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Polyaniline lubricating grease and preparation method thereof

A polyaniline grease, polyaniline technology, applied in lubricating compositions, petroleum industry, additives, etc., can solve the problems of limited anti-friction and anti-wear performance, poor dispersion performance, easy agglomeration, etc. Excellent anti-corrosion performance, low cost, improved dispersion performance, anti-friction and anti-wear performance

Active Publication Date: 2018-12-21
长沙德驰润滑油脂有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the strong conjugated π-electron system in the polyaniline molecule, its dispersion performance in the grease is poor and it is easy to agglomerate. Therefore, the anti-friction and anti-wear performance of polyaniline in the grease is limited.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] 10 g of polyaniline was weighed and added to 50 g of 1-butyl 3-methylimidazolium hexafluorophosphate, the mixture was heated to 80° C. and stirred for 1 hour, and then the mixture was cooled to room temperature. Add acetone to dilute and filter for 3 times, then put the filter cake in an oven and dry at 40°C for 24 hours to obtain 1-butyl 3-methylimidazolium hexafluorophosphate modified polyaniline powder.

[0026] Weigh 3g of the modified polyaniline powder prepared in the above steps, add it to 50g of synthetic oil, heat the mixture to 80°C and stir for 2 hours to fully disperse the polyaniline in the synthetic oil, then add 20g of polytetrafluoroethylene , continue stirring at 80° C. for 2 hours, wait for the mixture to cool to room temperature, and use a grinder to grind three times to obtain polyaniline grease.

Embodiment 2

[0028] 15 g of polyaniline was weighed and added to 60 g of 1-butyl 3-methylimidazolium tetrafluoroborate, the mixture was heated to 60° C. and stirred for 1 hour, and then the mixture was cooled to room temperature. Add petroleum ether to dilute and filter 5 times, and then put the filter cake in an oven at 50° C. for 24 hours to obtain 1-butyl 3-methylimidazolium tetrafluoroborate-modified polyaniline powder.

[0029] Weigh 5 g of the modified polyaniline powder prepared in the above steps, add it to 80 g of mineral oil, heat the mixture to 100° C. and stir for 2 hours to fully disperse the polyaniline in the mineral oil, then add 20 g of bentonite, at 80 Stirring was continued for 2 hours at °C, and the mixture was cooled to room temperature, and ground three times with a grinder to obtain polyaniline grease.

Embodiment 3

[0031] 6g of polyaniline was weighed and added to 50g of 1-hexyl 3-methylimidazolium hexafluorophosphate, the mixture was heated to 80°C and stirred for 1.5 hours, and then the mixture was cooled to room temperature. Add absolute ethanol to dilute and filter 3 times, then put the filter cake in an oven and dry at 60°C for 24 hours to obtain 1-hexyl 3-methylimidazolium hexafluorophosphate modified polyaniline powder.

[0032] Weigh 30g of synthetic oil and 30g of mineral oil and mix them thoroughly, weigh 6g of modified polyaniline powder prepared in the above steps, add it to the prepared mixed oil, heat the mixture to 80°C and stir for 1.5 hours, Fully disperse the polyaniline in the mixed oil, then add 8 g of attapulgite, continue stirring at 100° C. for 1.5 hours, wait until the mixture is cooled to room temperature, and use a grinder to grind three times to obtain polyaniline grease.

[0033] Tribological performance evaluation:

[0034] The MS-10J four-ball friction test...

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Abstract

The invention discloses polyaniline lubricating grease and a preparation method thereof. The preparation method comprises the following steps: mixing polyaniline with ionic liquid, performing heating,performing stirring, then performing cooling, adding an organic solvent, performing filtration, and baking filter cakes so as to obtain ionic liquid modified polyaniline, wherein the mass ratio of the polyaniline to the ionic liquid is 0.1-0.5; mixing base oil with ionic liquid modified polyaniline, performing heating, performing stirring, then adding a thickening agent, continuing performing stirring, and after performing cooling, performing grinding with a grinding machine so as to obtain the polyaniline lubricating grease. According to the polyaniline lubricating grease and the preparationmethod thereof disclosed by the invention, the polyaniline is modified with the ionic liquid, so that the dispersibility and the friction reduction and abrasion resisting properties of the polyaniline in lubricating grease are improved; besides, excellent anticorrosion property and environment stabilizing property of the polyaniline and the low cost characteristic are fully utilized, so that theprepared lubricating grease is low in cost, good in environmental stability, excellent in friction reduction and abrasion resisting properties and excellent in anticorrosion property.

Description

technical field [0001] The invention relates to a polyaniline lubricating grease and a preparation method thereof, belonging to the technical field of lubricants. Background technique [0002] Grease not only requires good anti-friction and anti-wear properties, but also requires excellent anti-corrosion properties. At present, in order to improve these properties of lubricating grease, anti-friction and anti-wear additives and anti-corrosion additives are widely used in the production of lubricating grease. However, due to the wide variety of anti-friction and anti-wear additives and anti-corrosion additives, and there are compatibility problems between different additives, the production process of lubricating grease is complicated and the cost is high. Moreover, some additives contain elements such as sulfur and zinc, which are likely to cause environmental pollution during use. Therefore, it is necessary to prepare a lubricating grease with good anti-friction and anti-...

Claims

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Application Information

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IPC IPC(8): C10M169/06C10M149/22C10N30/06C10N50/10C10N30/12
CPCC10M149/22C10M169/06C10M2217/046C10N2030/06C10N2030/12C10N2050/10C10N2020/04
Inventor 谢向阳周茂林
Owner 长沙德驰润滑油脂有限公司