Modified polyphenylene ether high molecular polymer, high molecular film and corresponding preparation method
A high-molecular polymer and high-molecular film technology, which is applied in the field of modified polyphenylene ether high-molecular polymers, can solve the problem of high-frequency signal transmission and high-speed digitalization, and the inability of flexible circuit boards to achieve high-frequency signal transmission impedance matching And other issues
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[0033] A preferred embodiment of the present invention also provides a method for preparing the above-mentioned modified polyphenylene ether polymer, which includes the following steps:
[0034] Step S1, uniformly mixing a polyphenylene ether polymer, a reactive reactant and a solvent to prepare a resin composition. In the resin composition, the weight ratio of the polyphenylene ether polymer to the active reactant is 1:10˜50:1. The solvent only needs to dissolve the polyphenylene ether polymer and the active reactants. In this embodiment, the viscosity of the resin composition is 40000cps˜60000cps.
[0035] The chemical structural formula of the polyphenylene ether polymer is
[0036]
[0037] The active reactant may be selected from but not limited to one of 2-methacrylic anhydride, 4-chloromethylstyrene and trans-cinnamoyl chloride.
[0038] In this embodiment, the solvent is N,N-dimethylacetamide (DMAc). In other embodiments, the solvent may also be other organic so...
Embodiment 1
[0057] Add 60g of 4,4'-difluorobenzophenone and 71g of 4,4'-difluorobenzophenone successively in the first reaction flask. The polyphenylene ether copolymer, 77g of potassium carbonate, 30mL of xylene and 393.6g of N,N-dimethylacetamide were stirred and dissolved, and then heated at 130 degrees Celsius for 12 hours in a nitrogen atmosphere to prepare the chemical structural formula: of the first product.
[0058]Add 50g of the first product and 23.6g of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO, the chemical formula is ), 102.7g of phenol and 0.9g concentration of 97% sulfuric acid and stirring and dissolving, then heated at 140 degrees centigrade in nitrogen atmosphere for 12 hours to prepare the chemical structural formula as
[0059] polyphenylene ether polymers.
[0060] Add 10g of the above-mentioned polyphenylene ether polymer, 3.5g of 2-methacrylic anhydride, 0.1g of sodium acetate and 100mL of N,N-dimethylacetamide to the third reaction flask in s...
Embodiment 2
[0062] Add 10g of the polyphenylene ether polymer in Example 1, 3.5g of 4-chloromethylstyrene, 0.1g of sodium acetate and 100mL of N,N-dimethylacetamide into the reaction flask in sequence and Stir and dissolve, then heat at 80 degrees Celsius for 12 hours in a nitrogen atmosphere to prepare the chemical structural formula as
[0063] modified polyphenylene ether polymers. The viscosity of the modified polyphenylene ether polymer is 51s000cps.
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