The invention belongs to the technical field of aluminum alloy profiles and particularly relates to an electrostatic spraying process for aluminum alloy profiles. The electrostatic spraying process for the aluminum alloy profiles comprises steps as follows: surfaces of aluminum alloys are polished, sprayed with water, washed and dried; a to-be-processed workpiece is degreased, sprayed with water and washed; the degreased workpiece is subjected to oil removal, sprayed with water and washed; the surface of the workpiece subjected to oil removal is sprayed with a diluted surface conditioner; the workpiece subjected to surface conditioning is phosphorized, the phosphorized workpiece is passivated, the surface of the passivated workpiece is sprayed with water and washed, the workpiece is dried and cooled, and the dried workpiece is obtained; the surface of the dried workpiece is sprayed with powdery paint in an electrostatic spraying manner by a spray gun and left to stay still, and the workpiece which is sprayed and left to stay still is obtained; the workpiece which is sprayed and left to stay still is conveyed to a baking room and then cooled to the room temperature. With the adoption of the electrostatic spraying process for the aluminum alloy profiles, the adhesive force, the hardness, the wear resistance, the acid resistance and other performance of surface coatings are remarkably improved, and the service life of the aluminum alloy profiles is prolonged effectively.