Algal residue containing 3D printing wire rod and preparing method thereof

A 3D printing and algae residue technology, applied in the field of materials, can solve the problems of cumbersome preparation process of porous adsorption materials, difficult follow-up treatment, secondary pollution, etc., and achieve the effect of solving follow-up recycling problems, reducing environmental burden, and high printing accuracy

Inactive Publication Date: 2019-01-04
FUJIAN NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the problems of the above-mentioned background technology, the purpose of the present invention is to solve the problems of the existing porous adsorption materials such as cumbersome preparation process, high energy consumption, difficult follow-up treatment, easy to cause secondary pollution, etc., and turn "residual biomass" into treasure , providing a 3D printing wire containing algae residue and a preparation method thereof

Method used

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  • Algal residue containing 3D printing wire rod and preparing method thereof
  • Algal residue containing 3D printing wire rod and preparing method thereof
  • Algal residue containing 3D printing wire rod and preparing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A kind of 3D printing wire material containing algae residue, is characterized in that, is made of the following components by weight percentage:

[0037] Polylactic acid (PLA) 71

[0038] Chlorella Algae Residue 28.95

[0039] White oil 0.05

[0040] The preparation method of a 3D printing wire containing algae residue comprises the following steps:

[0041] A. Vacuum dry PLA (710g) and chlorella algae residue (289.5g) for 12 hours respectively;

[0042] B. According to the weight percentage formula, weigh the dried PLA (710g), chlorella algae residue (289.5g) and white oil (0.5g);

[0043] C. Place the weighed components in a high-speed kneader, keep the rotating speed at 1000rpm / min, and stir at high speed for 5min;

[0044] D. Put the above-mentioned fully mixed and uniform raw materials into the twin-screw extruder, and set the extrusion temperature at 110°C, 120°C, 135°C, 160°C, 175°C, 175°C, 170°C, 165°C, 160°C, At 155°C, melt and plasticize in the twin-scre...

Embodiment 2

[0051] A kind of 3D printing wire material containing algae residue, is characterized in that, is made of the following components by weight percentage:

[0052] Polybutylene succinate (PBS) 77

[0053] Spirulina algal residue 22.8

[0054] White oil 0.2

[0055] A preparation method for 3D printing wire containing algae residue comprises the following steps:

[0056] A. Vacuum dry PBS (770g) and spirulina algae residue (228g) for 12 hours respectively;

[0057] B. According to the weight percentage formula, weigh the dried PBS (770g), spirulina algae residue (228g) and white oil (2g);

[0058] C. Place the weighed components in a high-speed kneader, keep the rotating speed at 2000rpm / min, and stir at a high speed for 6min;

[0059] D. Put the above-mentioned fully mixed and uniform raw materials into the twin-screw extruder, and set the extrusion temperature at 98°C, 105°C, 110°C, 120°C, 130°C, 132°C, 125°C, 125°C, 120°C, 110°C, melt and plasticize in the twin-screw melt...

Embodiment 3

[0066] A kind of 3D printing wire material containing algae residue, is characterized in that, is made of the following components by weight percentage:

[0067] Polyamide (PA)) 65

[0068] Scenedesmus slag 34.7

[0069] White oil 0.3

[0070] A preparation method for 3D printing wire containing algae residue comprises the following steps:

[0071] A. Vacuum dry PA (650g) and Scenedesmus residue (347g) for 12 hours respectively;

[0072] B. According to the weight percentage formula, weigh the dried PA (650g), Scenedesmus algal residue (347g) and white oil (3g);

[0073] C. Place the weighed components in a high-speed kneader, keep the rotating speed at 2000rpm / min, and stir at a high speed for 6min;

[0074] D. Put the above-mentioned fully mixed and uniform raw materials into the twin-screw extruder, and set the extrusion temperature at 195°C, 200°C, 205°C, 215°C, 220°C, 220°C, 215°C, 215°C, 200°C, Melt and plasticize in the twin-screw melting cavity and extrude the raw...

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PUM

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Abstract

The invention discloses an algal residue containing 3D printing wire rod and a preparing method thereof. The 3D printing wire rod is prepared from 59-91 wt% of matrix resin, 8-40 wt% of algal residuesand 0.05-2 wt% of white oil. The preparing method includes the steps of firstly, conducting drying; secondly, weighing the materials; thirdly, conducting high-speed kneading; fourthly, conducting melting and granulating; fifthly, conducting melting and extruding; sixthly, conducting cooling and dragging; seventhly, conducting binding; eighthly, conducting printing through the FDM technology to form a specific structure. By introducing the residual biomass, the wire rod is rich in functionality group, can be combined with dye molecules or heavy metal ions and is low in price; the fine particleporous supporting framework is prepared through the efficient precise FDM technology. The wire rod as an adsorbing agent overcomes the defect that secondary contamination is caused when an adsorbingagent and a solution can hardly be separated after dyes are processed by polysaccharides in the forms of solution, powder, microspheres and gel; the wire rod has certain recycling performance, and thegreen circulation and efficient utilization of the material are realized.

Description

technical field [0001] The invention belongs to the field of materials, and in particular relates to a 3D printing wire material containing algae residue and a preparation method thereof. Background technique [0002] Water pollution caused by heavy metals and dyes has always been a serious environmental problem. Heavy metal ions and synthetic dyes are common toxic and carcinogenic substances. They are not easily biodegradable and accumulate in organisms through the food chain, leading to various diseases and disorders. Adsorption is the most commonly used method for this type of wastewater treatment in many researchers and engineering practices. Since the adsorbents used are mostly in the form of powder, this makes subsequent treatment difficult, causing serious secondary pollution, and contains dyes. Or the heavy metal adsorbent is highly toxic, and the energy consumption and cost input are too large if the conventional centrifugation method is used to collect. Most chem...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29B9/06B29C48/00C08L67/04C08L67/02C08L55/02C08L77/00C08L91/00C08L99/00B33Y70/00C02F3/32C02F101/20C02F101/30
CPCB29B9/06B33Y70/00C02F3/322C02F2101/20C02F2101/30C08L55/02C08L67/02C08L67/04C08L77/00C08L2205/03C08L91/00C08L99/00
Inventor 陈庆华徐晓榕林陈胜夏新曙钱庆荣杨松伟肖荔人
Owner FUJIAN NORMAL UNIV
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