fuel by catalyzing rice straw. The method comprises the following steps that the rice straw serves as a main raw material, primary pretreatment is carried out on the rice straw so as to obtain straw powder, then secondary pretreatment is carried out on the straw powder so as to obtain a straw suspension II. According to the method, the structure of cellulose is changed through the pre-treatment process, the size of particles of the cellulose is decreased, the probability of effective chemical reaction collision between cellulose moleculesand a solvent is improved, and the yield of a final target product is increased; and a catalyst carrier is used for adsorbing a catalyst, then the carrier is taken as a unit, a target substrate is catalyzed, and therefore a good effect is achieved.

Description

technical field [0001] The invention relates to the technical field of development and utilization of new energy, in particular to a method for catalytically preparing biomass fuel from rice straw. Background technique [0002] Methyl levulinate is a light yellow, transparent oily compound, a high-efficiency diesel additive, and can also be used alone as a clean fuel. The product quality meets the requirements of the EN590 standard, and the emission meets the requirements of the ULSD standard. This product can reduce greenhouse gas emissions by 96%, and is allowed to be blended with petroleum diesel at a ratio of 65% in Europe. Compared with grease biodiesel, the cost is reduced by 50%, but the sales price is more than 30%. And it has the characteristics of biodegradability, low condensation, good oxidation stability, etc., and it is the development direction of high-grade diesel fuel. However, due to the refractory structure of biomass, most of the current direct alcoholy...

Claims

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Application Information

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IPC IPC(8): C10B53/02B01J27/053
CPCB01J27/053C10B53/02Y02E50/10Y02E50/30
Inventor 曹大强
Owner ANHUI SHENGBAO NEW ENERGY TECH CO LTD
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