A kind of low VOC high performance PPE-PS composite material and preparation method thereof
A PPE-PS, composite material technology, applied in the field of polymer materials, can solve problems such as poor compatibility, achieve low VOC, improve physical properties, and improve VOC effects
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[0040] The preparation method of the PPE-g-PS comprises the following steps:
[0041] (1) with Co 60 - Gamma rays are used as the radiation source to pre-irradiate PPE for 2-4 hours; Co 60 - The gamma ray scanning width is 1.2-2.4m, the beam length is 8-10cm, and the irradiation energy is 10-16kGy.
[0042] (2) Weigh a certain amount of PPE, styrene (St), ionized water, tert-butyl peroxy-2-ethylhexanoate (TBPO), sodium dodecylbenzenesulfonate (SDBS) and sodium phosphate ( Na3PO4); the mass ratio of PPE, styrene, ionized water, tert-butyl peroxy-2-ethylhexanoate, sodium dodecylbenzenesulfonate and sodium phosphate is (100-160): (60-80) :(400-600):(0.3-0.5):(6-8):(3-5).
[0043] (3) Put PPE, styrene, ionized water, tert-butyl peroxy-2-ethylhexanoate, sodium dodecylbenzenesulfonate and sodium phosphate into the reaction kettle in turn, and stir and reflux reaction at 60-80°C 6-8h;
[0044] (4) After the reaction is finished, the product is suction filtered, washed and dried ...
Embodiment 1
[0057] (1) Weighing 80 parts of PPE, 20 parts of PS, 2 parts of PPE-g-PS, 10 parts of modified basalt fiber and 0.1 part of Irganox1330 and mixing them evenly to obtain a mixture;
[0058] (2) Extruding and granulating the mixture obtained in step (1) to obtain PPE-PS composite material P1.
[0059] Among them, the temperature and screw speed of each zone of the twin-screw extruder are: the temperature of the first zone is 170°C, the temperature of the second zone is 220°C, the temperature of the third zone is 220°C, the temperature of the fourth zone is 220°C, the temperature of the fifth zone is 220°C, and the temperature of the sixth zone is 220°C. The head temperature is 220°C; the screw speed is 200r / min.
Embodiment 2
[0061] (1) Weigh 100 parts of PPE, 30 parts of PS, 6 parts of PPE-g-PS, 20 parts of modified basalt fiber, 0.2 part of Irganox1330, 0.1 part of Irganox1010, 0.2 part of Irganox168 and mix them evenly to obtain a mixture ;
[0062] (2) Extrude and granulate the mixture obtained in step (1) to obtain PPE-PS composite material P2.
[0063] Among them, the temperature and screw speed of each zone of the twin-screw extruder are respectively: the temperature of the first zone is 190°C, the temperature of the second zone is 240°C, the temperature of the third zone is 240°C, the temperature of the fourth zone is 240°C, the temperature of the fifth zone is 240°C, and the temperature of the sixth zone is 240°C. The head temperature is 240°C; the screw speed is 260r / min.
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