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Flame-retardant modified silicone oil, and preparation method and application thereof

A modified silicon and flame-retardant technology, which is applied in the preparation of silicone oil, the application in textile production, and the field of flame-retardant modified silicone oil. It can solve the problems of flame retardancy and achieve excellent softness and flame retardancy. Effect

Active Publication Date: 2019-02-01
黄山市强力化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] But the silicone oils prepared by the above two inventions are all flammable, and it is impossible to solve the problem that it can be used as a softener to play a flame-retardant function on the woven twill cotton bleached cloth.

Method used

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  • Flame-retardant modified silicone oil, and preparation method and application thereof
  • Flame-retardant modified silicone oil, and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] A flame-retardant modified silicone oil, prepared by the following method:

[0049] (1) prepare each raw material, the molar proportion of each raw material is:

[0050] Tetrabromophthalic anhydride diol 10mol%

[0051] Trimethylolmelamine resin 16mol%

[0052] 1,4-dibromo-2,3-butanediol 15mol%

[0053] Hexaethylcyclotrisiloxane 8mol%

[0054] Methyldichlorosilane 16mol%

[0055] 3-Aminopropylsilanetriol 15mol%

[0056] Ethylenediaminetetramethylenephosphonic acid 10mol%

[0057] Hexamethyldisiloxane 10mol%

[0058] The catalyst is phosphotungstic acid, and the dosage is 1% of the total molar weight of raw materials

[0059] Antioxidant is three (nonylphenol) phosphites, and consumption is 0.3% of material total molar weight

[0060] (2) Tetrabromophthalic anhydride diol, trimethylol melamine resin, 1,4-dibromo-2,3-butanediol, hexaethylcyclotrisiloxane, methyl dichlorosilane , 3-aminopropylsilanetriol and the catalyst were added to the reaction kettle, and the ...

Embodiment 2

[0065] A flame-retardant modified silicone oil, prepared by the following method:

[0066] (1) prepare each raw material, the molar proportion of each raw material is:

[0067] Tetrabromophthalic anhydride diol 18mol%

[0068] Trimethylolmelamine resin 15mol%

[0069] 1,4-dibromo-2,3-butanediol 14mol%

[0070] Hexaethylcyclotrisiloxane 9mol%

[0071] Methyldichlorosilane 14mol%

[0072] 3-Aminopropylsilanetriol 12mol%

[0073] Ethylenediaminetetramethylenephosphonic acid 9mol%

[0074] Hexamethyldisilazide 9mol%

[0075] The catalyst is phosphotungstic acid and the dosage is 1.5% of the total molar weight of raw materials

[0076] Antioxidant is three (nonylphenol) phosphites, and consumption is 0.3% of material total molar weight

[0077] (2) Tetrabromophthalic anhydride diol, trimethylolmelamine resin, 1,4-dibromo-2,3-butanediol, hexaethylcyclotrisiloxane, methyldichlorosilane, Add 3-aminopropylsilanetriol and catalyst into the reactor, and carry out polymerization ...

Embodiment 3

[0082] A flame-retardant modified silicone oil, prepared by the following method:

[0083] (1) prepare each raw material, the molar proportion of each raw material is:

[0084] Tetrabromophthalic anhydride diol 15mol%

[0085] Trimethylolmelamine resin 12mol%

[0086] 1,4-dibromo-2,3-butanediol 18mol%

[0087] Hexaethylcyclotrisiloxane 6mol%

[0088] Methyldichlorosilane 18mol%

[0089] 3-Aminopropylsilanetriol 13mol%

[0090] Ethylenediaminetetramethylenephosphonic acid 8mol%

[0091] Hexamethyldisiloxane 10mol%

[0092] The catalyst is phosphotungstic acid and the dosage is 0.5% of the total molar weight of raw materials

[0093] Antioxidant is three (nonylphenol) phosphites, and consumption is 0.2% of material total molar weight

[0094] (2) Tetrabromophthalic anhydride diol, trimethylolmelamine resin, 1,4-dibromo-2,3-butanediol, hexaethylcyclotrisiloxane, methyldichlorosilane, Add 3-aminopropylsilanetriol and catalyst into the reactor, and carry out polymerization...

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Abstract

The invention belongs to the field of preparation of modified silicone oil, and relates to a flame-retardant modified silicone oil, a preparation method thereof, and an application thereof in textileproduction. The modified silicone oil is mainly prepared through a copolymerization reaction of (perbromo-1,2-phenylene)dimethanol, trimethylol melamine resin, 1,4-dibromo-2,3-butylene glycol, hexaethylcyclotrisiloxane, methyldichlorosilane, 3-aminopropylsilane triol, ethylenediamine tetramethylenephosphonic acid and 1,3-bis(trimethylsilyl)urea. Monomers with high content of flame-retardant elements, such as bromine, nitrogen and phosphorus, comprising (perbromo-1,2-phenylene)dimethanol, trimethylol melamine resin, 1,4-dibromo-2,3-butylene glycol and ethylenediamine tetramethylenephosphonic acid are used as main copolymerization raw materials, and are copolymerized with an organosiloxane raw material to obtain the modified silicone oil. The obtained modified silicone oil has an excellent flexible performance, also has an excellent flame retardant performance due to the high content of the flame retardant elements comprising bromine, nitrogen and phosphorus, can be applied to textiles of machine-made bleached twill pure cotton clothes, and has an oxygen index reaching 32% or above.

Description

technical field [0001] The invention belongs to the field of preparation of modified silicone oil, and in particular relates to a flame-retardant modified silicone oil, and also relates to a preparation method of the above-mentioned silicone oil and its application in textile production. Background technique [0002] Although ordinary silicone oil is not flammable, when it is used as a softener on textiles, it cannot effectively prevent the burning of cotton and various fiber textiles. The oxygen index of textiles using ordinary silicone oil as a softener is still low, and the flammability Strong, flammable, and a great safety hazard; in order to reduce its flammability and improve safety, it is necessary to use truly flame-retardant silicone oil to further increase the oxygen index of textiles while ensuring softness. [0003] CN104628990A discloses a slip elastic silicone oil for textiles, a preparation method and an application thereof. The method is to add isophorone di...

Claims

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Application Information

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IPC IPC(8): C08G77/26C08G77/06D06M15/643
CPCC08G77/06C08G77/26D06M15/6436D06M2200/30D06M2200/50
Inventor 叶光华王永垒胡红莉方少平
Owner 黄山市强力化工有限公司
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